蚀变粗面岩中再平衡结构黑云母的电子探针分析

黑云母的化学成分中蕴含着重要的成因信息,对具有交代结构的黑云母进行微区成分分析,能够精细反映交代蚀变过程中元素迁移情况,为解决矿床形成机制方面的科学问题提供矿物学证据。本文以北大巴山平利地区蚀变粗面岩中具有再平衡结构的黑云母斑晶为研究对象,进行电子探针面扫描和剖面成分分析。结果表明,斑晶内部为岩浆成因黑云母,边缘为"扩散-反应"过程所致的再平衡成因黑云母。斑晶边缘与内部相比,TiO_2含量由平均5.78%降至2.22%,表明在交代蚀变过程中黑云母中Ti等高场强元素被淋滤出进入流体;而CaO含量由平均0.06%升至0.14%,F含量由平均0.60%升至0.80%,指示蚀变流体内富含Ca、F等组分。本研究揭示了粗面岩中铌矿床的形成与热液作用关系密切,成矿流体中Ca、F等组分在铌元素的迁移及富集过程中具有重要作用。     

‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.     

Effects of the peat acid digestion protocol on geochemically and morphologically diverse tephra deposits

Tephra shards for electron probe microanalysis are most efficiently extracted from peat using acid digestion, which removes organic material that hinders density separation methods. However, strong acids are known to alter glass chemical compositions, and several studies have examined how acid digestion affects rhyolitic volcanic glass. The focus on rhyolitic tephra in these studies leaves considerable uncertainty, as the dissolution rates of natural glasses (including tephra) are determined by the chemical composition and surface area/volume ratio, both of which vary in tephra deposits. Here, we use duplicate samples of basaltic, trachydacitic and rhyolitic tephra to examine physical and geochemical alteration following acid digestion. Scanning electron microscope imagery reveals no discernible degradation of glass surfaces, and electron probe microanalysis results from duplicate samples are statistically indistinguishable. These findings suggest the acid digestion protocol for organic peats does not significantly alter glass geochemistry regardless of shard morphologies or geochemical compositions.     

不同NeQuick电离层模型参数的应用精度分析

Galileo采用NeQuick作为全球广播电离层模型,其实际应用中以有效电离水平因子Az代替太阳活动指数作为NeQuick的输入参数,并利用二次多项式拟合得到广播星历中播发的3个电离层参数。本文在总结和讨论NeQuick模型参数估计方法及其变化特征的基础上,分别以全球电离层格网、GPS基准站及JASON-2测高卫星提供的电离层TEC为参考,分析不同NeQuick模型参数(包括以太阳活动参数F10.7为输入的NeQuick2、以本文解算参数为输入的NeQuickC和以Galileo广播电离层参数为输入的NeQuickG)在全球大陆及海洋地区的应用精度,并与GPS广播的Klobuchar模型对比。结果表明,NeQuickG在全球范围内的修正精度为54.2%~65.8%,NeQuickC的修正精度为71.1%~74.2%,NeQuick2的修正精度与NeQuickG相当,略优于GPS广播星历中播发的Klobuchar模型。     

太阳活动高峰年山东区域电离层时空变化研究

2012年为太阳活动高峰年份,为了研究太阳活动高年区域电离层的变化特征,该文选取了山东区域内的SDCORS站点,构建了山东区域垂直电子含量(VTEC)球谐格网模型,对该年山东区域电离层时空变化规律进行分析。实验研究表明,在空间变化上山东区域电离层表现出较强的纬度相关性,出现了明显的分层现象。同时给出了山东电离层在时间上呈现出的时段变化、日变化、月变化、季节变化,发现VTEC受太阳活动影响较大,除了存在明显的单峰和双峰结构外,该年还发生了半年度异常现象。     

极光粒子沉降研究:谱形式及其在极区大气中的传输

分析了近年来南极地区极光沉降粒子的卫星、火箭、地面观测和研究结果,分别给出了极光椭圆区、极盖区、南大西洋异常区和极尖／极隙区粒子沉降的形式来源和特点。并根据磁尾研究的新进展,提出极光粒子沉降谱存在另外两种形式谱：（１）κ分布谱;（２）κ分布加上一个或多个脉冲谱,这两种谱来源于磁尾中性片区（绝热区非绝热区）。南极不同的区域,极光粒子有不同的沉降特点。这些沉降对极区电离层产生极大的影响。根据带电粒子在磁化大气中运动的Ｆｏｋｋｅｒ Ｐｌａｎｋ 方程,利用带电粒子在大气中传输的电离理论,导出极光粒子谱在极区大气中传播的解析表达式,对各种极光粒子谱在极区中的演化规律加以分析,并以此来解释在南极地区探测到的不同高度的极光电子谱的演化     

Microanalysis of Fe3+/ΣFe in oxide and silicate minerals by investigation of electron energy-loss near-edge structures (ELNES) at the Fe M 2,3 edge

