高空西北气流下铜仁东部特大暴雨的预报分析及思考

利用贵州省预报业务常规、地面自动站加密观测资料、NCEP/FNL1°×1°再分析资料、业务数值预报模式,分析2020年6月29日铜仁市东部高空西北气流影响下的特大暴雨环境场特征,地面中小尺度场特征以及3家数值预报模式检验,初步分析产生此次特大暴雨的可能成因是在副高东南退,东北冷涡槽后高空西北气流维持,低层冷平流下传西输,地面辐合维持增强为涡旋,地面东路弱冷空气侵入,能量锋区斜压性增强;短临监测发现雷达回波有列车效应,低层辐合高层辐散的共轭配置,中层气旋式辐合;初步得出了西北气流影响下弱天气尺度环境场的铜仁市东部暴雨的预报着眼点。     

小秦岭金矿区小麦和玉米重金属的健康风险评价

重金属污染引发的农产品质量安全问题已成为全社会关注的焦点。为了解小秦岭金矿开发引起的重金属污染风险,采集了同点位的农田土壤、小麦和玉米籽粒样品,测定了其中Hg、Pb、Cd、Cr、As、Cu和Zn的含量及其在土壤中的形态;采用指数法和RAC风险评价法分析了土壤重金属的污染风险,采用转移因子和目标风险指数法评价了小麦、玉米籽粒中重金属的健康风险。结果表明:小秦岭金矿区土壤中Hg、Pb、Cd、Cu、Zn含量受矿业活动影响强度大,在土壤中累积明显;土壤中Hg、Cd、Pb、Cu总量超过了国家限值,呈现污染;Cd、Hg、Cu具有潜在生态风险。小麦和玉米籽粒中Pb以及玉米籽粒中的Cd的平均含量高于国家标准,呈现一定程度的污染;部分小麦样品中的Hg、Cd和部分玉米样品中的Cd超过WHO/FAO安全限值,小麦和玉米籽粒中度Pb平均含量超过欧盟安全标准,说明具有潜在的健康风险。重金属的转移因子表明Cd、Zn及Cu比其他重金属更容易从土壤转移到小麦和玉米籽粒中;通过小麦对重金属的摄入量略高于玉米,远低于WHO/FAO推荐剂量;目标风险指数评价表明,只消费小麦或玉米基本不产生健康风险,但同时消费矿区生长的小麦和玉米具有较高的Pb健康风险。     

南岭山地高速公路雾区恶劣能见度研究

使用2003年10月-2005年3月南岭山地京珠高速公路粤北段云岩雾区路段5套能见度仪的每分钟能见度资料和3套自动气象站的每分钟温度、湿度、风向、风速等气象要素资料, 分析研究了南岭山地高速公路雾区浓雾的能见度特征.结果表明, 南岭山地高速公路雾区各月雾日频率以1月最多, 近一半的天数都有雾; 3月次之, 7月最少.11月到次年5月雾日占全年雾日的80%以上, 形成明显的"雾季".南岭山地高速公路雾区浓雾存在日变化, 雾的频率在一天内凌晨最高, 午后最低, 明显比辐射雾的日变化小, 说明夜间辐射降温虽然不是南岭山地高速公路雾区起雾的主要原因, 但还是起到了一定的加强作用.虽然南岭山地雾区大气中含有丰富的凝结核, 南岭山地形成浓雾还是需要较高的相对湿度, 相对湿度至少要达到91%以上才能形成雾.在雾区出现5.2 m/s的大风时仍然有雾, 有雾时90%以上的风速在3 m/s以下, 有几乎一半的浓雾出现时风速在2 m/s左右, 这与辐射雾形成时大都是静小风的情况形成了鲜明对照.南岭山地高速公路雾区浓雾受地形影响比较大, 迎风坡出现雾的频率比背风坡高.     

