氦光泵磁力仪探头设计和环路数字化研究

磁法勘探是一种常用的地球物理勘探方法,其中光泵磁力仪是国内外应用于航空和地面磁法测量最多的磁力仪器.为满足深部矿产资源勘查对高精度磁测设备的需求,本文开展了低噪声、宽量程的高性能数字氦光泵磁力仪关键技术研究,主要包括磁传感器探头优化设计和新型数字化环路设计两方面.首先通过深入分析影响氦光泵磁力仪灵敏度的主要决定因素,对磁传感器关键部件氦灯、氦室进行小型化技术研究,解决高性能氦泵源和原子气室等关键件的制作工艺,提高氦灯效率和氦吸收室的磁共振信号输出强度,制作出高性能、低噪声的小型化氦光泵探头.然后,针对常规模拟跟踪环路的局限性,通过数字化技术研究,采用FPGA、DSP、DDS、环路跟踪算法和信号处理软件等技术构成新型数字环路,弥补现有基于模拟跟踪环路技术的模拟式氦光泵磁力仪的不足,该数字环路降低了氦光泵磁力仪的电路噪声,增强了抗电磁干扰能力,并扩展了磁力仪的量程.本文通过小型探头和数字环路的技术设计,研制出高精度大量程的地面数字氦光泵磁力仪,并用于第三方测试.通过第三方测试证明：实测仪器的静态噪声小于4 pT,磁场测量范围为20000~100000 nT,梯度容限大于10000 nT/m.

     

中国大陆含油气盆地的氦同位素组成及大地热流密度

根据天然气中氦同位素组成,讨论了中国大陆主要含油气盆地氦同位素地球化学特征与大地热流密度。不同地区425个~3He/~4He 值表明中国含油气盆地天然气的氦同位素组成变化范围较大,为4.0×10~(-9)—7.21×10~(-6),在统计直方图上呈现三个峰值:1.5×10~(-8),3.0×10~(-7)和1.5×10~(-6)。中国东部大陆裂谷系中、新生代盆地内天然气的~3He/~4He 值分布范围为1.02×10~(-7)—7.21×10~(-6),50%以上大于大气的值(1.4×10~(-6));其他地区含油气盆地天然气的~3He/~4He 值分布范围为4.0×10~(-9)—7.01×10~(-7),全部小于大气的~3He/~4He 值。根据天然气中~3He/~4He 值计算的大地热流密度值分布在30—82mW/m~2 之间。利用~3He/~4He 值计算的大地热流密度值与用其他方法测得的值相一致,在中国大陆水平方向上呈现"东高西低"的变化趋势。     

A social–ecological systems analysis of impediments to delivery of the Aichi 2020 Targets and potentially more effective pathways to the conservation of biodiversity

The Aichi 2020 Targets, under the Convention on Biological Diversity (CBD), aim to halt the loss of biodiversity by 2020, in order to ensure that ecosystems continue to provide essential services. Here we apply a social–ecological systems analysis to provide insight into the diverse system interactions that pose impediments to delivery of the Aichi Targets. We applied an analytical framework of pair-wise exchanges along six axes between the social, economic, environmental and political loci of the global social–ecological system. The analysis identified that many impediments result from partial decoupling in the system through phenomena including delayed feedbacks and insufficient information flows. It suggests 15 of the Aichi Targets are unlikely to be delivered; 3 are likely to be delivered in part; and 2 in full. We considered how interventions at leverage points may overcome the impediments, and compared these to actions included within the Implementation Decision for the Aichi Targets, to find gaps. These new leverage points to fill identified gaps involve many aspects of system re-coupling: co-production of knowledge and more equitable food systems governance (environmental–social axis); support for social change movements (social–political axis); an appropriate financial target for biodiversity conservation investment, with a clear means of implementation such as a currency transaction tax (economic–political axis); and co-governance of natural resources (environmental–political axis). The recently released Global Biodiversity Outlook 4 shows that 18 of the 20 Aichi Targets are tracking in accordance with our analysis; and that current efforts are unlikely to result in an improvement in the base state of biodiversity by 2020, confirming some of our results. We argue that attention to the interactions within, and the partial decoupling of, the global social–ecological system provides new insights, and is worthy of further attention both for delivery of the Aichi Targets and for guiding longer term actions for the conservation of biodiversity.     

