Evidence for deep groundwater flow and convective heat transport in mountainous terrain, Delta County, Colorado, USA

The Tongue Creek watershed lies on the south flank of Grand Mesa in western Colorado, USA and is a site with 1.5 km of topographic relief, heat flow of 100 mW/m², thermal conductivity of 3.3 W m^–1 °C^–1, hydraulic conductivity of 10^-8 m/s, a water table that closely follows surface topography, and groundwater temperatures 3–15°C above mean surface temperatures. These data suggest that convective heat transport by groundwater flow has modified the thermal regime of the site. Steady state three-dimensional numerical simulations of heat flow, groundwater flow, and convective transport were used to model these thermal and hydrological data. The simulations provided estimates for the scale of hydraulic conductivity and bedrock base flow discharge within the watershed. The numerical models show that (1) complex three-dimensional flow systems develop with a range of scales from tens of meters to tens of kilometers; (2) mapped springs are frequently found at locations where contours of hydraulic head indicate strong vertical flow at the water table, and; (3) the distribution of groundwater temperatures in water wells as a function of surface elevation is predicted by the model.     

Identification of sources of chemical constituents in groundwater from the Vilnius wellfields, Lithuania

The only source of drinking water in Vilnius City, Lithuania's capital, is groundwater. It can be supplied from 20 wellfields situated in the City or its environs. About half of them (11) are located in the valley of the Neris River crossing the City. The exploited aquifers were formed by melting continental glaciers and modified by the river. Until 1990 groundwater resources had not been conserved—the per capita consumption for domestic use in Vilnius reached 350 l/day. After 1990, due to the increasing cost of supplying drinking water, its consumption was reduced by a factor of three. As pumping rates of wellfields in Vilnius were increased or decreased, the groundwater quality was changed significantly. It is mainly affected by the surface water and shallow aquifers of the hydrologic system. The unoxidised organic matter that enters the exploitable aquifers from rivers and polluted shallow groundwater consumes scarce oxygen resources, thus creating anoxic conditions favourable for increasing the accumulation of iron, manganese and ammonium. Modelling and monitoring data show that the concentrations of sulphates and chlorides in Vilnius wellfields indicate not only the rise of brackish water from below, but also downward seepage of polluted surface water into the aquifers.     

Determination of specific yield using a water balance approach – case study of Torla Odha watershed in the Deccan Trap province, Maharastra State, India

Specific yield is an essential parameter for any groundwater management plan. Volumetric analysis in the domain of groundwater budgeting for the non-monsoon months has been undertaken for a typical watershed of the Deccan basalt province. The Torla Odha watershed covers an area of over 22 km² on a third-order tributary of the westerly flowing Bhima River. The watershed receives a normal annual rainfall of 643 mm. The entire water demand is supplied by dug wells, which penetrate a shallow aquifer. The specific yield was estimated by comparing the monthly net volume of water removed from the aquifer, with the volume of aquifer de-saturated, based on monthly water level data. The estimated specific yield ranges from 0.0019 in May to 0.0173 in November with an average value of 0.0093. A correlation of the groundwater levels with the detailed geology suggests that the higher specific yield value (0.017) corresponds to dewatering of the weathered zone within the shallow aquifer. The specific yield of the massive basalt immediately below the weathered zone varies from 0.0089 to 0.0103. The underlying vesicular basalt, which is dissected by sheet joints, has a relatively higher specific yield (0.0121). The massive basalt, which forms the base of the shallow aquifer system, has a lower specific yield from 0.0019 to 0.0022.

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Résumé Le débit spécifique est un paramètre essentiel pour tout plan de gestion des eaux souterraines. Les analyses volumétriques, dans le cadre des bilans hydriques des eaux en dehors des mois de mousson, ont été entreprises pour un bassin-versant typique de la province basaltique du Deccan. Le bassin-versant du Torla Odha couvre une superficie de 22 km², et alimente l’affluent du troisième ordre de la rivière Bhima, qui coule vers l’Ouest. La pluviométrie annuelle atteint 643 mm. Toute la demande en eau es assurée par des puits foncés pénétrant dans l’aquifère phréatique. Le débit spécifique a été estimé en comparant le volume net mensuel d’eau captée dans l’aquifère, avec le volume de l’aquifère dé-saturé, basé sur les données des niveaux piézométriques mensuels. Le débit spécifique estimé s’étend entre 0,0019 en Mai et 0.173 en Novembre; la moyenne se situe à 0,0093. Une corrélation entre les niveaux des eaux souterraines et la géologie, suggère que les débits spécifiques les plus importants (0,017) correspondent aux zones altérées de l’aquifère phréatique. Le débit spécifique du massif basaltique, immédiatement sous la zone altérée, varie entre 0,0089 et 0,0103. Le basalte vésiculaire, situé juste en dessous et traversé par des diaclases parallèles, possède un débit spécifique sensiblement plus élevé (0,0121). Le basalte massif, qui forme la base de l’aquifère phréatique, possède un débit spécifique moins important, compris entre 0,0019 et 0,0022.

