Oxidation of As-bearing gold ore—a comparison of batch and column experiments

This study deals with the experimental determination of the rate of weathering and As release from Au-bearing sulfide ores of the Mokrsko-West deposit (Czech Republic). The elevated As contents in the ore and the possible As mobilisation must be taken into account due to the close proximity of the deposit to the Vltava River, a source of drinking water for Prague. Crushed and homogenized ore material was divided into four grain-size fractions showing uniform chemical and mineralogical composition and subjected to batch and column leaching experiments. The most important reactions controlling metal leaching include (i) oxidation of sulfides, (ii) carbonate equilibrium and (iii) precipitation of hydrated ferric oxides (HFO). Hydrated ferric oxides were found to be important sorbents of mobilized As. The highest concentration of As in the leachates was obtained from the 64–1000 μm fraction. The oxidation rate in the agitated batch experiment calculated on the basis of sulfate concentrations is an order of magnitude higher (3.8×10⁻⁹ to 4.4×10⁻⁸ mol SO₄²⁻ h⁻¹ g⁻¹) than in the static column experiment (9.6×10⁻¹⁰ to 7.4×10⁻⁹ mol SO₄²⁻ h⁻¹ g⁻¹). The higher oxidation rate of batch experiments is explained by abrasion of oxidation products (mainly HFO) and by further exposition of reaction surfaces of the sulfide grains.     

The North of Eastern Siberia: Refuge of Mammoth Fauna in the Holocene

The global climate changings at the end of Pleistocene led to extinction of the typical representatives of Mammoth fauna–mammoth, woolly rhinoceros, wild horse, bison, muskox, cave lion, etc.–on the huge territories of Northern Eurasia. Undoubtedly the Mammoth fauna underwent pressure from the Upper Paleolithic Man, whose hunting activity also could play the role in decreasing the number of mammoths and other representatives of megafauna (large mammals). Archaeological data testify that the typical representatives of Mammoth fauna were the Man's hunting objects only till the end of the Pleistocene. Their bone remains are not usually found on the settlements of Mesolithic Man. Formerly it was supposed that the megafauna of ‘Mammoth complex’ was extinct by the beginning of Holocene. Nevertheless the latest data testify that the global extinction of the Mammoth fauna was sufficiently delayed in the north of Eastern Siberia. In the 1990s some radiocarbon data testified that the mammoths on the Wrangel Island existed for a long time during the Holocene from 8000 till 3700 y. BP. The present radiocarbon data show that wild horses inhabited the north of Eastern Siberia (the lower stream of the Enissey river, the Novosibirskie Islands, the East Siberian sea-shore) 3000–2000 y. BP. Musk-oxen lived on the Taimyr Peninsula and the Lena River delta about 3000 y. BP. Some bison remains from Eastern Siberia belong to the Holocene. The following circumstances could promote the process of preservation of the Mammoth fauna representatives. The cool and dry climate of this region promotes the maintenance of steppe associations – habitats of those mammals. The Late Paleolithic and Mesolithic settlements are not found in the Arctic zone of Eastern Siberia from the Taimyr Peninsula to a lower stream of the Yana River; they are very rare in the basins of the Indigirka and Kolyma Rivers. So, the small number of the Stone Age hunting tribes on the North of Eastern Siberia was another factor in the long-term preservation of some Mammoth fauna representatives.     

Mitigation of liquefaction and associated ground deformations by stone columns

Soil liquefaction and associated ground failures have been a major source of damage during the past earthquakes. The risk of liquefaction and associated ground deformation can be reduced by various ground-improvement methods including the stone column (gravel drain) technique. This paper presents the current state of the stone column technologies as a liquefaction countermeasure. A comprehensive review is provided aiming to: (a) identify key considerations for the general use of stone columns as a liquefaction countermeasure, (b) provide insights for design and construction, (c) compile the latest research developments, and (d) identify sources of useful information. Case histories of field applications and observed field performance are cited to portray different stone column applications and observed effectiveness. The paper identifies areas where more research is needed and includes recommendations for future research and development.     