解决语义悖论的振荡周期函数模型--一种对语义悖论的可能解释

通过对悖论性命题的仔细分析，发现这些命题的真值会发生周期性的变化。因此，将振荡周期函数纳入语形学，以便从形式上揭示悖论性命题真假周期性过渡这种对立统一结构，再纳入动态蒙太格赋予振荡函数里的变元以意义，这样就从语形、语义、语用的角度构建了一种动态语义模型，从而达到消解语义悖论的目的。     

Diffusion of helium in zircon and apatite

Diffusion of helium has been characterized in natural zircon and apatite. Polished slabs of zircon and apatite, oriented either normal or parallel to c were implanted with 100 keV ³He at a dose of 5 × 10^{15 3} He/cm². Diffusion experiments on implanted zircon and apatite were run in Pt capsules in 1-atm furnaces. ³He distributions following experiments were measured with Nuclear Reaction Analysis using the reaction ³He(d,p)⁴He. For diffusion in zircon we obtain the following Arrhenius relations:

Although activation energies for diffusion normal and parallel to c are comparable, there is marked diffusional anisotropy, with diffusion parallel to c nearly 2 orders of magnitude faster than transport normal to c. These diffusivities bracket the range of values determined for He diffusion in zircon in bulk-release experiments, although the role of anisotropy could not be directly evaluated in those measurements.In apatite, the following Arrhenius relation was obtained over the temperature range of 148–449 °C for diffusion normal to c:

In contrast to zircon, apatite shows little evidence of anisotropy. He diffusivities obtained in this study fall about an order of magnitude lower than diffusivities measured through bulk release of He through step-heating, and within an order of magnitude of determinations where ion implantation was used to introduce helium and He distributions measured with elastic recoil detection.Since the diffusion of He in zircon exhibits such pronounced anisotropy, helium diffusional loss and closure cannot be modeled with simple spherical geometries and the assumption of isotropic diffusion. A finite-element code (CYLMOD) has recently been created to simulate diffusion in cylindrical geometry with differing radial and axial diffusion coefficients. We present some applications of the code in evaluating helium lost from zircon grains as a function of grain size and length to diameter ratios, and consider the effects of “shape anisotropy”, where diffusion is isotropic (as in the case of apatite) but shapes of crystal grains or fragments may depart significantly from spherical geometry.     

全球化背景下产业区位形成悖论的理论阐释及其实践意义

产业区位问题一直是区域经济学、经济地理学和产业组织学等学科的重要研究内容.在全球化的浪潮中,跨国公司产业区位的形成出现在两种截然相反的过程,即在全球尺度上区位选择的分散性和区域尺度上区位选择的集聚性,并且本地产业也出现了许多不确定性集聚,形成了传统的区位理论无法解释的悖论.作者运用产业区位形成的要素变化理论、价值链和全球产业链理论以及全球化下的本地化理论来解释这种现象,试图为现代产业区位的选择提供理论基础.在此基础上,文章提出了对发展中国家的几点启示.     

Geochemical monitoring of the 2002–2003 eruption at Stromboli volcano (Italy): precursory changes in the carbon and helium isotopic composition of fumarole gases and thermal waters

Significant changes in the helium and carbon isotopic composition of shallow thermal waters vs. gas and a crater fumarolic gas have been recorded at Stromboli prior and during the 2002–2003 eruption. The³He/⁴He ratios corrected for air contamination (Rc/Ra), and δ¹³C of fumarolic gases gradually increased from May to November 2002 before the eruption onset. These variations imply early degassing of a gas-rich magma at depth that likely fed both the intense Strombolian activity and small lava overflows recorded during that period. The lava effusion of late December 2002 was shortly preceded by a marked Rc/Ra decrease both in water and fumarolic gases. Comparison of He/CO₂ and CH₄/CO₂ ratios in dissolved gas and with values rules out the Rc/Ra decrease due to an increasing input of radiogenic⁴He. The Rc/Ra decrease is attributed to the He isotope fractionation during rapid magma ascent and degassing. A new uprising of ³He-rich magma probably occurred in January to February 2003, when Rc/Ra ratios displayed the highest values in dissolved gases ever measured before (4.56 Rc/Ra). The increase in He/CO₂ and CH₄/CO₂ ratios and decrease in δ¹³C of dissolved CO₂ was recorded after the 5 April 2003 explosive paroxysm, likely caused by enhanced gas-water interaction inducing CO₂ dissolution. No anomalous Rc/Ra values were recorded in the same period, when usual Strombolian activity gradually resumed.Editorial responsibility: H Shinohara     

H2与He的映震灵敏性及其干扰初析

从氢气（H2）与氦气（He）在地壳中的分布与地壳中的分布与地球化学特征的分析着眼，论证了它们的映震灵敏性，并列举了国内外典型震例。同时，中调指出作为深源气体的H2、He动态中同样存在干扰异常，而且地下热水开采的干扰尤为突出。因此，在大力发展H2、He前兆观测的同时，须要深入研究其干扰问题。     

