25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

Historic Dead Sea Level Fluctuations Calibrated with Geological and Archaeological Evidence

The Dead Sea, the Holocene terminal lake of the Jordan River catchment, has fluctuated during its history in response to climatic change. Biblical records, calibrated by radiocarbon-dated geological and archaeological evidence, reinforce and add detail to the chronology of the lake-level fluctuations. There are three historically documented phases of the Dead Sea in the Biblical record: low lake levels ca. 2000–1500 B.C.E. (before common era); high lake levels ca. 1500–1200 B.C.E.; and low lake levels between ca. 1000 and 700 B.C.E. The Biblical evidence indicates that during the dry periods the southern basin of the Dead Sea was completely dry, a fact that was not clear from the geological and archaeological data alone.     

Counting chronology and climate records with about 1000 annual layers of a Holocene stalagmite from the Water Cave in Liaoning Province, China

One active stalagmite from the Water Cave in Liaoning Province contains growth layers of three sizes. Based on thermal ionization mass spectrometry 230Th dating, we found that middle size layers are annual layers, with each middle layer consisting of one narrow dark layer and a wide bright layer. The small layers within middle layers are sub-annual layers and the large layers are multi-year layers. Based on the layer-counting method, we established a high-resolution time scale for layer thickness. Our results reveal two dramatic century-scale climate cycles over the past 1000 years in this region.     

Hydration and refractive indices of Holocene tephra glass in Hokkaido, Northern Japan

Refractive indices of incompletely hydrated tephra glasses vary widely. Thus, glass refractive index is not a practical indicator for identifying Holocene tephras. Hydration near the surface of tephra glass shards can be removed by either hydrofluoric acid treatment or annealing for 12 h at 400°C. The annealing procedure is a particularly reliable and simple way to dehydrate tephra glasses. Standard deviations (s) of refractive indices for glasses after 12 h annealing are small (s=0.0014–0.0018), in contrast with untreated glasses (s=0.0034–0.0405). The refractive indices of dehydrated tephra glasses are 0.006–0.014 lower than those of the untreated (hydrated) glasses. Using the 400°C 12-h annealing procedure, values for the refractive indices of eight Holocene tephras in Hokkaido were obtained. These refractive indices are useful indicators for identification and correlation of Holocene tephras.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

拱坝非线性地震反应分析

本文根据一致粘弹性模型的概念，引入应变率的影响，将混凝土静态William-Warnke三参数模型改造成一致粘塑性William-Warnke三参数本构模型，并用这个模型对某高拱坝进行了非线性地震响应分析，与线弹性模型和应变率无关的William-Warnke三参数模型的结果进行了比较，初步探讨了应变率对拱坝地震反应的影响。     

中全新世以来黑龙江同江地区的孢粉组合与植被、气候演化

对黑龙江省同江县96－QP剖面从下至上划分4个孢粉组合带：1是以蒙古栎－桦属－蒿属－苔草属－木本科－水龙骨科为主组合带；2是以蒿属－莎草科－禾本科－桦属－栎属为主组合带；3是以桦属－蒙古栎松属－蒿属－莎草科－禾本科为主组合带；4是以松属－桦属－蒙古栎－蒿属－苔草属为主组合带。这4个孢粉组合带清楚地反映了古植被，古气候演替4个阶段；依次为温性落叶阔叶林－针，阔叶混交林→以落叶阔叶树稍多的针、阔叶混交林－草原→以松占优势的针、阔叶混交林。其气候变化是温暖湿润－温和略干－温和略湿－温凉湿润。     

甘青地区中晚全新世植被变化与人类活动

史前时期人类对环境的影响是近几年来国际研究的热点。在甘青地区，全新世的孢粉资料比较多。但在中晚全新世，该区人类对环境的影响作用及其程度仍不清楚，许多孢粉分析资料中并没有充分考虑人类活动的影响。本文选取孢粉分辨率较高、代表性较好的青海湖、兰州、秦安大地湾三地的资料，着重研究了其中乔木成分的变化。分析发现，孢粉组合中乔木成分的变化与气候变化的趋势并不一致。通过对考古及历史资料的分析，笔者认为，该区的植被很早就受到人类活动的影响。自全新世中期，本区植被中的乔木成分波动下降。5000－3000a BP期间，史前农业对植被的影响较大。3000－2000a BP期间，植被略有恢复。2000a BP以后，人为影响加剧，植被中乔木成分迅速下降。研究者认为，依赖孢粉资料重建中晚全新世的气候变化历史应当慎重。     

Palaeolimnology of Lake Piene-Kuuppalanlampi (Kurkijoki, Karelian Republic, Russia): isolation history, lake ecosystem development and long-term agricultural impact

The post-glacial history of Lake Pieni-Kuuppalanlampi, western Lake Ladoga region, was studied by means of stratigraphic pollen and diatom analyses. Diatoms were analysed to track the isolation history of the basin and the limnological effects of the early land-use phases indicated by pollen analysis. Chrysophycean stomatocysts and Isoëtes spores were also employed in the limnological reconstructions. Sediment dating was provided by six conventional radiocarbon dates.The lower part of the 370-cm long sediment sequence represents early Holocene, large lake conditions: the (freshwater) Yoldia and Ancylus stages of the Baltic basin, with a short-term lagoonal or isolation phase at the end of Yoldia. The basin was isolated due to Ancylus lake regression at 9785 cal B.P. For the small-lake sequence (0–250 cm) we used diatom inferences (WA-method) for hindcasting water chemistry. The post-isolation limnology of Pieni-Kuuppalanlampi reflects the development of vegetation on its small hill-top catchment. In its early development, the lake was mesotrophic, but became more acidic (pH about 6) and oligotrophic after the decline of temperate hardwood trees and the spread of spruce to the area after around 5000 B.P. The lake ecosystem appears to have reacted sensitively to agricultural land-use in the catchment from AD 400–800 onwards: inferred total phosphorus levels and pH both rise during these periods.