江西德兴铜厂铜矿水－岩体系氢氧同位素演化

 江西铜厂铜矿床露天采场岩石76个全岩氧同位素组成表明,该超大型铜矿的形成与具有5个水-岩交换成矿体系汇集在一起有关。水-岩体系计算表明,成矿流体储库形成是大气降水与千枚岩和花岗闪长斑岩在300℃以及W/R比值为0.5左右条件下形成,而后上升进入矿化沉积体系时温度降低,W/R比值超过10.0,计算的最少水量达1.9×10¹⁰t以上。     

硫化物矿物电子探针能谱快速定量分析

电子探针在地质普查对找矿、矿床成因与评价以及矿产综合利用等方面的研究中，均会碰到大量的硫化物矿物的分析测试任务。在能谱定量分析方法的基础上新开发出矿物能谱快速定量分析方法，建立了数十硫化物矿物能谱谱库，并编制了矿物自动检索和拟合的计算机程序。该方法提高了矿物定量分析精度，缩短了分析时间，保证了生产、科研任务的顺利完成。     

The Existence of the Negative Charge of Gold in Sulphide Minerals and Its Formation Mechanism1;

Abstract: Through a study, particularly an X-ray photoelectron spectroscopy (XPS or ESCA) analysis, of gold-bearing arsenopyrite and pyrite in Carlin-type gold deposits of Guangxi, China, and hydrothermally synthesized gold-bearing pyrite and marcasite, the authors have found that these minerals contain “invisible gold” whose binding energy is lower than that of native gold (Au°). Therefore they suggest that gold occurs in a negative charge state in these sulphide minerals as it replaces some sulphur and is combined with sulphur with the covalent bond. This paper also preliminarily discusses the possibility of its formation from the chemistry and geochemistry of gold, crystal chemistry of arsenopyrite, pyrite and marcasite and geochemical environment.     

The influence of pressure on the structure and dynamics of hydrogen bonds in zoisite and clinozoisite

Density functional theory calculations have been used to study the pressure-induced changes of the hydrogen bond of Fe-free orthozoisite and clinozoisite and the concomitant shifts of the OH-stretching frequencies. Two independent parameter-free lattice dynamical calculations have been employed. One was based on a plane-wave basis set in conjunction with norm-conserving pseudopotentials and a density functional perturbation theory approach, while the other used a localised basis set and a finite displacement algorithm for the lattice dynamical calculations. Both models confirm the unusually large pressure-induced red-shift found experimentally (−33.89 cm⁻¹/GPa) in orthozoisite, while the pressure-induced shifts in clinozoisite are much smaller (−5 to −9 cm⁻¹/GPa). The atomistic model calculations show that in orthozoisite the nearly linear O–H⋯O arrangement is compressed by about 8% on a pressure increase to 10 GPa, while concomitantly the O–H distance is significantly elongated (by 2.5% at 10 GPa). In clinozoisite, the O–H⋯O arrangement is kinked at ambient conditions and remains kinked at high pressures, while the O-H distance is elongated by only 0.5% at 10 GPa. The current calculations confirm that correlations between the distances and dynamics of hydrogen bonds, which have been established at ambient conditions, cannot be used to infer hydrogen positions at high pressures.     

钴的赋存状态及其在找矿和资源评估中的意义

通过分析含钴矿物类型的多样性 ,得出地球系统中钴呈硫化物、类硫化物、铁氧化物和呈类质同像代替铁多种赋存状态及其受晶体化学因素控制特点。基于钴赋存状态的不同 ,提出当前钴的地球化学找矿和矿产资源评估中仅以钴量化丰度值作为化探异常和矿石品位判据的局限性。指出元素状态丰度提供资源信息的重要意义     

论华南块状硫化物矿床成矿规律与找矿方向

华南块状硫化物矿床，在成因上同生喷气沉积为主，兼具后期叠加改造特点。在成矿时代上具多期成矿特征，尤以中－晚元古代，泥盆纪，石岩纪和晚侏罗世－白垩４个时代为主。在空间分布上具“成带分布，分段集中，成群产出”的规律，受拉张性明背景，火山或热泉活动及特殊岩相古地理环境控制。重要矿床集中于一些特殊成矿结中。成矿作用表现出明显的继承性和新生性，成矿物质组合也随着时间和空间而发生规律性变化。需指出，江南古陆周     

安徽铜陵冬瓜山铜(金)矿床H-O-S-Pb同位素组成及其示踪成矿物质来源

冬瓜山铜(金)矿床中主矿体成层状,受石炭系层位控制,对于其物质来源尚存在较大分歧。为了查明冬瓜山铜(金)矿床成矿物质来源,本文对冬瓜山铜(金)矿床不同类型矿体的氢、氧、硫、铅同位素进行了系统地测定。并将冬瓜山铜(金)矿床与铜陵矿集区内典型矽卡岩型矿床的硫、铅同位素组成进行了对比研究。结果表明:冬瓜山铜(金)矿床不同类型矿体之间具有相同的物质成分来源,不同类型矿体的成矿流体主要来源于岩浆水,硫源均为岩浆硫,且与区域上典型矽卡岩型矿床的硫同位素组成一致,铅同位素特征表明,不同类型矿体铅的来源主要为与岩浆作用有关的幔源铅。     

浙江八面山萤石矿床氢氧同位素地球化学

浙江常山八面山萤石矿床具有矿源层——岩浆岩侵入体——断裂构造"三位一体"的控矿模式,矿石类型以深灰色块状与条带状细粒萤石矿石为主,该类矿石外貌特征与灰岩极其相似,呈黑灰色、深灰色,比重较灰岩大;其次为紫色与翠绿色粗、巨晶块状萤石矿石,此类矿石主要产出于陡倾斜脉状矿体中.通过对不同矿石类型矿物原生包裹体水δ180和δD分...     

熊耳山银铅成矿区物探找矿方法应用研究

通过对铁炉坪、蒿坪沟银铅（金）矿区物探工作的研究分析，结合地质物化探工作，提出了在熊耳山寻找构造蚀变岩（破碎带）型银铅矿脉的找矿标志和工作方法。并利用两矿区的勘查验证结果，结合地物化异常标志，对两矿区外围预测区的找矿前景进行了类比分析。