The Fe M _2,3-edge spectra of solid solutions of garnets (almandine-skiagite Fe₃(Al_1–xFe_x)₂[SiO₄]₃ and andradite-skiagite (Fe_1–xCa_x)₃Fe₂[SiO₄]₃), pyroxenes (acmite-hedenbergite (Ca_1–xNa_x)(Fe²⁺ _1−xFe³⁺ _x)Si₂O₆), and spinels (magnetite-hercynite Fe(Al_1–xFe_x)₂O₄) have been measured using the technique of parallel electron energy-loss spectroscopy (EELS) conducted in a transmission electron microscope (TEM). The Fe M _2,3 electron energy-loss near-edge structures (ELNES) of the minerals exhibit a characteristic peak located at 4.2 eV and 2.2 eV for trivalent and divalent iron, respectively, prior to the main maximum at about 57 eV. The intensity and energy of the pre-edge feature varies depending on Fe³⁺/ΣFe. We demonstrate a new quantitative method to extract the ferrous/ferric ratio in minerals. A systematic relationship between Fe³⁺/ΣFe and the integral intensity ratio of the main maximum and the pre-edge peak of the Fe M _2,3 edge is observed. Since the partial cross sections of the Fe M _2,3 edges are some orders of magnitude higher than those of the Fe L _2,3 edges, the Fe M _2,3 edges are interesting for valence-specific imaging of Fe. The possibility of iron valence-specific imaging is illustrated by Fe M _2,3-ELNES investigations with high lateral resolution from a sample of ilmenite containing hematite exsolution lamellae that shows different edge shapes consistent with variations in the Fe³⁺/ΣFe ratio over distances on the order of 100 nm. Received: 14 April 1998 / Revised, accepted: 8 March 1999     

浙江新昌地幔岩捕虏体中的硫化物包裹体初步研究

浙江新昌一带晚第三纪碱性玄武岩中地幔岩（二辉橄榄岩）捕虏体内存在大量硫化物熔体包裹体。电子探针分析表明,硫化物相成分主要为镍黄铁矿,次为磁共铁矿。硫化物包裹体的Ｎｉ／Ｆｅ值与寄主地幔岩的橄榄石含量呈正相关。同一包裹体的硫化物相成分不均一,自中心至边缘硫化物的Ｎｉ／Ｆｅ、（Ｆｅ＋Ｎｉ）／Ｓ值和Ｎｉ呈均呈增加趋势。通过与中国汉诺坝、德国ＷｅｓｔＥｉｆｅｌ东欧Ｎｏｇｒａｄ－Ｇｏｍｏｒ地区资料的综合分析,     

Influence of environments of coal deposition on phosphorous accumulation in a high latitude, northern Alaska, coal seam

Although phosphorus is a very important biogenic element, its concentration in coal is generally low. Phosphorus (P) concentrations typically range from 0.001% to 0.229% in raw coals of the contiguous 48 states [Glick, D.C., Davis, A., 1984. Variability in the inorganic content of United States coals—a multivariate statistical study of final report, Part 10 (DOE-30013-Flo) to the US Dept. of Energy under contract no. DE-AC22-80PC 30013, 404 pp.]. Some Alaskan coal seams contain horizons that are unusually high in phosphorus. The present paper focuses on a bituminous coal from northern Alaska, where 0.15 m subsections of this coal seam have shown high phosphorous in certain subsections. In order to investigate the lateral extent of such high phosphorous bands in coal, the authors obtained three drill cores up to 3 km apart from the coal seam. A detailed investigation of the cores was undertaken to determine the nature and mode of occurrence of phosphorous minerals. Maceral composition allowed interpretation of environments of coal deposition. Acid-extractable phosphorous analysis of the subsections identified the high phosphorous horizons. Electron microprobe analyses identified the phosphorous mineral as crandallite. Correlation of high phosphorous intervals with corresponding environments of deposition suggests that phosphorous precipitation is promoted by an oxidizing environment with a lowered water table during the peat stage. A study of thin sections from high phosphorous samples showed that crandallite is associated with structured vitrinite and as cell fillings in fusinite. The study confirms the potential for using high phosphorous horizons for the correlation of coal seams, as noted in previous work by the authors (Rao and Walsh, 1997). A high phosphorous horizon is found at 0.45 m above the bottom of the seam in all of the drill holes, indicating a uniformity of the coal forming environment and the availability of crandallite constituent elements over the entire 3 km. The uniformity of high phosphorous concentrations through the top 2 m of the three drill holes also shows a distinct correlation.     

不同初始扰动对电离层扩展F影响的数值模拟

重力波、中性风场、电场是激发电离层扩展F的主要影响因子,本文基于中低纬电离层扩展F发展的物理模型,通过电场强度、背景风场对扩展F影响作用的分析和经验对比,首先验证了模型的有效性,后借助该模型数值模拟了给定背景环境下三种尺度初始电子密度扰动条件下扩展F的发展情况,同时研究了利用化学物质释放实现一定尺度扰动,进而激发扩展F的过程.结果表明,较强的背景电场、东向风场有利于扩展F的形成和抬升,与经验结论相吻合;电离层从被作用初始扰动到激发扩展F的过程中存在拐点效应,拐点之后扩展F被激发形成并且抬升迅速,同时短波长扰动相对于长波长扰动更有利于扩展F的激发和发展;化学物质H_2O释放通过耗散电子密度,形成了一定尺度扰动并诱发了扩展F的形成,该方法可作为一种人工激发扩展F的探索手段.