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111.
Mine waste dumps and heavy metal pollution in abandoned mining district of Boccheggiano (Southern Tuscany, Italy) 总被引:12,自引:1,他引:11
M. Benvenuti I. Mascaro F. Corsini P. Lattanzi P. Parrini G. Tanelli 《Environmental Geology》1997,30(3-4):238-243
Mining activity in the Boccheggiano-Fontalcinaldo area (Southern Tuscany) dates back at least to the 16th century AD and
lasted up to very recent times. Copper-rich hydrothermal veins, massive pyrite deposits, and their gossans were exploited.
Two mine waste dumps (Fontalcinaldo, Fontebona), one flotation tailings impoundment (Gabellino), and one roasting/smelting
waste dump (Merse-Ribudelli) in the study area were selected to ascertain the environmental effects of such protracted mining
activity. Primary waste mineralogy is mainly characterized by pyrite, gypsum, quartz, carbonates, chlorites, and micas. Secondary
oxidation mineralogy includes Fe and Cu sulfates and hydroxy sulfates, Cu carbonates, Fe and Al oxyhydroxides, and other phases
[neogenic cassiterite at Fontalcinaldo; probable calkinsite, (Ce,La)2(CO3)3· 4H2O, at Fontebona]. Mine waste samples show extremely variable contents of toxic elements (Cu, Pb, Zn, Bi, Cd, As), with average
values in the order of hundreds to thousands of parts per million (except for Bi and Cd). In some samples, the abundance of
proper minerals of these metals cannot account for the entire metal load. Conceivably, either solid solution substitutions
or adsorption processes contribute to the intake of released metals into newly formed minerals. Release and transport of pollutants
was affected to variable degrees by acid-neutralization processes. The highest metal and acid concentrations occur close to
the investigated wastes and rapidly decrease moving downstream some hundreds of meters or less, with the partial exception
for Mn and Fe. Other than dilution effects, this phenomenon may be ascribed to metal adsorption and precipitation of solid
phases.
Received: 16 April 1995 · Accepted: 14 December 1995 相似文献
112.
113.
An approach to studying heavy metal pollution caused by modern city development in Nanjing, China 总被引:8,自引:0,他引:8
Nanjing is currently one of the fastest developing regions in terms of construction and economy in China. Heavy metal pollution
is becoming more serious with the expansion of production and life scales. Four environmental units (highway, refinery, rubbish
dumps associated with human daily life, and shoal of the Yangtse River) were selected from the region according to the geneses
of the pollution to study and evaluate the distribution and mechanism of the contamination, the speciations of the polluting
elements, and the geneses of the pollution in the soils and sediments. The purposes of the study are to understand generally
the current situation and the cause of the pollution, and to provide a scientific basis to prevent and solve the pollution
problem. At the same time, it would be helpful to probe the effective way of studying heavy metal pollution resulting from
the development of modern cities and to accumulate data. It is indicated by the study that the heavy metals contained in the
soil of the environmental unit of the highway are Pb, Co and Cr; in the soil of the refinery Cr, V, Pb, Ni, and Co; in the
soil of the rubbish plot Co, Cu, and Sb; in the sediments of the shoal Pb, Co, Cu, and Ni. Fe-Mn oxide is given the first
place to the speciations in polluting heavy metals transmitted by air. Carbonate is more in speciations of polluting heavy
metals transmitted by water than in speciations of the metals transmitted by air. In the ten elements studied, Pb is most
directly poisonous to the plants in the region; Co and Cu are the next, and Ni is the least. Heavy metal pollution has been
occurring in the soils and sediments of the region and the situation will worsen if some effective measures are not taken.
Received: 18 October 1997 · Accepted: 3 February 1998 相似文献
114.
云南暴雨涡散场动能转换函数的动态分析 总被引:1,自引:0,他引:1
对1996年云南主汛期(6-8月)逐日散度风动能和旋转风动能之间的转换函数C(KD,KR)特征进行深入研究,同时分析了C(KD,KR)各项Af、Az、B、C在动能转换函数中所起的作用。研究结果表明,对流层内C(KD,KR)>0,同时对流层低层的C(K,KR)>中高层的C(KD,KR)之和.极易出现暴雨过程;Af项在整个动能转换中起主要作用,71%的Af与C(KD,KR)具有相同的符号,Az项和B项在动能转换中起振荡作用,Az+B控制着29%的动能转换方向。 相似文献
115.