An XRD, TEM and Raman study of experimentally annealed natural monazite

 The healing of radiation damage in natural monazite has been experimentally studied in annealing experiments using XRD, TEM, Raman microprobe and cathodoluminescence analysis. The starting material was a chemically homogeneous monazite from a Brazilian pegmatite with a concordant U–Pb age of 474 ± 1 Ma and a U–Th/He age of 479 Ma. The monazite shows nm-scale defects induced by radioactive decay. The X-ray pattern of the unheated starting material revealed two distinct monazite “phases” A and B with slightly different lattice parameters. Monazite A shows sharp reflections of high amplitudes and slightly expanded lattice parameters (1% in volume) compared to a standard monazite. Phase B exhibits very broad reflections of low amplitudes. Two sets of experiments were performed. First, dry monazite powder was annealed at 500, 800 and 1000 °C for 7 days. Each run product was analysed by X-ray diffractometry. Second, monazite grains were hydrothermally annealed at temperatures from 500 to 1200 °C for 5 to 15 days. TEM observations show that partial healing of the monazite lattice already occurred at 500 °C and increased gradually with temperature, so that after 10 days at 900 °C complete healing was achieved. The observations are interpreted accordingly: the starting material has a mosaic structure consisting of two domains, A and B, which are basically two monazite crystals with different lattice parameters. We suggest that the A domains correspond to well-crystallised areas where helium atoms are trapped. The accumulation of He causes expansion of the A monazite lattice. Diffraction domains B are interpreted as a helium-free distorted monazite crystal lattice, which can be referred to old alpha-recoil tracks. These B domains are composed of “islands” with an expanded lattice, induced by the presence of interstitials, and “islands” of a compressed monazite lattice, induced by presence of vacancies. Both the islands will pose stress on the lattice in the vicinity of the islands. The broadening of the B reflections is due to the expanded or compressed diffraction domains and to the different amount of the distortion. With increasing temperature the unit-cell volume of monazite A decreases, i.e. the position of the A reflections shifts towards smaller d _hkl values. This was interpreted as a relaxation of the monazite lattice due to helium diffusion out of the monazite lattice. Simultaneously, the nm-sized defect domains B are healed. At 900–1000 °C only a monazite with well-crystallised lattice and minimum unit-cell volume is observed. Received: 7 May 2001 / Accepted: 11 October 2001     

焦家深部金矿床成矿流体来源:来自黄铁矿微量元素及S-He-Ar同位素的约束

焦家金矿是胶东蚀变岩型金矿的典型代表，金储量超过200t。矿体受焦家主干断裂控制，呈脉状产出，发育钾化、绢英岩化、硅化和碳酸盐化等蚀变，矿石中主要载金矿物为黄铁矿。热液成矿期主要可分为四个阶段：黄铁矿-石英阶段（i）、金-石英-黄铁矿阶段（ii）、金-石英-多金属硫化物阶段（iii）和石英-碳酸盐阶段（iv）。本文选取焦家金矿床深部I号主矿体为研究对象，采集了不同标高（-600~-1100m）的钻孔岩心样品，分析了黄铁矿的微量元素和S-He-Ar同位素组成，以此讨论成矿流体的组成、性质及来源。研究发现：焦家深部I号矿体黄铁矿呈浅黄色，强金属光泽，自形-半自形粒状结构，粒度50~1000μm，呈浸染状-细脉状分布于黄铁绢英岩化碎裂岩中，为第ii成矿阶段的产物。黄铁矿的稀土元素含量较低，ΣREE为3.27×10^-6~38.5×10^-6，富集轻稀土元素，δCe值为0.81~1.05，δEu值为0.67~1.43，Th/La、Nb/La比值均小于1，指示成矿流体为富Cl的还原性流体。Co/Ni比值介于0.54~1.57之间，平均值为0.99，与变质流体相近；Y/Ho比值在21.9~35.5之间，与地幔值（25~30）和中国东部大陆地壳值（20~35）接近，指示成矿流体与壳-幔相互作用有关。Y/Ho值、Zr/Hf值和Nb/Ta值变化范围较大，表明成矿热液体系发生了交代作用或有外来热液加入。与大陆地壳相比，黄铁矿富集Cu、Pb、Zn、Cd、Co、Ni等亲硫、铁族元素，亏损高场强元素。焦家深部金矿床黄铁矿的δ³⁴S值介于7.5‰~9.8‰之间，平均值为8.7‰，低于浅部矿床δ³⁴S值，呈现出由浅到深δ³⁴S值逐渐降低的特点。胶东金矿硫同位素组成整体一致，绝大多数矿床δ³⁴S值均为正值，变化范围主要集中在6‰~12‰，其来源与古老的变质基底岩系、中生代花岗岩以及幔源流体具有继承演化关系。δ³⁴S值整体呈现出：石英脉型 < 硫化物石英脉型 < 蚀变岩型的变化规律，说明矿化类型的差异是造成硫同位素组成差别的最主要因素。黄铁矿的³He/⁴He值为1.6±0.1Ra~1.8±0.1Ra，⁴⁰Ar/³⁶Ar值为750~3106，均显示混合来源特征。幔源He所占比例为20%~22%，表明幔源流体可能参与了成矿过程。焦家金矿成矿与燕山晚期中国东部强烈的壳幔相互作用密切相关。