Polymetamorphic history of a relict Permian hornfels from the central Gran Paradiso Massif (Western Alps,Italy): a microstructural and thermodynamic modelling study

A petrological and thermobarometric study of the Lago Teleccio hornfelses was undertaken to reconstruct the polymetamorphic evolution and constrain the P–T conditions of Permian contact metamorphism. The Lago Teleccio metasedimentary rocks record a Variscan regional metamorphism characterized by amphibolite facies mineral assemblages including quartz, plagioclase, K‐feldspar (Kfs 1), biotite, garnet (Grt 1) and staurolite; this was followed by a late‐Variscan mylonitization event. Metamorphism of the Variscan metamorphic rocks at the contact with a Permian granitic intrusion produced static recrystallization and/or new growth of quartz, garnet (Grt 2), plagioclase, K‐feldspar (Kfs 2), cordierite, green spinel, biotite and prismatic sillimanite (Contact 1). This thermal event, which occurred at a peak pressure of 0.23–0.35 GPa, temperature of 670–700 °C and a_H2O of 0.75–1, was followed either during post‐contact metamorphism cooling or, more likely, during the early‐Alpine metamorphism by the breakdown of cordierite into an anhydrous kyanite + orthopyroxene + quartz assemblage. The poorly developed early‐Alpine eclogite facies metamorphism (Alpine 1) was characterized by relatively anhydrous mineral associations and low strain, which locally produced coronitic and pseudomorphous microstructures in metasedimentary rocks, with scanty formation of jadeite, zoisite and a new high‐pressure garnet (Grt 3). Greenschist facies retrogression (Alpine 2) was characterized by the local development of a chlorite‐ and muscovite‐bearing mineral association, suggestive of aqueous fluid incursion. In the hornfelses, the limited extent of metamorphic overprinting is suggested by the fine grain size of the Alpine mineral associations, which formed at the expense of the Permian contact metamorphic associations, and was favoured by the anhydrous mineralogy of the hornfelses.     

Topographic,pedologic and climatic interactions influencing streamflow generation at multiple catchment scales

Dominant flow pathways (DFPs) in mesoscale watersheds are poorly characterized and understood. Here, we make use of a conservative tracer (Gran alkalinity) and detailed information about climatic conditions and physical properties to examine how temporally and spatially variable factors interact to determine DFPs in 12 catchments draining areas from 3.4 to 1829.5 km² (Cairngorms, Scotland). After end‐member mixing was applied to discriminate between near surface and deep groundwater flow pathways, variation partitioning, canonical redundancy analyses and regression models were used to resolve: (i) What is the temporal variability of DFPs in each catchment?; (ii) How do DFPs change across spatial scales and what factors control the differences in hydrological responses?; and (iii) Can a conceptual model be developed to explain the spatiotemporal variability of DFPs as a function of climatic, topographic and soil characteristics? Overall, catchment characteristics were only useful to explain the temporal variability of DFPs but not their spatial variation across scale. The temporal variability of DFPs was influenced most by prevailing hydroclimatic conditions and secondarily soil drainability. The predictability of active DFPs was better in catchments with soils supporting fast runoff generation on the basis of factors such as the cumulative precipitation from the seven previous days, mean daily air temperature and the fractional area covered by Rankers. The best regression model R² was 0.54, thus suggesting that the catchments’ internal complexity was not fully captured by the factors included in the analysis. Nevertheless, this study highlights the utility of combining tracer studies with digital landscape analysis and multivariate statistical techniques to gain insights into the temporal (climatic) and spatial (topographic and pedologic) controls on DFPs. Copyright © 2011 John Wiley & Sons, Ltd.     

