On the origin of HNC in Comet Lee

We have modelled the chemistry occurring in the coma of Comet Lee and have critically evaluated the possible routes leading to HNC. We show that the observed levels of HNC cannot be produced by ion–molecule chemistry, or by reactions of energetic H atoms with HCN. Rather, it appears that HNC is injected into the coma following the photodestruction of an unknown precursor. We discuss the possible nature of the parent of HNC and conclude that photofragmentation of large HCN polymers, such as polyaminocyanomethylene (PACM), is responsible. The degradation of hydrogen cyanide polymers may constitute a common source of HNC in comets, accounting for HNC/HCN ratios in the range measured in Lee and Hyakutake (≈ 0.06–0.12). The high HNC/HCN ratio measured in Hale–Bopp (≈0.2) and its heliocentric variation may, however, require an additional source.     

自适应精致极化Lee滤波的复相干性估计方法

干涉相干性包含了极化SAR干涉测量(PolInSAR)中的极化和干涉信息,滑动窗口大小和滤波方法是准确估计干涉相干性的前提。本文以精致极化Lee滤波为基础,根据边缘检测和邻域相干性高低区分同质区域和异质区域,建立了自适应精致极化Lee滤波方法并估计相干性矩阵和干涉相干性。自适应精致极化Lee滤波能够根据边缘检测信息和邻域相干性高低程度调整滑动窗口大小并选择合适的估计方法,不仅提高了抑制斑点噪声的能力,而且保持了图像的边缘信息,有利于提高干涉相干性的估计精度。试验结果表明,该方法有效抑制了斑点噪声,较好地保持了SAR图像的边缘信息,有利于提高植被参数反演的精度。     

The effects of Hurricane Irene and Tropical Storm Lee on the bed sediment geochemistry of U.S. Atlantic coastal rivers

Hurricane Irene and Tropical Storm Lee, both of which made landfall in the U.S. between late August and early September 2011, generated record or near record water discharges in 41 coastal rivers between the North Carolina/South Carolina border and the U.S./Canadian border. Despite the discharge of substantial amounts of suspended sediment from many of these rivers, as well as the probable influx of substantial amounts of eroded material from the surrounding basins, the geochemical effects on the <63‐µm fractions of the bed sediments appear relatively limited [<20% of the constituents determined (256 out of 1394)]. Based on surface area measurements, this lack of change occurred despite substantial alterations in both the grain size distribution and the composition of the bed sediments. The sediment‐associated constituents which display both concentration increases and decreases include: total sulfur (TS), Hg, Ag, total organic carbon (TOC), total nitrogen (TN), Zn, Se, Co, Cu, Pb, As, Cr, and total carbon (TC). As a group, these constituents tend to be associated either with urbanization/elevated population densities and/or wastewater/solid sludge. The limited number of significant sediment‐associated chemical changes that were detected probably resulted from two potential processes: (1) the flushing of in‐stream land‐use affected sediments that were replaced by baseline material more representative of local geology and/or soils (declining concentrations), and/or (2) the inclusion of more heavily affected material as a result of urban nonpoint‐source runoff and/or releases from flooded treatment facilities (increasing concentrations). Published 2013. This article is a U.S. Government work and is in the public domain in the USA.     

城市热山波的动力和数值分析

木文采用对数压力坐标系的大气热力-动力学方程组,对城市热岛现象之一的热山波的特征、形成机制、存在条件及其对天气的影响进行了动力学和数值分析。     

Monitoring Surface Velocity from Repeated ADCP Observations and Satellite Altimetry

A method has been developed to monitor the surface velocity field by combining repeated acoustic Doppler current profiler (ADCP) observations and satellite altimetry data. The geostrophic velocity anomaly is calculated from the sea surface height anomaly field estimated from the altimetry data by an optimal interpolation. It has been confirmed that this accurately observes the smoothed velocity anomaly field when the interpolation scales are set according to the spatio-temporal sampling pattern of the altimeter used. The velocity anomaly obtained from the altimetry data is subtracted from the repeated ADCP observations to estimate temporal mean velocity along the ship tracks. Regularly sampled, nine-year time series of surface velocity can then be obtained by adding the computed mean velocity and the altimetry anomaly components. This clearly illustrates surface velocity fluctuations such as the movement of the Kuroshio axis due to its meandering and an increase of the interannual variability of the Subtropical Countercurrent toward its downstream region. This revised version was published online in July 2006 with corrections to the Cover Date.     

Hawaiian magma-reservoir processes as inferred from the petrology of gabbro xenoliths in basalt,Kahoolawe Island

Gabbro xenoliths in a tholeiitic lava of Kahoolawe Island, Hawaii, a 1.3–1.4 Ma shield volcano, are 1–3 cm in size and comprised of plagioclase, clinopyroxene, and orthopyroxene. Gabbro textures — while intergranular and in part subophitic-are open due to 28–48 vol.% of vesicular basalt occupying xenolith space. Vesicles in and around the xenoliths are lined or filled with rhyolitic glass (segregation vesicles). The host is evolved tholeiite (MgO 6.1 wt%) with phenocrysts, microphenocrysts, and glomerocrysts of olivine, clinopyroxene, orthopyroxene, and plagioclase, and megacrysts (1 cm) of plagioclase. The Sr-isotope ratio of one xenolith is 0.70489; the host basalt ratio is 0.70460. Xenolith isotope composition, grain resorption, and clinopyroxene (Fs_12.5–15Wo_38–35.5), orthopyroxene (Fs_19.5–24Wo_4.1), and plagioclase (An_68–65Or_0.8–1.2) compositions suggest that these gabbros crystallized from Kahoolawe tholeiitic magma of essentially the same composition as the host basalt, but pre-dating the magma represented by the host. Based on the absence of intergranular Fe–Ti oxide phases from the pl+cpx+opx assemblages, and the open, vuggy textures, we envision crystallization on a reservoir roof at temperatures >1100°C. Entrainment of gabbro assemblages and plagioclase megacrysts from a roof mush/suspension zone occurred during convection associated with replenishment of the magma reservoir. These open-textured gabbro xenoliths are therefore not fragments of preexisting coarse-grained bodies such as sills or segregation veins. Rhyolitic glass in vesicles represents a gas-effervescence filtration process that forced fractionated residual liquids from the groundmass into voids associated with the xenoliths.Sirrine Environmental Consultants, Fremont, CA 94538     

