The Effects of Different HITRAN Versions on Calculated Long-Wave Radiation and Uncertainty Evaluation

Four editions of the High Resolution Transmission (HITRAN) databases (HITRAN96, HITRAN2K, HITRAN04, and HITRAN08) are compared by using a line-by-line (LBL) radiative model in the long-wave calculation for six typical atmospheres. The results show that differences in downward radiative fluxes between HITRAN96 and HITRAN08 at the surface can reach a maximum of 1.70 W m 2 for tropical atmospheres. The largest difference in heating rate between HITRAN96 and HITRAN08 can reach 0.1 K day 1 for midlatitude summer atmosphere. Uncertainties caused by line intensity and air-broadened halfwidths are also evaluated in this work using the uncertainty codes given in HITRAN08. The uncertainty is found to be 1.92 W m 2 for upward fluxes at the top of the atmosphere (TOA) and 1.97 W m 2 for downward fluxes at the surface. The largest heating rate caused by the uncertainty of line intensity and air-broadened half-width can reach 0.5 K day 1 . The differences in optical depths between 1300 and 1700 cm 1 caused by different HITRAN versions are larger than those caused by the uncertainties in intensity and air-broadened half-width. This paper suggests that there is inaccurate representation of line parameters over some spectral ranges in HITRAN and more attention should be paid to these ranges in fields such as remote sensing.     

南亚高压的南北偏移与我国夏季降水的关系

该文定义了一个能较好反映南亚高压南北偏移的指数,并发现该指数与我国夏季降水,尤其是华北和长江流域的降水,无论在年际变化上还是长期趋势上都具有十分显著的相关关系。南亚高压位置偏北时,在我国东部至日本上空存在一个显著的异常反气旋,其中心自上而下向南倾斜,在高层给华北地区带来辐散,在低层使得气流在长江流域辐散,在华北地区辐合,造成华北地区降水偏多,长江流域降水偏少。同时,南亚高压偏北对应着高层西风急流以及中层西太平洋副热带高压偏北,使得我国整个雨带偏北。此外,通过与海温的相关分析发现,南亚高压的长期偏南趋势可能受到印度洋增暖的直接影响。南北偏移指数可作为预测我国夏季区域降水的重要指标,在气候预测业务中有一定的应用价值。     

A waveguide-based flexible CO2-laser heating system for diamond-anvil cell applications

Fiber-based laser heating systems offer high flexibility and are increasingly used in high-pressure/high-temperature research. Previous fiber-based laser heating systems were based on lasers delivering radiation with 1-μm wavelength that show unfavorable heating characteristics for many sample materials. We report on the development and first experiments of a waveguide (fiber)-based CO₂-laser heating system that can be used in a flexible manner for high-temperature research and for high-pressure/temperature experiments when combined with diamond-anvil cells. The waveguide-based CO₂-laser heating system allows convenient heating of optically transparent samples without the need for adding an additional laser absorber. In a pilot experiment, the flexible heating system has been installed on a Brillouin scattering system to measure high-temperature sound-wave velocities in single-crystal MgO. The waveguide-based CO₂-laser heating system offers perspectives for a variety of scientific applications, most importantly those that require the use of synchrotron facilities where space is limited and flexible solutions are required.     

High-pressure yield strength of rocksalt structures using quartz Raman piezometry

The Raman frequencies of quartz are used to evaluate deviatoric stresses in rocksalt-structure media in diamond-anvil cell experiments to pressures up to 20 GPa. The piezospectroscopic effect in quartz is modeled by first-principles calculations. Non-hydrostatic stresses measured in halogen salts give yield strength estimates of 3 GPa in the B1 structure (NaCl), and 4.5 GPa for the B2 structure (KCl and KBr). Raman measurements in MgO show that the yield strength is reached at around 6 ± 1 GPa. Measurements on quartz alone indicate similar yield strength. The estimated yield strength in MgO is thus likely a lower bound, in consistency with former radial X-ray diffraction measurements that gave a yield strength of 8 ± 1 GPa, and lower-pressure large-volume press experiments indicating a yield strength of 6 GPa at 5 GPa. Former values of the yield strength below 2 GPa determined by pressure gradient measurements were underestimated due to unverified assumptions in boundary conditions. The yield strength increases with increasing coordination of ionic solids, likely contributing to increase viscosity at phase transitions near the upper–lower mantle boundary.     

