高温气相色谱与石油分析

气相色谱最高柱温主要受柱系统技术水平的限制。使用耐高温如４００℃以上的固定相,改善配套部件的某些性能,可以将传统气相色谱的柱温提高到３２５℃以上。高温气相色谱的应用将为高分子量烃类研究提供重要的分离鉴定手段。综合国内外研究动态论述了高温气相色谱在原油的模拟蒸馏、高蜡原油分析及石蜡产品表征等几方面的研究现状和发展方向。     

Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

东天山喀尔里克山北坡淖毛湖盆地土壤粒度分布特征及成因

对东天山喀尔里克山北坡-淖毛湖盆地不同类型土壤的粒度进行分析.结果表明:研究区土壤主要由粉粒和砂粒组成,从喀尔里克山北坡、中部地区到淖毛湖盆地,土壤粒度平均值逐渐变大,颗粒分选性差,偏度多属极正偏或正偏,峰态集中在宽、中等和窄3个等级,表明其成土母质较粗、来源相对复杂.土壤的粒度参数Mz、σ、SK和KG值很好地表征了不同土地类型和植被类型及盖度对土壤粒度特征的影响.土壤粒度分维值呈现出随海拔降低逐渐减小的趋势,并且分维值与粘粒含量呈正相关关系.喀尔里克山北坡土壤中粘粒的含量高于中部地区和淖毛湖盆地的土壤,反映出不同地区土壤母质来源和沉积环境的差异.不同地带土壤概率累积曲线的空间变化及综合参数特征表现出地形和气候对颗粒运动形式有一定影响,并且不同地区土壤在成因上既有区别又有联系.     

高精度磁测在维西拉嘎洛铁矿勘查中的应用

测区引起磁异常的有磁铁矿(化)体和玄武岩,二者之间的磁性差异很大,为磁法勘探寻找磁铁矿奠定物性基础。通过磁法勘探的野外作业和室内数据整理分析,并经异常推断解释圈出矿体5个,并经坑探验证有效。     

Intrusion and its implication for subsidence: A case from the Baiyun Sag, on the northern margin of the South China Sea

We develop a series of simple numerical models to explain the anomalous subsidence and deposition phenomena on the northern continental margin of the South China Sea, in particular in the Baiyun Sag. The results suggest that a short-period high rate deposition of around 17 Ma is related to a rapid subsidence event, which may be due to episodic emplacement of a dense intrusion. Necking and gravity models indicate that in the basement of the Baiyun Sag, there is a dense zone that is 100–200 kg/m³ more dense than the surrounding country rock. Considering its high magnetic intensity and regional igneous activity, the dense zone is thought to be related to a phase of basalt intrusion that may have taken place around 17 Ma. Thermal and subsidence models indicate that a hot denser intrusion can cause significant subsidence immediately after the intrusion. The subsidence rate then slows down with cooling, thus becoming consistent with the observed subsidence curves at around 17 Ma. The results also indicate that the lithospheric strength under the Baiyun Sag is negligible, and that the high-velocity layer in the lowermost crust may be not an original part of the pre-rift crust. Instead, it is thought to be underplated intrusion emplaced at around 30 Ma when the continental margin broke up.     

基于国际先进项目管理理念的设计项目管理系统应用

设计项目管理系统的应用以国际先进项目管理理念为理论依据,以项目管理九大知识体系、五大基本过程以及赢得值（EV）分析为理论基础,将“成本、质量、时间”三大项目管理核心要素进行有机结合,实现融合了“流程管理、项目管理、协同设计、知识管理、ISO质量管理”五大方面内容的协同设计管理平台,为企业搭建起具有真正意义上的现代项目管理信息系统。     

青藏高原前期冬春季地面热源与我国夏季降水关系的初步分析

首先对青藏高原地表热通量再分析资料与自动气象站(AWS)实测资料进行对比, 结果表明: 相对于美国国家环境预报中心和国家大气中心20世纪90年代研制的NCEP/NCAR(Kalnay 等1996)和NCEP/DOE (Kanamitsu 等2002) 再分析资料, ECMWF(Uppala 等2004)资料在高原地区的地表热通量具有较好的代表性。进一步利用奇异值分解(SVD)方法分析了ECMWF资料反映的高原地面热源与我国夏季降水的关系, 发现前期青藏高原主体的冬季地面热源与长江中下游地区夏季降水量呈负相关, 与华北和东南沿海地区的夏季降水量呈正相关。而长江中下游地区夏季降水量还与春季高原南部的地面热源存在负相关、与高原北部的地面热源存在正相关。高原冬、春季地面热源场的变化是影响我国夏季降水的重要因子。     

SVD方法在气象场诊断分析中的普适性

本文首次从理论上推导证明两个气象场的奇异值分解（ＳＶＤ）在气象场时空分布耦合信号的诊断分析中具有普适性。结果表明，两个场的ＳＶＤ求解准则不同于典型相关分析（ＣＣＡ），且ＣＣＡ模型可视为ＳＶＤ之特例，尤其当各个场经ＰＣＡ滤波后，其ＣＣＡ完全与ＳＶＤ等价。ＳＶＤ分析的结果不但可完全代替ＣＣＡ，且计算更简便，所得耦合信号的物理解释更清晰，特别适合于大尺度气象场的遥相关型研究。     

海冰非均匀条件下大气环流模式和海洋环流模式耦合的实现

通过采用一种较好地考虑了海气通量交换对下垫面特征非线性依赖的通量计算方案,利用较成熟的逐日通量距平耦合方案实现了次网格尺度海冰非均匀条件下一个全球大气环流模式和一个全球海洋环流模式在高纬地区的耦合,并完成了一个50年的长期积分。模拟结果表明,通量计算方案中水道的作用是合理的,耦合模式能较好地模拟出北半球高纬海冰的主要地理分布特征,但夏季北冰洋内部靠近欧亚大陆部分边缘海区海冰密集度偏大。     

Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.