Isotopic geochemistry of Hualalai shield-stage tholeiitic basalts from submarine North Kona region,Hawaii

The geochemical data of Hualalai tholeiitic basalts allow extension of the temporal variations established at Mauna Loa back in time, and provide important information for the long-term temporal variation of the Hawaiian lavas. We report new Hf, Pb, Nd, and Sr isotope compositions for 32 Hualalai tholeiitic basalts collected from deep submarine portions of the North Kona region. The samples were collected from the lower section of the North Kona bench (dives K218 and K219), a submarine stratigraphic section at Hualalai volcano's northwest rift zone (dive S690), and an elongate ridge outboard of the central section of the bench (dive S692), during two JAMSTEC Hawaii cruises in 2001 and 2002. The Hualalai shield-stage tholeiitic basalts have magma source isotopic signatures similar to Mauna Loa. The new data shows temporal Pb and Sr isotope trends that correspond to the long-term temporal variations in Loa-trend lavas, and the Hualalai–Mauna Loa lavas seem to show inter-shield geochemical excursions. Variation in Pb and Sr isotopes at Hualalai appears to take place over a longer time scale than at Mauna Loa. The merged Hualalai–Mauna Loa isotopic trends support models where heterogeneous material in the plume conduit is distributed chaotically, with variable cross-sectional density and length scale.     

Observation of Tidal Tilt On Kilauea Volcano, Hawaii

Summary. We have analysed the east-west tilt components, O₁, K₁, N₂, M₂ and S₂ from a continuously recording tiltmeter located in Uwekahuna Vault on Kilauea Volcano, Hawaii, for the period 1971—79. Detailed analysis of the M₂ component gives values of 30.9 ± 2.0 (95 per cent) nrad and 116.0 ± 2.0° for the amplitude and phase, respectively, compared to values of 48.5 nrad and 139.4° for the equilibrium tide. the total theoretical tide, found by summing the equilibrium and load tides, amounts to 37.2 nrad at a phase of 121.7°. the 20 per cent discrepancy with that observed may be due to an inaccurate cotical chart, cavity effects in the vault, strain—tilt coupling or an inappropriate solid earth model. In the vicinity of Hawaii (≤ 3°) two independent cotidal charts give almost identical results for the near field ocean load. At greater distances, we use the Schwiderski (1978) cotidal chart. We estimate that local cavity and strain—tilt coupling effects are less than 12 per cent owing to the agreement between geodetically determined and instrumental tilt but we can not rule out regional effects. Assuming these are small and the cotical charts correct, we find that the M₂ results are brought into satisfactory agreement if, instead of using an average oceanic earth model in the (< 75 km) vicinity of Hawaii, we use an earth model with nearly one-half the oceanic rigidity. Such a low upper mantle and crustal rigidity is consistent with Kilauea's position above the thermal upwelling associated with the Hawaiian hotspot.     

中朝地台的志留系——纪念中、韩两国杰出的微体古生物学者安太庠和李河荣

中朝地台内部无争议的志留系只有朝鲜半岛平南盆地的谷山组和宝良里组。中朝地台北缘活动陆缘带志留系比较发育,有桃山组、西别河组(至少其大部分)等。李河荣等根据牙形刺将朝鲜半岛太白山盆地的桧洞里组划归志留系,但是从层序、岩石和安太庠修定的牙形刺化石来看,桧洞里组可能不是志留系,而是与中朝地台华北区峰峰组八陡段(或包括部分耀县组)可比的中奥陶世地层。微体古生物学家安太庠和李河荣分别为中国和韩国的牙形学及其生物地层学研究做出了重要贡献。他们的英年早逝,对东北亚地学研究是一个重大损失。     

Derelict fishing gear in the northwestern Hawaiian Islands: diving surveys and debris removal in 1999 confirm threat to coral reef ecosystems

Marine debris threatens Northwestern Hawaiian Islands' (NWHI) coral reef ecosystems. Debris, a contaminant, entangles and kills endangered Hawaiian monk seals (Monachus schauinslandi), coral, and other wildlife. We describe a novel multi-agency effort using divers to systematically survey and remove derelict fishing gear from two NWHI in 1999. 14 t of derelict fishing gear were removed and debris distribution, density, type and fouling level documented at Lisianski Island and Pearl and Hermes Atoll. Reef debris density ranged from 3.4 to 62.2 items/km². Trawl netting was the most frequent debris type encountered (88%) and represented the greatest debris component recovered by weight (35%), followed by monofilament gillnet (34%), and maritime line (23%). Most debris recovered, 72%, had light or no fouling, suggesting debris may have short oceanic circulation histories. Our study demonstrates that derelict fishing gear poses a persistent threat to the coral reef ecosystems of the Hawaiian Archipelago.