Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.     

Arsenic, antimony and other toxic elements in the drinking water of Eastern Thessaly in Greece and its possible effects on human health

Twenty-six groundwater samples were collected from the Eastern Thessaly region and analysed by ICP-ES for these elements: Al, As, P, Pb, Zn, Mn, Fe, Cr, Sb, Cu, Na, Br, Cl, Si, Mg, Ag, Be, Bi, Dy, Er, Eu, Au, Ge, Ho, In, Ir, Os, Pt, Re, Rh, Ru, Lu, Hf, Hg, Tm, Zr and Nb. The objectives of the study were to assess the level of water contamination with respect to the EC and the USEPA health-based drinking water criteria. The geology of the studied area includes schists, amphibolites, marbles of Palaeozoic age, ophiolites, limestones of Triassic and Cretaceous age, Neogene and Quaternary deposits. The element ranges for groundwater samples are: Al 7–56 μg l⁻¹, As 1–125 μg l⁻¹, Br 6–60 μg l⁻¹, Cl 500–25,000 μg l⁻¹, Cr 1–6 μg l⁻¹, Cu 1–15 μg l⁻¹, Fe 10–352 μg l⁻¹, Mg 2,940–40,100 μg l⁻¹, Mn 0–8 μg l⁻¹, Na 3,650–13,740 μg l⁻¹, P 20–48 μg l⁻¹, Pb 0–7 μg l⁻¹, Sb 0–21 μg l⁻¹, Si 3,310–13,240 μg l⁻¹ and Zn 7–994 μg l⁻¹. The results of groundwater analyses from the region of Eastern Thessaly showed elevated concentrations of As and Sb. Factor analysis explained 77.8% of the total variance of the data through five factors. Concentration of Br, Cl, Mg, Na and Si is directly related to the presence of saltwater in the aquifer, so grouping of these variables in factor 1 probably reflects the seawater intrusion. Al, As and Sb are known to form complexes in the environment, so grouping of these elements in factor 2 indicates their similar geochemical behaviour in the environment. The high negative loading of Mn in factor 2 indicates the presence of manganese oxides–hydroxides in the study area. Pb and Zn are associated together in sulphide mineralisation; so grouping of these elements in factor 3 reflects the sulphide mineralization paragenesis in the Melivoia area. P and Cu are associated together in phosphate fertilizers; so grouping of these variables in factor 4 could be related to agricultural practices. Cr, Fe, Mn and Mg are associated together in iron and manganese oxides–hydroxides and the weathering products of the olivine of the ultrabasic rocks; so grouping of these elements in factor 5 reflects the lithology of the area. There is a natural contamination of groundwaters with elevated concentrations of As and Sb due to the presence of the arsenopyrite and stibnite mineralisation in the Melivoia, Sotiritsa and Ano Polydendri areas. Contamination over the health-based drinking water guidelines given by EC and EPA has been investigated from nine sampling sites out of 26 of Eastern Thessaly region.     

Identification of sources of chemical constituents in groundwater from the Vilnius wellfields, Lithuania

The only source of drinking water in Vilnius City, Lithuania's capital, is groundwater. It can be supplied from 20 wellfields situated in the City or its environs. About half of them (11) are located in the valley of the Neris River crossing the City. The exploited aquifers were formed by melting continental glaciers and modified by the river. Until 1990 groundwater resources had not been conserved—the per capita consumption for domestic use in Vilnius reached 350 l/day. After 1990, due to the increasing cost of supplying drinking water, its consumption was reduced by a factor of three. As pumping rates of wellfields in Vilnius were increased or decreased, the groundwater quality was changed significantly. It is mainly affected by the surface water and shallow aquifers of the hydrologic system. The unoxidised organic matter that enters the exploitable aquifers from rivers and polluted shallow groundwater consumes scarce oxygen resources, thus creating anoxic conditions favourable for increasing the accumulation of iron, manganese and ammonium. Modelling and monitoring data show that the concentrations of sulphates and chlorides in Vilnius wellfields indicate not only the rise of brackish water from below, but also downward seepage of polluted surface water into the aquifers.     