New radiometric dates on the lowest stratigraphical section (TD1 to TD6) of Gran Dolina site (Atapuerca,Spain)

Ages based on independent methods, such as combined ESR-U series, luminescence, and magnetostratigraphic analyses have been obtained for the upper stratigraphical section of Gran Dolina site (TD6 to TD11 levels). However, the chronostratigraphical framework of this European Paleolithic key site remains incomplete because of its great antiquity and the lack of reliable methods. This paper provides new radiometric dates by electron spin resonance applied to optically bleached quartz grains for the whole stratigraphic sequence. The results agree with the previous chronostratigraphical framework for the upper part of the stratigraphical sequence. The ages for the Homo antecessor remains from TD6 layer range between 800 and 900 ka. The lowest layers attributed to endogenous sediments (TD1) could be contemporaneous with the Sima del Elefante TE9 human bearing layer dated to 1.2 Ma. The results suggest a human occupation of possibly more than 1 Ma at the Gran Dolina site. This study confirms moreover the potential of ESR dating method applied on quartz in karstic environment.     

Development of spatially diverse and complex dune-field patterns: Gran Desierto Dune Field, Sonora, Mexico

The pattern of dunes within the Gran Desierto of Sonora, Mexico, is both spatially diverse and complex. Identification of the pattern components from remote‐sensing images, combined with statistical analysis of their measured parameters demonstrate that the composite pattern consists of separate populations of simple dune patterns. Age‐bracketing by optically stimulated luminescence (OSL) indicates that the simple patterns represent relatively short‐lived aeolian constructional events since ～25 ka. The simple dune patterns consist of: (i) late Pleistocene relict linear dunes; (ii) degraded crescentic dunes formed at ～12 ka; (iii) early Holocene western crescentic dunes; (iv) eastern crescentic dunes emplaced at ～7 ka; and (v) star dunes formed during the last 3 ka. Recognition of the simple patterns and their ages allows for the geomorphic backstripping of the composite pattern. Palaeowind reconstructions, based upon the rule of gross bedform‐normal transport, are largely in agreement with regional proxy data. The sediment state over time for the Gran Desierto is one in which the sediment supply for aeolian constructional events is derived from previously stored sediment (Ancestral Colorado River sediment), and contemporaneous influx from the lower Colorado River valley and coastal influx from the Bahia del Adair inlet. Aeolian constructional events are triggered by climatic shifts to greater aridity, changes in the wind regime, and the development of a sediment supply. The rate of geomorphic change within the Gran Desierto is significantly greater than the rate of subsidence and burial of the accumulation surface upon which it rests.     

New chronological constraints for the lowermost stratigraphic unit of Atapuerca Gran Dolina (Burgos,N Spain)

We present the results of a combined Electron Spin Resonance (ESR) and Luminescence dating study for the lowermost stratigraphic unit (TD1) of the palaeoanthropological site of Atapuerca Gran Dolina, Spain. Ten samples collected through the Main Section were dated using either the Multiple Centre (MC) ESR approach or the single-grain thermally transferred optically stimulated luminescence (SG TT-OSL) technique, both of which were applied to quartz grains. The two methods yield consistent ages, providing a robust chronostratigraphic framework for the TD1 deposits and enabling improved correlation of the magnetostratigraphic succession (comprising three intervals of normal polarity; N1 to N3, from bottom to top) with the Geomagnetic Polarity Time Scale. Specifically, the results provide a late Early Pleistocene chronology for TD1, and clearly position the deposits in the post-Olduvai time range (<1.77 Ma). The final age estimates range from 1.30 ± 0.14 Ma (TT-OSL) close to the bottom of the section to a mean ESR age of 1.05 ± 0.12 Ma (1 s.d.) for three samples from the N3 interval towards the top. Consequently, the N3 interval may confidently be correlated to the Jaramillo Subchron, while we propose a correlation of N1 and N2 with the Cobb Mountain subchron and Punaruu excursion, respectively; although we cannot exclude that these two normal intervals may correspond to other, unknown, geomagnetic events given the existing uncertainties associated with the ESR and luminescence ages.From a methodological point of view, the ESR MC approach shows that the Titanium signal provides the most reliable burial ages for TD1. In contrast, the Aluminium centre yields systematically overestimated age estimates, as a result of incomplete resetting of the signal before sediment deposition. The SG TT-OSL ages presented here are amongst the oldest published so far, and highlight the potential of the high temperature SG TT-OSL₂₉₀ approach for obtaining finite ages exceeding 1 Ma at Atapuerca.Finally, these new dating results provide key insights into the rates and nature of sedimentary processes at Gran Dolina, modifying long-standing interpretations of the cave formation and infilling dynamics. An age of at least 1.4 Ma may be inferred for the base of the sedimentary infill at the Main Section, providing minimum age constraint for the formation of the cavity and, by extension, for the intermediate level of the Atapuerca karst. The opening of the cave, which pre-dates human occupation, most likely occurred close to or slightly after 0.9 Ma. This suggests that both TD4 and TD6 archaeological levels were deposited within a relatively short time range of <100 kyr. The so-called autochthonous fluvial deposits from TD1 unit, or at least those dated in the present study, were also clearly primarily derived from outside the karst system, and were not reworked from older deposits within the karst. They experienced sufficient daylight exposure and minimum transport times within the karst system to enable consistency between the ESR and TT-OSL burial ages and the independent magnetostratigraphic evidence. Our results highlight the need to reconsider the terminology traditionally employed to differentiate the two main phases of Gran Dolina's sedimentary infill.     