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Resumen El rendimiento específico es un parámetro esencial para cualquier plan de manejo de aguas subterráneas. Se ha llevado a cabo el análisis volumétrico, en el entorno de balance de aguas subterráneas, para los meses sin monzón de una cuenca típica de la provincia de basaltos Deccan. La cuenca Rorla Odha cubre un área de 22 km² en un tributario de tercer orden del Río Bhima que fluye al oeste. La cuenca capta una lluvia anual normal de 643 mm. La totalidad de la demanda de agua es abastecida por pozos manuales que penetran un acuífero somero. Se estimó el rendimiento específico al comparar el volumen neto mensual de agua removido del acuífero con el volumen de agua de-saturado estimado a partir de datos de niveles de agua mensuales. Los valores estimados de rendimiento específico varían de 0.0019 en mayo a 0.0173 en noviembre con un valor promedio de 0.0093. La correlación de niveles de agua subterránea con la geología de detalle sugieren que el valor más alto (0.017) de rendimiento específico corresponden con el desaguado de la zona de intemperismo dentro del acuífero somero. El rendimiento específico del basalto masivo que se encuentra inmediatamente debajo de la zona de intemperismo varía de 0.0089 a 0.0103. El basalto vesicular subyacente, el cual está disectado por fracturas laminares, tiene un rendimiento específico relativamente más alto (0.0121). El basalto masivo, que forma la base del sistema de acuífero somero, tiene un rendimiento específico más bajo el cual varía de 0.0019 a 0.0022. Palabras clave: basalto Deccan. India. Rendimiento específico. Recarga de agua subterránea. Balance hídrico.

     

青藏高原地面-对流层系统的能量收支

利用CCM3中的辐射模式CRM，计算了1月和7月地－气系统、地面－对流层系统和地面辐射能收支，研究了青藏高原地面－对流层系统辐射能收支的冬、夏季节特征及其与地面和地－气系统辐射能收支的关系，并与东部平原地区和高原北侧干旱地区比较。文中还讨论了云和高原冬季地面积雪对辐射能收支的影响，比较了大气辐射加热和地面感热通量对夏季高原对流层大气加热的贡献。     

土壤热异常影响地表能量平衡的个例分析和数值模拟

The statistical relationship between soil thermal anomaly and short-term climate change is presented based on a typical case study. Furthermore, possible physical mechanisms behind the relationship are revealed through using an off-line land surface model with a reasonable soil thermal forcing at the bottom of the soil layer.In the first experiment, the given heat flux is 5 W m-2 at the bottom of the soil layer (in depth of 6.3 m)for 3 months, while only a positive ground temperature anomaly of 0.06℃ can be found compared to the control run. The anomaly, however, could reach 0.65℃ if the soil thermal conductivity was one order of magnitude larger. It could be even as large as 0.81℃ assuming the heat flux at bottom is 10 W m-2. Meanwhile, an increase of about 10 W m-2 was detected both for heat flux in soil and sensible heat on land surface, which is not neglectable to the short-term climate change. The results show that considerable response in land surface energy budget could be expected when the soil thermal forcing reaches a certain spatial-tem poral scale. Therefore, land surface models should not ignore the upward heat flux from the bottom of the soil layer. Moreover, integration for a longer period of time and coupled land-atmosphere model are also necessary for the better understanding of this issue.     

The Production of Methanol by Flowering Plants and the Global Cycle of Methanol

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.     

某盆地油气勘查成本预算和风险分析

某高原盆地的油气资源量较为丰富，可找到大型油气田。根据含油气盆地地质构造特征、生油岩的厚度与热演化程度、储集层和区域性盖层的发育情况等因素，确定了两个含油气远景区，拟作为重点找油气靶区。提出了两个可供选择的油气勘探布署方案。在此基础上，选用适当的成本预算基本参数，进行油气勘查成本估算，并对两个方案进行了优选对比与具体的风险分析，提出方案决策意见。     

Heat flow and thermal modeling of the Yinggehai Basin, South China Sea

Geothermal gradients are estimated to vary from 31 to 43 °C/km in the Yinggehai Basin based on 99 temperature data sets compiled from oil well data. Thirty-seven thermal conductivity measurements on core samples were made and the effects of porosity and water saturation were corrected. Thermal conductivities of mudstone and sandstone range from 1.2 to 2.7 W/m K, with a mean of 2.0±0.5 W/m K after approximate correction. Heat flow at six sites in the Yinggehai Basin range from 69 to 86 mW/m², with a mean value of 79±7 mW/m². Thick sediments and high sedimentation rates resulted in a considerable radiogenic contribution, but also depressed the heat flow. Measurements indicate the radiogenic heat production in the sediment is 1.28 μW/m³, which contributes 20% to the surface heat flow. After subtracting radiogenic heat contribution of the sediment, and sedimentation correction, the average basal heat flow from basement is about 86 mW/m².Three stages of extension are recognized in the subsidence history, and a kinematic model is used to study the thermal evolution of the basin since the Cenozoic era. Model results show that the peak value of basal heat flow was getting higher and higher through the Cenozoic. The maximum basal heat flow increased from 65 mW/m² in the first stage to 75 mW/m² in the second stage, and then 90 mW/m² in the third stage. The present temperature field of the lithosphere of the Yinggehai Basin, which is still transient, is the result of the multistage extension, but was primarily associated with the Pliocene extension.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

Dissolved silica budget in the North basin of Lake Lugano

We studied the dissolved silica cycle in the water column of the North basin of Lake Lugano, Switzerland/Italy. Lake Lugano is a meromictic, eutrophic lake, permanently stratified below 100-m depth. A one-box model was used to calculate a silica mass-balance over 1993, based on various lake measurements, such as sediment traps, sediment cores, water analysis and biota countings. We found that the North basin of Lake Lugano is at steady state as far as dissolved silica is concerned. The primary source of dissolved silica in the lake is river input (about 80%), with diffusion from bottom sediments and groundwater input also playing a role. Atmospheric input is negligible. The main export of dissolved silica occurs via biogenic uptake by diatoms and final burial of their frustules in the bottom sediment. Loss of dissolved silica through the lake outflow only represents 15% of the total output. Of the total amount of Si exported to the lake bottom through diatom sinking, less than 20% is re-supplied to the surface water by diffusion. Thus, the lake acts as an important permanent sink for silica. The long residence time of dissolved silica in the lake (7 years) is related to the strong physical stratification of the lake. Only about 10% of the standing stock are available to phytoplankton uptake.