弯道超高法在泥石流流速计算中的应用——以四川省汶川县G317国道磨子沟泥石流为例

选取四川省汶川至马尔康公路线的磨子沟作为试验对象,采用弯道超高法推算其泥石流流速。进而可以计算出该次泥石流的平均流量,为公路的改建工程提供设计依据。经过实地调查,用此方法计算磨子沟2005年8月17日暴发的泥石流流速为4.4m/s。同其他流速方法计算的结果相比较,前者值偏大,且偏向于工程安全值。弯道超高法可以解决泥石流观测的局限性和泥石流发生的不可重复性。此方法简便易行,对泥石流防治工程具有一定的实用价值。     

Design of Inclined Covers with Capillary Barrier Effect

A design procedure is proposed to minimize water infiltration into landfills by optimizing the water diversion length of inclined covers with capillary barrier effect (CCBE). This design procedure is based on a conceptual, mathematical and numerical approach and aims at selecting materials and optimizing layer thickness. Selection among candidate materials is made based on their hydraulic conductivity functions and on a threshold infiltration rate imposed on the designer. The capillary break layer (CBL; bottom layer) is characterized by a weak capillarity, while the moisture retention layer (MRL; upper layer) is characterized by a compromise between strong capillarity and high hydraulic conductivity. The thickness of the CBL corresponds to the height where suction reaches its maximum value for a given infiltration rate. This height can be calculated using the Kisch [Géotechnique 9 (1959)] model. The optimal thickness of the MRL is determined by applying an adaptation of the Ross [Water Resources Research 26 (1990)] model. The results obtained using the proposed design procedure were compared to those obtained from numerical simulations performed using a finite element unsaturated seepage software. The procedure was applied for two cover systems; one where deinking by-products (DBP) were used as MRL and sand as CBL and another where sand was used as MRL and gravel as CBL. Using this procedure, it has been shown that an infiltration control system composed of thin layers of sand over gravel is highly efficient in terms of diversion length and that its efficiency can be enhanced by placing a hydraulic barrier – such as a layer of DBP – above the MRL.     

The Alcamayo and Cedrobamba catastrophic debris flow (January, March and April 2004) in Machupicchu area—Peru

A debris flow originating from the Alcamayo River on 10th April 2004 destroyed a part of the town of Aguas Calientes, resulting in 11 victims, and with serious affects to the tourist flow to the Machupicchu inka citadel. On the same day, as well as in January and March 2004, other similar phenomena occurred on the Cedrobamba and Leonchayoq Rivers, affecting the railway and an electrical tower, and disrupting the train service.     

Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

Chemical characterization of the Neogene Aquifer, Belgium

The evolution of groundwater chemistry along the direction of groundwater flow was studied using hydrochemical data from samples collected along a flow line in the Neogene Aquifer, Belgium. Infiltrating water was found to have a very low mineral content and low pH because the sediments are strongly decalcified. Increasing SiO₂ and cation concentrations along the groundwater flow line indicate silicate-weathering processes, confirmed with the aid of saturation indices, calculated with PHREEQC, and stability diagrams. A classification system based on redox sensitive species was developed and shows that an extensive redox sequence is present in the aquifer. At a shallow depth, pyrite oxidation has caused an increase in sulphate, while iron is precipitated as hydroxides. Elevated arsenic concentrations are related to the reduction of these iron hydroxides at a relatively shallow depth and to the dissolution of siderite at greater depth. Dissolution of carbonate in the aquifer material, present in deep layers and to the north, has lead to increased Ca²⁺ and HCO₃ ^? concentrations. The Ca²⁺ from the groundwater is exchanged for Na⁺, Mg²⁺ and K⁺ adsorbed to the clay surfaces at the bottom of the groundwater reservoir. Although the Neogene Aquifer is well flushed, there are still some marine influences present in the deepest parts.     

Hydrochemistry and isotope geochemistry as tools for groundwater hydrodynamic investigation in multilayer aquifers: a case study from Lomellina, Po plain, South-Western Lombardy, Italy

A multicriteria approach in studying hydrodynamics of a multilayer aquifer system has been used in the Lomellina region (Northern Italy). It involves the reconstruction of the hydrogeological framework coupled to the definition of the hydrochemical and isotopic features of the aquifers. A shallow phreatic aquifer, reaching depths of about 60–80 m from the surface, and deeper aquifers containing confined groundwater, were distinguished. Groundwater generally shows mineralisation decreasing with depth; dissolved ions depict calcium-bicarbonate hydrochemical facies and stable isotopes define the recharge mechanisms, the origin of groundwater, and the hydraulic confinement of deep aquifers. The phreatic aquifer is fed by local infiltration and by streams and irrigation channels. Tritium and Carbon-14 groundwater dating indicate long residence times (on the order of thousands of years) for confined aquifers. The confined aquifers show essentially passive hydrodynamic conditions and maintain a higher piezometric level than the phreatic aquifer. This inhibits the possibility of recent water penetrating far below the surface. The hydrogeological setting of the Lomellina region displays features which are common to other sectors of the Po plain. As a consequence, the results of this study, although conducted on a restricted area, are highly illustrative of groundwater hydrodynamics in large sedimentary aquifers.