Paleolimnological reconstructions of Rouyn-Noranda lakes within the zone of influence of the Horne Smelter,Québec,Canada

Diatoms were identified and enumerated from a surface sediment calibration set of 50 lakes in northwestern Québec. The relationship between species composition and environmental variables was examined using canonical correspondence analysis (CCA). Forward selection and Monte Carlo permutation tests in CCA indicated that diatom species distributions in the data set are most strongly correlated to lakewater pH. A strong (r ² _boot = 0.83) weighted averaging calibration model, that includes bootstrapped error estimates, was developed for inferring past lakewater pH. Using this model, temporal changes in pH were reconstructed for two kettle lakes, Lac de la Pépinière and Lac Perron. Based on limnological data, both the study lakes were expected to have recently acidified due to increased acidic precipitation and increases in anthropogenic metal loading. However, our long-term pH inference data indicate that these lakes were naturally acidic during pre-industrial times. Nonetheless, the rate of acidification, particularly in Lac de la Pépinière, has accelerated in the last ∼75 years. These long-term pH records developed for the dilute lakes in northwestern Québec suggest that the region has received increased atmospheric pollutants from the nearby Horne smelter in Rouyn-Noranda. The pH inference profiles are markedly different from many other paleolimnological studies in acid-sensitive regions of Canada that have become acidic primarily as a result of industrial activities. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.     

An Experiment Using the High Resolution Eta and WRF Models to Forecast Heavy Precipitation over India

In the present study using the Weather Research and Forecasting (WRF) and Eta models, recent heavy rainfall events that occurred (i) over parts of Maharastra during 26 to 27 July, 2005, (ii) over coastal Tamilnadu and south coastal Andhra Pradesh during 24 to 28 October, 2005, and (iii) the tropical cyclone of 30 September to 3 October, 2004/Monsoon Depression of 2 to 5 October 2004, that developed during the withdrawal phase of the southwest monsoon season of 2004 have been investigated. Also sensitivity experiments have been conducted with the WRF model to test the impact of microphysical and cumulus parameterization schemes in capturing the extreme weather events. The results show that the WRF model with the microphysical process and cumulus parameterization schemes of Ferrier et al. and Betts-Miller-Janjic was able to capture the heavy rainfall events better than the other schemes. It is also observed that the WRF model was able to predict mesoscale rainfall more realistically in comparison to the Eta model of the same resolution.     

燃煤烟气中SO2治理方法综述

对燃煤烟气中SO2的脱除方法进行综述和分析。     

株州市土壤重金属污染的对应分析

株州市土壤重金属污染的主要原因是工厂排放有害气体，或是水体污染物随灌溉进入土壤。采用对应分析方法，将市区土壤重金属污染分析３种类型。靠近人业污染源附近，镉的含量及污染指数高；大部分土壤受多种重金属污染；水稻土主要表现为铅的污染。     

Mineralogical and geochemical behavior of mill tailing material produced from lead-zinc skarn mineralization,Hanover, Grant County,New Mexico,USA

Mineral extraction and processing, especially metal mining, produces crushed and milled waste; such material, exposed to weathering, poses the potential threat of environmental contamination. In this study, mill tailings from inactive Pb-Zn mines in New Mexico, southwest USA, have been examined for their potential environmental impacts by means of detailed mineralogical and geochemical characterization. The principal ore minerals remaining in the tailings material are sphalerite, chalcopyrite, and very minor galena, smithsonite, and cerrusite, accompanied by the gangue minerals pyrite, pyrrhotite, magnetite, hematite, garnet, pyroxene, quartz, and calcite. White precipitate occurring on tailings surfaces is composed of gypsum and hydrated magnesium sulfates. Pyrite is mostly unaltered or shows only micron-scale rims of oxidation (goethite/hematite) in some surface samples. This iron oxide rim on pyrite is the only indication of weathering-derived minerals found by microscopy. There are variations in element concentrations with depth that reflect primary variations through time as the tailings ponds were filled. Cadmium and Zn concentrations increase with depth and Ag and Pb are low for the uppermost core samples, while Cu, Ni, and Co concentrations are generally high for the uppermost core samples. These elemental distributions indicate that little or no leaching has taken place since emplacement of the tailings because no accumulation or enrichment of these metals is observed in Hanover tailings, even in reducing portions of tailings piles. Element concentrations of surface samples surrounding the tailings reflect underlying mineralized zones rather than tailings-derived soil contamination. We observed no successive decreasing metal concentrations in prevalent wind directions away from the tailings. Stream sediment samples from Hanover Creek have somewhat elevated Zn, Cd, and Pb concentrations in areas that receive sediments from erosion of the tailings. However, input from tributaries downstream of the ponds appears to be principal source of heavy metals in Hanover Creek. The results of this study indicate that there is low risk for groundwater heavy-metal contamination from Hanover tailings. Tailings material do not show significant geochemical oxidation/alteration or metal leaching with depth. Our studies indicate that neutralizing minerals present in the tailings are sufficient to keep the tailings material chemically stable. Geochemically, however, tailings materials are being eroded and may pose a threat to Hanover Creek via siltation.     