Holocene peat and carbon accumulation rates in the southern taiga of western Siberia

Although recent studies have recognized peatlands as a sink for atmospheric CO₂, little is known about the role of Siberian peatlands in the global carbon cycle. We have estimated the Holocene peat and carbon accumulation rate in the peatlands of the southern taiga and subtaiga zones of western Siberia. We explain the accumulation rates by calculating the average peat accumulation rate and the long-term apparent rate of carbon accumulation (LORCA) and by using the model of Clymo (1984, Philosophical Transactions of the Royal Society of London Series B 303, 605-654). At three key areas in the southern taiga and subtaiga zones we studied eight sites, at which the dry bulk density, ash content, and carbon content were measured every 10 cm. Age was established by radiocarbon dating. The average peat accumulation rate at the eight sites varied from 0.35 ± 0.03 to 1.13 ± 0.02 mm yr⁻¹ and the LORCA values of bogs and fens varied from 19.0 ± 1.1 to 69.0 ± 4.4 g C m⁻² yr⁻¹. The accumulation rates had different trends especially during the early Holocene, caused by variations in vegetation succession resulting in differences in peat and carbon accumulation rates. The indirect effects of climate change through local hydrology appeared to be more important than direct influences of changes in precipitation and temperature. River valley fens were more drained during wetter periods as a result of deeper river incision, while bogs became wetter. From our dry bulk density results and our age-depth profiles we conclude that compaction is negligible and decay was not a relevant factor for undrained peatlands. These results contribute to our understanding of the influence of peatlands on the global carbon cycle and their potential impact on global change.     

Holocene hydrographical changes of the eastern Laptev Sea (Siberian Arctic) recorded in δO profiles of bivalve shells

Oxygen isotope profiles along the growth axis of fossil bivalve shells of Macoma calcarea were established to reconstruct hydrographical changes in the eastern Laptev Sea since 8400 cal yr B.P.. The variability of the oxygen isotopes (δ¹⁸O) in the individual records is mainly attributed to variations in the salinity of bottom waters in the Laptev Sea with a modern ratio of 0.50‰/salinity. The high-resolution δ¹⁸O profiles exhibit distinct and annual cycles from which the seasonal and annual salinity variations at the investigated site can be reconstructed. Based on the modern analogue approach oxygen isotope profiles of radiocarbon-dated bivalve shells from a sediment core located northeast of the Lena Delta provide seasonal and subdecadal insights into past hydrological conditions and their relation to the Holocene transgressional history of the Laptev Sea shelf. Under the assumption that the modern relationship between δ¹⁸O_w and salinity has been constant throughout the time, the δ¹⁸O of an 8400-cal-yr-old bivalves would suggest that bottom-water salinity was reduced and the temperature was slightly warmer, both suggesting a stronger mixture of riverine water to the bottom water. Reconstruction of the inundation history of the Laptev Sea shelf indicates local sea level ∼27 m below present at this time and a closer proximity of the site to the coastline and the Lena River mouth. Due to continuing sea level rise and a southward retreat of the river mouth, bottom-water salinity increased at 7200 cal yr B.P. along with an increase in seasonal variability. Conditions comparable to the modern hydrography were achieved by 3800 cal yr B.P.     

Fifty-thousand-year vegetation and climate history of Noel Kempff Mercado National Park, Bolivian Amazon

Pollen and charcoal records from two large, shallow lakes reveal that throughout most of the past 50,000 yr Noel Kempff Mercado National Park, in northeastern lowland Bolivia (southwestern Amazon Basin), was predominantly covered by savannas and seasonally dry semideciduous forests. Lowered atmospheric CO₂ concentrations, in combination with a longer dry season, caused expansion of dry forests and savannas during the last glacial period, especially at the last glacial maximum. These ecosystems persisted until the mid-Holocene, although they underwent significant species reassortment. Forest communities containing a mixture of evergreen and semideciduous species began to expand between 6000 and 3000 ¹⁴C yr B.P. Humid evergreen rain forests expanded to cover most of the area within the past 2000 ¹⁴C yr B.P., coincident with a reduction in fire frequencies. Comparisons between modern pollen spectra and vegetation reveal that the Moraceae-dominated rain forest pollen spectra likely have a regional source area at least 2-3 km beyond the lake shore, whereas the grass- and sedge-dominated savanna pollen spectra likely have a predominantly local source area. The Holocene vegetation changes are consistent with independent paleoprecipitation records from the Bolivian Altiplano and paleovegetation records from other parts of southwestern Amazonia. The progressive expansion in rain forests through the Holocene can be largely attributed to enhanced convective activity over Amazonia, due to greater seasonality of insolation in the Southern Hemisphere tropics driven by the precession cycle according to the Milankovitch Astronomical Theory.     