Spatial and seasonal patterns of European short-snouted seahorse Hippocampus hippocampus distribution in island coastal environments

This study represents the first report on seahorses in the Macaronesian islands (North-East Atlantic), determining the spatial and seasonal abundance, population structure and physical appearance of European short-snouted seahorse Hippocampus hippocampus. Animals were surveyed off Gran Canaria Island in two bays, Melenara and Sardina del Norte, within three habitats: rocky bottom, artificial substrata and seagrass. Populations were monitored over a 5-year period (spring 2006–winter 2011) using 15-minute visual fast count (VFC) surveys. Seahorses were characterised by low abundances, small proportions of subadults and roughly equal sex ratios at each site. We aimed to determine whether environmental conditions and geographical position could explain differences in seahorse abundance and population structure between the study sites. Melenara Bay (mean sighting rate = 0.44 individuals VFC–¹; SD 0.72) offered protected environments where seahorse distribution varied with substratum type, irrespective of season. Strong hydrodynamic forces in winter affected abundance and size at exposed locations in Sardina del Norte Bay (mean sighting rate=0.21 individuals VFC^?1; SD 0.52). Our findings contribute to the scarce available knowledge about this Data Deficient species (IUCN Red List), helping to establish future conservation strategies and management recommendations for the preservation of H. hippocampus populations around Gran Canaria Island and other localities with similar coastal environments.     

A numerical study of the relative importance of wind and topographic forcing on oceanic eddy shedding by tall, deep water islands

A process-oriented, quasi-geostrophic, barotropic model has been developed with the aim of studying the relative importance of wind and topographic forcing on oceanic eddy generation by tall, deep water islands. As a case study, we chose the island of Gran Canaria. Topographic forcing was established using different intensities (weak, medium, strong, and very strong) for the oceanic current incident to the island. Wind forcing was introduced to simulate the mean wind curl observed in atmospheric tall island wakes. As observed from in situ data, the resulting wind curl consists of two cells of opposite sign which become a complementary source of vorticity at the island lee. The intensity and the shape of the two cells depend on the strength of the incident wind against the obstacle. The oceanic model was forced at three different wind (trade winds) speeds which correspond to weak, medium and strong wind intensities. Results from several numerical experiments show that in those periods where the incident wind is in the medium–strong range and the incident current speed is low (low Reynolds number), the wind forcing is the trigger mechanism for oceanic eddy generation. Eddies are spun off from the island for a lower Reynolds number (Re)/intensity of the oceanic flow (Re = 20) when compared with only topographic forcing (Re > 60). However, when the current speed is strong (high Reynolds number), the vorticity input by the wind is quickly advected by the oceanic flow and does not contribute to oceanic eddy generation. When only wind forcing is considered, only two stationary eddies are generated in the island wake. In this case, eddies of opposite sign are not sequentially spun off by the island and a Von-Kármán-like eddy street is not developed downstream of the island. Therefore, the main mechanism responsible for the development of an eddy street is the topographic perturbation of the oceanic flow by the island flanks. The wind over the island wake acts only as an additional source of vorticity, promoting the generation of an eddy street at a lower intensity of the incident oceanic flow, but not being capable of generating an eddy street without the topographic forcing.     