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.     

Effects of Deicing-Salts on Heavy Metal Mobility Zum Einfluß von Streusalzen auf die Beweglichkeit von Schwermetallen

Heavy metal input into roadside soils and effects of deicing salts are often discussed as separate environmental problems. However, a relationship between salt input and heavy metal mobility has already been detected in laboratory tests. During a 2-year field study, the soil solution of a roadside soil was continuously sampled. The results of soil solution analysis not only showed a strong rise in deicing-salt related sodium, calcium and chloride concentrations, but also high zinc and cadmium values in winter and spring. Additional laboratory tests confirmed the mobilizing effects of salt solution which contained NaCl and CaCl₂. Cation exchange and the formation of chlorocomplexes are discussed as the responsible mechanisms.     

Use of Factor Analysis to Study the Distribution of Metalliferous Bauxitic Tailings in the Seabed of the Gulf of Corinth,Greece

In 1994, a detailed marine environmental survey was carried out in surface sediments of the northern flank (Antikyra Bay) and the basin floor of the Gulf of Corinth. Metalliferous tailings (red-mud slurry) of a bauxite processing plant are discharged through a pipeline at a water depth of 100 m, in the Antikyra Bay, covering an area of 16 km². The bauxitic tailings are detached from the main deposit at the outfalls, flow as turbidity currents downslope, and are redeposited on the basin floor of the Gulf of Corinth, where they cover an area of about 277 km². One hundred sediment samples, that were collected from red-mud deposits and the surrounding natural sediments, were analyzed for Ag, Al, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Si, Ti, V, and Zn concentrations. Statistical analysis of the heavy metals concentrations using factor analysis allowed (i) an examination of the interrelations among metals and (ii) distinguishing possible sample groups on the basis of metal concentrations in order to study the mechanisms of transport of the red mud and the degree of mixing with natural sediments. Factor 1 (Al, Cr, Ti, Fe, Co, Ni, Pb, Ag, Hg, V, Cd, and Cu) and the positive pole of Factor 2 (Cu, Ag, Cd, and Hg) are red-mud factors, reflecting different metal behaviors, which are related to processes that take place during the transport and redeposition of the red mud. The negative poles of Factors 2 and 3 and the positive pole of Factor 4 are related to natural sediment supply processes. Q-mode factor analysis identifies three distinct sediment groups located in different areas, on the base of the degree of mixing of red mud with natural sediments.     

一次滇西南秋季暴雨的中尺度分析与诊断

应用大尺度物理量场诊断分析和中尺度带通滤波处理技术,对2001年10月25日发生在云南西南部的一次暴雨过程机制进行了分析。结果表明,在副热带高压(下称副高)外围大尺度西南气流环境场中,中尺度系统是此次暴雨产生的直接原因;大尺度环境场为暴雨的发生提供了充沛的水汽来源,而中尺度系统则在水汽的强烈辐合、向上输送,使对流层中下层达到准饱和状态扮演了十分重要的角色。     

Incremental Growth of Plains-Type (Compactional) Folds in a Cratonic Environment as Revealed by the Sedimentary Sequence

The enigma of the origin and development of plains-type folds, as they were christened in the early 20th Century, essentially has been solved. The folds, a considerable distance from the tectonic disturbance, were formed by draping of sediments over differentially displaced Precambrian basement fault blocks. These Precambrian basement fault blocks controlled the location, size, and shape of the folds. Forces were transmitted through the rigid basement causing readjustment along the indigenous fracture/fault pattern formed much earlier. In the U.S. Midcontinent, the crystalline basement is overlain by a thin veneer of sediments, and once the structures were formed, they continued to develop as evidenced by features in the overlying sediments. As the stress was transmitted through the basement and then relaxed, the fault blocks moved differentially in concert to these outside forces. Sediment compaction and nondeposition over structural topographic highs reacted accordingly to form the features as seen today. To determine the structural history, structural closure on different horizons on the anticline is plotted in their appropriate stratigraphic position at depth. This gives a compaction line for each tectonically coherent segment. Similar segments show a relatively straightline with offsets at major unconformities indicating breaks in the continuum. It is at these breaks that the section can be stretched until the compaction line matches as a continuum with the resulting gap giving the approximate amount of missing section for that part of the rock column. Conversely, the amount of closure on a structure at depth for each line segment can be estimated by extrapolating downward in that segment. This technique to determine depth of burial and thus the amount of missing stratigraphic section from well data at numerous locations has been compared with estimates made by other methods and the results are similar. Where no other data are available or for quick estimates, then, it is proposed that this approach will give reasonable results and that the values can be used as a constraint in basin modeling.