Late Holocene δC and pollen records of paleosalinity from tidal marshes in the San Francisco Bay estuary, California

Records of stable carbon isotopes (δ¹³C) are presented from cores collected from four San Francisco Bay marshes and used as a proxy for changes in estuary salinity. The δ¹³C value of organic marsh sediments are a reflection of the relative proportion of C₃ vs. C₄ plants occupying the surface, and can thus be used as a proxy for vegetation change on the marsh surface. The four marshes included in this study are located along a natural salinity gradient that exists in the San Francisco Bay, and records of vegetation change at all four sites can be used to infer changes in overall estuary paleosalinity. The δ¹³C values complement pollen data from the same marsh sites producing a paleoclimate record for the late Holocene period in the San Francisco Bay estuary. The data indicate that there have been periods of higher-than-average salinity in the Bay estuary (reduced fresh water inflow), including 1600-1300 cal yr B.P., 1000-800 cal yr B.P., 300-200 cal yr B.P., and ca. A.D. 1950 to the present. Periods of lower-than-average salinity (increased fresh water inflow) occurred before 2000 cal yr B.P., from 1300 to 1200 cal yr B.P. and ca. 150 cal yr B.P. to A.D. 1950. A comparison of the timing of these events with records from the California coast, watershed, and beyond the larger drainage of the Bay reveals that the paleosalinity variations reflected regional precipitation.     

川西亚高山三个森林群落的湿林冠蒸发速率

于3个假说和林冠上方2m处的气象变量，采用Penman-Monteith组合模型估算了一个生长季节内川西亚高山林区分别以云杉(SF)、冷杉(FF)和白桦(BF)为优势树种的3个林分的湿林冠蒸发速率(Er)。研究结果表明，SF、FF和BF的湿林冠蒸发量(E)分别为44．51mm、88．51mm和57．8mm，分别占总降雨量的9．2％、16．6％和10．2％。与SF和BF相比，FF具有最高的月平均Er和蒸发比例。SF、FF和BF的平均Er分别为0．097mm／h(变化范围：0．028-0．487mm／h)、0．242mm／h(变化范围：0．068～0．711mm／h)和0．149mm／h(0．060～0．576mm／h)。最高和最低的月平均Er分别在6月(SF、FF和BF分别为0．120mm／h、0．317mm／h和0．169mm／h)和10月(SF、FF和BF分别为0．083mm／h、0．187mm／h和0．101mm／h)。8：00至16：00期间的平均点Er显著高于0：00至8：00以及16：00至0：00期间的平均Er。Er显著的日变化和月变化主要归因于林冠上方的太阳辐射、空气温度和相对湿度的变化。     

青海湖南岸全新世黄土地球化学特征及气候环境意义

位于青藏高原东北部的青海湖是我国最大的内陆湖泊，通过湖相沉积进行湖区全新世环境演变研究已取得诸多成果。作者选择青海湖南岸黑马河有绝对年代控制的全新世黄土剖面，利用CaCO2、CaO、MgO和Sr元素组分以及氧、碳同位素等较为可靠的地球化学指标，尝试进行了湖区全新世黄土的分层，探讨了黄土堆积过程中的气候环境演变。结果表明，青海湖南岸的黄土按成土作用强度的不同可分为两层：上部为成土化较弱的黄土层；下部为成土化较高的古土壤层，其仍可进一步分为两个亚层。全新世湖区气候环境的波动在地球化学分布特征中有较强表现。     

中国兴凯湖北岸平原晚全新世花粉记录及泥炭沼泽形成

通过兴凯湖北岸平原泥炭剖面高分辩率花粉分析研究，对晚全新世花粉划分4个组合带。XKH-4组合时期(1857～1746aB．P．)为沼泽发育前期，这一时期花粉浓度小，陆生草本植物占优势，气候干冷。XKH-3组合时期(1746～1287aB．P．)为沼泽发育早期，这一时期花粉浓度较大，且水生植物花粉含量为剖面最高，喜温落叶阔叶植物大发展时期，气候温和湿润。XKH-2组合时期(1287～602aB．P．)为沼泽发育中期，这一时期花粉浓度最小，但以陆生草本植物为主，木本植物为辅，水生植物急剧减少，针叶植物出现两次高峰，气候向冷干方向发展。XKH-1组合时期(602aB．P．至今)为沼泽发育盛期，这一时期花粉浓度最大，陆生草本植物大发展时期，气候波动较大。