城市污泥接种堆置处理对重金属的形态及其生物有效性的影响

污泥堆肥化后的土地利用是污泥处理处置的重要方法之一。经过对荆马河底泥接种堆置处理,揭示出污泥中重金属的形态发生明显的变化。荆马河底泥中的重金属污染物主要以结合态和残渣态的形式存在,水溶态和交换态的量很小,经接种堆置处理后,水溶态和交换态量大幅削减,结合态和残渣态量有所增加,总量变化不大,生物学方法和化学方法测定都表明,处理后的底泥生物毒性有明显降低,重金属的生物有效性降低。     

1996年8月8日闽西地区特大暴雨过程分析

本文研究了9601号热带风暴减弱为低压环流后引起突发性大暴雨的成因。结果表明：9610号热带风暴减弱后的低压环流移支福建省南部地区,造成闽西地区湿斜压锋区和不稳定能量明显增强,在低压西侧辐合线所提供的福合上升运动激发下,中尺度对流云团迅速发展,导致远离低压中心的闽西突发大暴雨。闽西特殊的地形对特大暴雨的产生起了组织和增幅作用。另外,还通过逐时数字红外云团图的分析,揭示中尺度对流云团发展演变特征与突发性大暴雨的关系,供日常短时预报参考。     

Heavy metal pollution of coastal river sediments, north-eastern New South Wales, Australia: lead isotope and chemical evidence

 Heavy metal and metalloid concentrations within stream-estuary sediments (<180-μm size fraction) in north-eastern New South Wales largely represent natural background values. However, element concentrations (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn) of Hunter River sediments within the heavily industrialized and urbanized Newcastle region exceed upstream background values by up to one order of magnitude. High element concentrations have been found within sediments of the Newcastle Harbour and Throsby Creek which drains into urbanized and light industry areas. Observed Pb enrichments and low ²⁰⁸Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁶Pb/²⁰⁴Pb ratios are likely caused by atmospheric deposition of Pb additives from petrol and subsequent Pb transport by road run-off waters into the local drainage system. Sediments of the Richmond River and lower Manning, Macleay, Clarence, Brunswick and Tweed River generally display no evidence for anthropogenic heavy metal and metalloid contamination (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn). However, the rivers and their tributaries possess localized sedimentary traps with elevated heavy metal concentrations (Cu, Pb, Zn). Lead isotope data indicate that anthropogenic Pb provides a detectable contribution to investigated sediments. Such contributions are evident at sample sites close to sewage outlets and in the vicinity of the Pacific Highway. In addition, As concentrations of Richmond River sediments gradually increase downstream. This geochemical trend may be the result of As mobilization from numerous cattle-dip sites within the region into the drainage system and subsequent accumulation of As in downstream river and estuary sediments. Received: 5 September 1997 · Accepted: 4 November 1997     

Medium-term responses of rocky bottoms to sewage discharges from a deepwater outfall in the NE Atlantic

An investigation on the effects of deepwater outfall discharges on the status of rocky reef communities was carried out. The sanitation system was found to be an environmentally suitable option for the protection of those habitats situated in high energy coastal environments. Sediments occurring between the predominating rocky substrates showed low values of the fine fraction (<63microm) and organic matter content. In addition, high average concentrations of Cd, Hg and Zn were found in these sediments, though these values were similar to those registered in non-affected sites, far away from the outfall. On the other hand, those assemblages typical of hard substrates that settled near the outfall showed an increase in total richness and abundance of macroinvertebrates. Moreover, the average number of species of each taxonomic group, a good indicator of the maintenance of the previous trophic structure, only varied considerably over time at the rip-rap protection. In a global context, those changes were not directly related to the discharge disturbances, but to the natural variability or the successional processes occurring within those communities. Only communities dwelling in the rip-rap protection area were affected by the proximity of the discharges.     