Study on the relationship between speciation of heavy metals and their ecotoxicity

Heavy metal is a main pollutant in the marine ecosystem, so study on the effect of heavy metal on phytoplankton is important. Algae (Chaetoceros sp.,Dunaliella sp.,Dicrateria zhanjiangenis Hu. var. sp.) were laboratory cultured to observe the effect of heavy metals on their growth. The effect of different metal ion concentration, the detoxication effect of complexation agents and the growth of algae in different media and different nutrition levels were studied to evaluate the effect of metal speciation. It is proved that trace amount of heavy metals can stimulate the growth of algae cells but that high concentration is lethal. The sequence of toxicity is Cd²⁺>Zn²⁺>Pb²⁺. In ordinary nutrition conditions, the detoxication sequence of complexation agents toChaetoceros sp. is EDTA >sodium salicylate>sodium oxalate >sodium citrate>sulfanilic acid>O-phenanthroline. This is in good conformity with the stability constant sequence of these agents with copper and good evidence that toxicity of metal ion is related to its activity and not to its total concentration. Project supported by the Fund of Excellent Young Teachers of State Educational Commission of China.     

济南市土壤重金属污染现状及其土壤生物学表征

以济南市区及郊区农田土壤为对象,研究土壤中重金属污染的特征,结果表明,土壤重金属污染不仅引起了生态环境的恶化,而且影响土壤生物多样性,降低了土壤活性。济南市土壤动物各类群的数量与土壤重金属元素含量的相关性统计结果显示:土壤原生动物数量与Co、Ni含量呈明显负相关;土壤线虫数量与Cu、Mo含量呈显著负相关;旱生土壤动物数量与Cu含量呈显著负相关;说明重金属元素对土壤动物多样性具有不利影响,土壤线虫是耐污种类,旱生动物多为不耐污种类,土壤线虫与旱生动物密度之比可以作为土壤重金属污染程度的生物学指标。通过对土壤地球化学元素含量与土壤生物学参数的相关性分析,找到了重金属的敏感生物指标:Pb污染的生物学指标为土壤线虫;As污染的生物学指标是真菌PLFA含量等,用土壤生物作为敏感、快速的重金属污染生物毒性的指示物,具有广阔的应用前景。     

袁河流域强降水的天气背景与回波特征分析

为了更好地监测预警江西袁河流域强降水天气,使用江西雨量资料、欧洲中心格点（1°×1°）再分析资料和江西雷达回波等资料,对袁河流域5次大暴雨过程进行分析,结果表明：（1）袁河流域强降水天气形势场是925～700 hPa切变线、低层辐合高层辐散中心、西南气流达到12～18 m·s-1等因素影响;T-LnP图上整层水汽充沛,可降水量在75 mm以上;降水前低层累积不稳定能量CAPE（1000 J/Kg）和对流抑制能CIN（100 J/Kg）。（2）强降水回波的组合反射率CR在50 dBz左右,回波顶高在13 km左右,垂直积分液态水含量在12 kg·m2左右;40 dBz回波顶高在6～7 km,45 dBz回波顶高在6.5 km以下。（3）强降水和回波强度dBZ成正相关,随降水的增强,回波明显增强;当回波强度≤20 dBz时,雨强几乎不变;当回波强度在20～35 dBz之间,雨强随回波强度增加而缓慢加大;当回波强度在35～50 dBz之间,雨强随回波强度加大明显增加;而当回波强度≥50 dBz时,雨强反而趋于下降或维持。研究结果对袁河流域强降水的监测预警和预报服务有指导意义。     

Mineralogy and heavy metal content in sediments from Rio Gato,Carelmapu and Cucao,Southern Chile