Chrono‐stratigraphy of the Upper Pleistocene and Holocene archaeological sequence in Cova Gran (south‐eastern Pre‐Pyrenees,Iberian Peninsula)

The Cova Gran de Santa Linya (Lleida, Spain) is a recently discovered site, with a broad chrono‐cultural sequence that contains archaeological levels dating to the Middle Palaeolithic, Early Upper Palaeolithic, Late Upper Palaeolithic, Neolithic and Early Bronze Age. We present the chronometric and stratigraphic context of these occupations, which were dated using ¹⁴C accelerator mass spectrometry and thermoluminescence. The sequence provides important indicators that aid in the reconstruction of the history of human occupation on the southern slopes of the Spanish Pyrenees over the past 50,000 years. Copyright © 2011 John Wiley & Sons, Ltd.     

Source and genesis of sulphate and phosphate–sulphate minerals in a quartz‐sandstone cave environment

Gypsum (CaSO₄·2H₂O), alunite (KAl₃(SO₄)₂(OH)₆), and rare phosphate–sulphate sanjuanite Al₂(PO₄)(SO₄)(OH) 9(H₂O) and rossiantonite (Al₃(PO₄)(SO₄) 2(OH)₂(H₂O)₁₄) have recently been identified as secondary mineral deposits in different quartz‐sandstone caves in the Gran Sabana region, Venezuela. Due to the extended time scale required for speleogenesis in the hard and barely soluble quartz‐sandstone lithology, these caves are considered to be as old as 20 to 30 My. The study of these peculiar secondary mineral deposits potentially reveals important insights for understanding the interaction between deep, superficial and atmospheric processes over thousands to perhaps millions of years. In this study, chemical and petrographic analyses of potential host rock sources, sulphur and oxygen isotope ratios, and meteorological, hydrological and geographical data are used to investigate the origin of sulphates and phospho–sulphates. The results suggest that the deposition of sulphates in these caves is not linked to the quartz‐sandstone host rock. Rather, these mineral deposits originate from an external atmospheric sulphate source, with potential contributions of marine non‐sea salt sulphates, terrestrial dimethyl sulphide and microbially reduced H₂S from the forests or peatbogs within the watershed. Air currents within the caves are the most plausible means of transport for aerosols, driving the accumulation of sulphates and other secondary minerals in specific locations. Moreover, the studied sulphate minerals often co‐occur with silica speleothems of biological origin. Although this association would suggest a possible biogenic origin for the sulphates as well, direct evidence proving that microbes are involved in their formation is absent. Nonetheless, this study demonstrates that these quartz‐sandstone caves accumulate and preserve allogenic sulphates, playing a yet unrecognized role in the sulphur cycle of tropical environments.     

Towards a simple dynamic process conceptualization in rainfall–runoff models using multi‐criteria calibration and tracers in temperate,upland catchments

Empirically based understanding of streamflow generation dynamics in a montane headwater catchment formed the basis for the development of simple, low‐parameterized, rainfall–runoff models. This study was based in the Girnock catchment in the Cairngorm Mountains of Scotland, where runoff generation is dominated by overland flow from peaty soils in valley bottom areas that are characterized by dynamic expansion and contraction of saturation zones. A stepwise procedure was used to select the level of model complexity that could be supported by field data. This facilitated the assessment of the way the dynamic process representation improved model performance. Model performance was evaluated using a multi‐criteria calibration procedure which applied a time series of hydrochemical tracers as an additional objective function. Flow simulations comparing a static against the dynamic saturation area model (SAM) substantially improved several evaluation criteria. Multi‐criteria evaluation using ensembles of performance measures provided a much more comprehensive assessment of the model performance than single efficiency statistics, which alone, could be misleading. Simulation of conservative source area tracers (Gran alkalinity) as part of the calibration procedure showed that a simple two‐storage model is the minimum complexity needed to capture the dominant processes governing catchment response. Additionally, calibration was improved by the integration of tracers into the flow model, which constrained model uncertainty and improved the hydrodynamics of simulations in a way that plausibly captured the contribution of different source areas to streamflow. This approach contributes to the quest for low‐parameter models that can achieve process‐based simulation of hydrological response. Copyright © 2009 John Wiley & Sons, Ltd.