Heavy metal contamination in western Xiamen Bay sediments and its vicinity, China

Concentrations of selected heavy metals (Cu, Pb, Zn, Cd, Cr, Ni and Fe) in surface sediments from nine sites in western Xiamen Bay and its vicinity were studied in order to understand current metal contamination due to urbanization and economic development in Xiamen, China. The sediment samples were collected in December 2004 and July 2005 respectively in order to examine temporal variations. In this study, we found that heavy metal concentrations in surface sediments sampled in the western Xiamen Bay and adjacent Maluan Bay and Yuandang Lagoon varied from 19 to 97mg kg(-1) for Cu, 45 to 60mg kg(-1) for Pb, 65 to 223mg kg(-1) for Zn, 0.11 to 1.01mg kg(-1) for Cd, 37 to 134mg kg(-1) for Cr, 25 to 65mg kg(-1) for Ni and 3.08 to 4.81% for Fe. Although all metal concentrations in sediments meets Chinese National Standard Criteria for Marine Sediment Quality, both metal enrichment factors (EF) and geoaccumulation index (I(geo)) show that Pb contamination exists in the entire study area and contamination of other metals are also present in some locations depending on the sources, of which sewage outlets and commercial ports are the main sources of contaminants to the area. This study shows that using the sediment quality standard criteria only to assess sediments cannot properly reflect sediment contamination. A multiple approaches should be applied for the sediment quality assessment.     

土壤铅含量高光谱遥感反演中波段选择方法研究

利用高光谱遥感数据进行了南京郊外土壤重金属元素铅的含量反演,由于高光谱数据波段众多,波段选择或变换至关重要。比较了基于次贪婪的前向选择模型的最小角度拟合和基于遗传算法进行波段选择的最小二乘和偏最小二乘拟合,结果发现基于遗传算法的偏最小二乘反演结果优于全波段的偏最小二乘,表明波段选择在高光谱反演重金属中是有益的。尽管采取了波段选择后的各方法在反演时均能达到70%以上的训练精度,但因遗传算法搜索的解空间范围更宽广,使得基于遗传算法的偏最小二乘优于前向选择模型的最小角度拟合。最后还比较了基于遗传算法的普通最小二乘和偏最小二乘拟合,结果表明偏最小二乘更优,因此在高光谱反演重金属含量当中,偏最小二乘精度较高,而在波段选择方法中,遗传算法更优。     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。     

粤西沿海“4.20”特大暴雨特征分析

根据气象常规观测资料、湛江新一代天气雷达资料、CFL-08风廓线雷达资料及卫星云图,分析2012年4月20日粤西沿海特大暴雨的天气环流形势、能量场、对流不稳定度、水汽输送和辐合辐散等环境特征及物理量场特征。结果表明:这次暴雨过程粤西地区共经历两次强降水过程,分别是受飑线系统、以及高空槽和低空切变影响;西南低空急流的出现有利于粤西暴雨的形成、维持和发展;暴雨过程粤西上空垂直累积液水含量达25~30g/m2;暴雨期间风向随高度明显逆转,有冷平流输送;约2.0 km高度以下低空急流的下传和增强与暴雨的产生有密切关系;短时间内多普勒天气雷达的速度回波低层辐合区域远远大于辐散区域是可能产生强降水的标志。     

陶诗言先生在中国暴雨发生条件和机制研究中的贡献

作者在1998年庆贺陶诗言先生八十华诞的文集中曾专题阐述和评价了陶先生对中国暴雨研究的贡献。 至今十五年过去了,陶诗言先生虽已于2012年仙逝,但其深邃的科学思想依然闪烁着智慧的火花。他在中国暴雨研究中留下的宝贵遗产不但深刻影响过去和现代两代人的暴雨研究和业务发展,而且也将继续影响将来的中国暴雨研究。本文是对陶诗言先生在中国暴雨的研究中所作的贡献并结合现代研究的成果作进一步介绍和评价。主要集中在暴雨发生的动力和热力条件与机理方面。全文内容包括六个方面:（1）季节突变对中国梅雨爆发的影响;（2）暴雨发生的多尺度相互作用;（3）暖湿季风输送带对北方大暴雨的影响;（4）高空急流对暴雨的作用;（5）暴雨和强对流发生的物理条件;（6）地形对暴雨的作用     

长三角盛夏—初秋强降水的延伸期过程预报探析

针对长三角汛期强降水过程,根据不同降水类型的特性,提出分时段建立低频模型并给出建模流程。综合分析长三角汛期强降水期的低频特性,将低频气旋及反气旋区分划分7个关键区。重点研究盛夏—初秋时段的强降水特征,在总结强降水期低频特征的基础上,借助EOF分解建立延伸期大—暴雨的预报模型:1区或2区有低频气旋维持并发展;6区、7区或5区存在低频反气旋。并且在7个关键区中1、2区的低频气旋及5、6、7区的低频反气旋为主要低频系统,起决定作用,而3区的低频系统为次要低频系统,起辅助作用。利用该模型提前30 d预报出2012年汛期最强降水过程,并分析本次过程的低频系统演变,给出动态演变模型。