In southern Chile, with a mild and rainy climate, high levels of heavy metals have been detected in many gold placer deposits. Many of the contaminants pose risks to human life, and consequently damage the trofic chain in this environment. The study zones selected correspond to the handicraft gold-bearing sands of Rio Gato (Los Muermos), Carelmapu and Cucao. These are all located in the X Region of “Los Lagos” in Chile. The type of methodology used in the characterization of the associated mineralization consists of testing each representative sample with a grain size distribution, statistical parameter analysis and a mineralogical analysis, using a binocular magnifying glass, a petrographic microscope, XRD and SEM/EDX. The chemical composition was defined by means of X ray fluorescence and micro-chemical analysis. The results of the study about sediments in southern Chile are presented. The major concentrations of heavy minerals are generally located in areas of dynamic river energy. In the samples, more than 70% of the heavy minerals were distributed among grain sizes corresponding to thin sand with good grain selection (meshes of 0.25–0.06 mm). The main mineral phases present in the analysed samples were gold, zircon, olivine, ilmenite, hornblende, hypersthene, hematite, garnet, chromite, chlorite, augite, amphibolitic-epidote, etc. The main heavy metals found as a result of the study were mercury, lead, cadmium, chrome, tellurium, indium, zinc, cobalt, copper, platinum, gold, etc., and as well some less common elements like cerium, praseodymium, gadolinium, neodymium, samarium and lanthanum. This research work is only a starting point for carrying out a risk probability mapping of heavy metals and the mineralogy of the Cucao, Carelmapu and Rio Gato gold-bearing sands.     

Differences in trace metal concentrations among fluvial morphologic units and implications for sampling

 This study examines the segregation of trace metals within and between fluvial morphologic units in sand-sized and finer bed sediments in a cobble bed stream. The types of fluvial morphologic units sampled are low gradient riffles, high gradient riffles, glides, eddy drop zones, lateral scour pools, attached bars, and detached bars. Three to nine samples were collected from ten of each type of morphologic unit. All 12 metals show significantly different concentrations between some morphologic units in sediments smaller than 2 mm. Eddy drop zones and attached bars consistently have the highest metal concentrations, while low gradient riffles, high gradient riffles, and glides typically have the lowest concentrations. Metals showing the greatest between-unit variability are Al, Cr, Fe, Cu, and Ti, followed by Co, Mn, and Pb, while Mg, Mn, V, and Zn display relatively few differences between units. Lateral and longitudinal variations of metals within units are not significant, and there was no consistent, predictable variation in metal concentrations with distance downstream. Results indicate that metal studies in other gravel- and cobble-bed streams should include a reconnaissance survey to determine variations between morphologic units, stratify sampling by morphologic unit, and analyze spatial autocorrelation to determine sample spacing. Received: October 1997 · Accepted: 23 March 1998     

从平衡-封闭-静态转向非平衡-开放-动力学研究-热液矿床成因的若干新概念概述

热液金属矿床成因研究过程中,观测与实验始终是密切结合的。上世纪70年代,平衡热力学的实验数据的快速积累,使人们用热力学理论计算可以预测和反演矿石和岩石的成因。但是,没有矿物-水溶液的反应速率数据,又没有与流体力学的结合,搞清楚矿石成因是困难的。七、八十年代,开始研究矿物与水溶液的反应动力学实验。科学家们开始瞄准了从平衡-封闭-静态转向非平衡-开放-动力学研究的这个大方向。1992年我们建立地球化学动力学开放研究实验室。研究高温高压矿物与水反应速率,发现固液的开放体系的自组织现象。实验发现温度影响矿物的各个元素反应速率改变,发现在跨越水临界态时矿物与水反应速率涨落、在近临界的气-液两相不混溶区一些金属进入气相、超临界流体的氧化作用及特别的溶剂性能影响矿物溶解性质。实验证实:临界态区流体与矿石成因有关。水岩相互作用的反应动力学实验温度从低温到550度,揭示矿石的金属来源、迁移、金属与蚀变分带机制。一大批大于300度的矿物与水反应动力学实验在国际界是少有报道的。九十年代,超高压的科学发展,与同步辐射光源的技术进步的结合,使固体地球科学又迈向了地球深内部。我们发展了高温高压流体性质的原位直测(测量850℃水溶液)红外谱,发现深部流体的新性质:气液两相流体的新结构,在临界温度区(300~400℃),水分子氢键网络的破坏受压力影响不大(23MPa~3GPa),同时,出现水的高电导率。研发新仪器为开放-流动-非平衡的反应动力学实验与极端条件下物质性质的直接观测结合,在科学前沿领域开辟了创新道路。