四种重金属对海洋钙质角毛藻的毒性 总被引:4,自引:0,他引:4
研究了Hg^2+、Cu^2+、Zn^2+、Cd^2+4种重金属,其单一及4种混合对海洋单胞藻钙质角毛藻Chaetoceros calcutrans的毒性效应,结果表明:单一的重金属毒性强于4种重金属混合,而且不同重金属对单胞藻的毒性效应有所不同,其毒性均Hg^2+〉Cu^2+〉Zn^2+〉Cd^2+。 相似文献
116.
本文讨论1961 ̄1996年11月份福建省莆田地区出现暴雨过程的成因,分析表明暴雨的发生与南海东部沿海热带气旋(或低压)的例槽和北方冷空气共同影响密切相关,并讨论其形势特点、分析其物理量特征,同时进行对比分析。 相似文献
117.
The aim of this paper is to show the concise chemico-physical adsorbent performance of water purification systems utilizing geo-(e.g., allophane, clinoptilolite, and smectite) and bio-polymer materials(e.g.,chitosan or cellulose nanocomposite materials) and to propose an optimal ground-water remediation technique. The performance of geo-materials is evaluated based on the individual sorption and immobilization capacities for various priority substances and pollutants(e.g., lead, zinc, cadmium, c... 相似文献
118.
Nsikak U. Benson Essien D. Udosen Joseph P. Essien Winifred U. Anake Adebusayo E. Adedapo Oyeronke A. Akintokun Omowunmi H. Fred-Ahmadu Abass A. Olajire 《国际泥沙研究》2017,32(3)
This study determines the pollution, fractionation, and ecological risks of sediment-bound heavy metals from coastal ecosystems off the Equatorial Atlantic Ocean. Contamination Factor(CF), pollution load index(PLI), and geoaccumulation index(Igeo) were used to assess the extent of the heavy metal pollution, while the potential ecological risk was evaluated using the risks assessment code(RAC) and Hkanson potential ecological risk. The analysis revealed concentrations(mg/g, dw) of the cadmium(Cd),chromium(Cr), copper(Cu), nickel(Ni), and lead(Pb) in sediments for wet and dry seasons vary from 4.40-5.08, 14.80-21.09. 35.03-44.8, 2.14-2.28, and 172.24-196.39, respectively. The results also showed that the metal fractionation percentages in the residual, oxidizable, and reducible fractions are the most significant, while the exchangeable and carbonate bound trace metals are relatively low. The RAC values indicate no risk for Cd and Ni and low risk for other metals at all the studied sites during both seasons.Potential ecological risk analysis of the heavy metal concentrations indicates that Cd had high individual potential ecological risk, while the other metals have low risk at all investigated sites. The multi-elemental potential ecological risk indices(R_1) indicate high ecological risk in all the ecosystems. 相似文献
119.
120.
Attenuation of Heavy Metals and Sulfate by Aluminium Precipitates in Acid Mine Drainage During the mixing of acid mine waters with nearly neutral tributaries, often precipitates are formed which are high in iron or aluminium. These precipitates cover the river bed for many kilometres. Near the town of Lehesten (Thuringian slate mining area), leachates of slate quarries and waste rock dumps contain high amounts of aluminium, sulfate, copper, nickel, zinc, manganese, and H+ ions as a result of the oxidation of incorporated pyrite. These leachates enter the brooks Loquitz, Kleine Sormitz, and Rehbach leading to the phenomenon named above. The contribution of the forming aluminium‐rich precipitates on the attenuation of sulfate and heavy metals by sorption or coprecipitation was studied by analysing the composition of water and sediment samples as well as samples of suspended matter. Sulfate is often considered as conservative tracer in acid mine drainage. However, sulfate does not behave conservatively in this system what might be explained by the adsorption of sulfate to the aluminium precipitates. Instead, conservative behaviour was found for calcium, potassium, chloride, zinc, manganese, and nickel. A formation of jurbanite can be excluded because of the low sulfate contents. The sulfate content of the sediment depends on the pH. At low pH values (4.8) the S/Al ratio corresponds to the theoretical ratio in basaluminite and decreases with rising pH. Sulfate is weakly bound to the solid phase and can easily be replaced by OH– ions. A formation of basaluminite is possible at low pH values with a fluent transition to aluminium hydroxide. Therefore the precipitates are assumed to consist predominantly of aluminium hydroxide with sulfate being adsorbed to the surface. 相似文献