Bulk modulus of Fe-rich olivines corrected for non-hydrostaticity

In situ X-ray diffraction was used to measure the isothermal bulk modulus at room conditions (K_T0) of synthetic olivines with different iron contents. The chemical formulae of the olivine samples were ${({\mathrm{Fe}}_x,{\mathrm{Mg}}_{1?x})}_2\mathrm{Si}{\mathrm{O}}_4$ with x = 0.45; 0.64; 0.82; 1, with 1% standard deviation (referenced as Fa45, Fa64, Fa82 and Fa100, respectively). All experiments were performed in the multi-anvil apparatus installed at NSLS beamline X17B2, to pressures up to about 7 GPa. Unit-cell volumes under hydrostatic conditions and differential stresses present in the samples were calculated using the method developed by Singh et al. (1998), and pressures measured using NaCl as a standard were then corrected for these stresses. Using a second-order Birch–Murnaghan equation of state, we obtained the isothermal bulk modulus of each composition: $K_{T0}^{\mathrm{Fa45}}=131.4\pm 2.6$ GPa, $K_{T0}^{\mathrm{Fa64}}=132.1\pm 3.1$ GPa, $K_{T0}^{\mathrm{Fa82}}=136.3\pm 1.7$ GPa and $K_{T0}^{\mathrm{Fa100}}=134.8\pm 1.4$ GPa. These values combined with data available in the literature show that the K_T0 of Fe-rich olivines increases very slowly with the Fe content, but possibly not in a simple linear trend.     

利用TBB资料对西太平洋副热带高压特征的分析和描述

利用卫星TBB资料和500 hPa位势高度场资料, 分析了西太平洋副热带高压(下称西太副高)的北进及南撤特征。结果表明: 西太平洋副热带地区的TBB场呈带状分布, >275K的TBB区随季节的变化从1月至12月表现为先北跳又南落之势, 它与西太副高的北跳和南落同步, 其大值区可以表征西太副高的范围。西太副高脊线(500 hPa上的u=0 线)与TBB大值区轴线的走向基本一致。不同季节可以不同的TBB值来描述西太副高。同时指出, 以TBB大值区所描述的西太副高与雨区的配置较588 gpdm等高线与雨区的配置要好, 并且可以避免588 gpdm等高线所产生的假象。另外, 每3 h TBB场的分析可为暴雨的逐3 h预报提供参考。     

青藏高原感热与黄土高原春季降水异常关系研究

利用1961～2000年黄土高原56站的春季降水、气温资料,用SVD方法分析了其与青藏高原感热场的关系。结果表明,降水量与青藏高原感热场的前两模态代表了两场间的主要耦合特征;上年冬季和秋季青藏高原感热场的异常通过影响大气环流,能够导致次年黄土高原春季降水异常;青藏高原感热对黄土高原西部和南部、北部的部分地区影响较显著,而对陕西北部、山西中部影响不明显。前期高原感热场SVD第一、二模态的变化,可以作为黄土高原春季降水异常的预测信号。     

DFT study of migration enthalpies in MgSiO<Subscript>3</Subscript> perovskite

The effect of pressure on ionic diffusion in orthorhombic MgSiO₃ perovskite has been investigated using density functional theory. An intensive investigation of possible silicon pathways revealed new positions of the saddle-points and an enthalpy of migration at 26.2 GPa of 4.7 eV that is in fair agreement with the experimental values of about 3.5 eV at 25 GPa. This is much lower than found in previous studies (~9 eV) and removes the need to explain silicon diffusion by a complicated process involving coupled oxygen vacancies, as has been previously proposed. Our migration enthalpies for oxygen and magnesium are in excellent agreement with experiments. We find that oxygen diffusion occurs via a chain of several inequivalent jumps along the octahedron edges, and that magnesium occurs via two inequivalent [110] jumps and one [001] jump. We also present activation volumes for all three species at 25 and 135 GPa.     

羌塘中部高压变质带的退变质作用及其构造侵位

羌塘中部的高压变质带主要由榴辉岩、石榴石白云母片岩和蓝片岩等组成,它们在遭受高压变质作用之后折返,构造侵位于晚古生代展金组地层中,二者以韧性变形带为接触边界.本文以高压变质带中的榴辉岩和韧性变形带为研究对象,讨论了高压变质带折返过程中的退变质作用特征及折返时代.研究表明,榴辉岩在高峰期变质作用之后的折返过程中经历了由榴辉岩相→蓝片岩相→绿帘角闪岩相的退变质作用演化过程;在高压变质带构造侵位过程形成的韧性变形带中,白云母石英片岩的白云母40Ar-39Ar坪年龄为219±2Ma.高压变质带在219Ma左右构造侵位于展金组地层中,并于214Ma之前最终抬升出露地表.     

南亚高压季节性变化与甘肃省春季和初夏降水关系初探

通过对南亚高压的季节性变化与甘肃省春季第一场≥10mm的区域性降水即第一场透雨出现时间和初夏转入多雨期的统计分析,初步揭示了南亚高压在季节性变化过程中及最终在青藏高原上空建立与甘肃省特别是甘肃河东地区春季第一场透雨及转入多雨期的相关关系。分析结果表明,南亚高压在季节性变化过程中登上中南半岛与甘肃省河东地区春季第一场透雨的出现具有显著关系,南亚高压在青藏高原上空建立与甘肃省初夏转入多雨期同样具有显著关系。因此。准确掌握南亚高压的季节性变化及登上高原的日期。不论对于准确预报出春季第一场透雨,还是转入多雨期,都有着重要的参考和指导意义。