Elemental particle size distributions. Measured and estimated dry deposition in Sfax region (Tunisia)

Mass size distribution of the crustal elements (Al, Ca, Fe, Mg, Si, Ti), anthropogenic elements (Zn, Mn, Cr, Cu, K, P, Pb) and sea elements (Na, Cl) were obtained from measurements carried out with an inertial cascade impactor in Sfax. A fitting procedure by data inversion was applied to those data. This procedure yields accurate size distributions of aerosols in the diameter range 0.1–25 μm in two different sites. In a coastal industrial site, the mass distribution of the aerosol showed a bimodal structure; and in urban area, the lower particle mode cannot be observed. The elemental dry deposition flux was calculated as a function of particle size. The element flux size distribution increased rapidly with particle size. The modelling results indicate that the majority of the crustal and anthropogenic elements flux (>90%) was due to particles larger than 3 μm in diameter.     

上海软粘土微观特性及在土体变形与地面沉降中的作用研究

对上海软粘土的颗粒及集合体成分、孔径分布、微结构、孔隙溶液与阳离子交换性作了分析 ,对固结前后的孔径变化与人工回灌对土体性质可能带来的影响作了探讨 ,从物理化学角度阐述了软粘土微观特性对土体固结变形及地面沉降的影响.     

Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.     

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

城市地区抗御地震灾害风险评估项目综述

城市地区抗御地震灾害风险评估项目系联合国在上世纪末为减轻地震灾害所实施的规模宏大，影响甚远的国际性研究项目，其宗旨是为了提高社会公众防灾意识，有效地减轻城市地区的地震灾害。这一历时2年的项目在有限的经费支持下，取得了令人瞩目的成绩。结合自贡市开展这个项目的实践。综合介绍和总结了该项目的情况及经验。     

Evapotranspiration from citrus trees growing in sandy soilunder drip irrigation with saline water

An experiment on evapotranspiration from citrus trees under irrigation with saline waterwas carried out for 4 months. Two lysimeters planted with a citrus tree in the green house wereused. One lysimeter was irrigated with saline water (NaCl and CaCl2 of 2000 mg/L equivalence,EC = 3.8 dS/m, SAR = 5.9) and the other was irrigated with freshwater using drip irrigation. Theapplied irrigation water was 1.2 times that of the evapotranspiration on the previous day.Evapotranspiration was calculated as the change in lysimeter weight recorded every 30 minutes.The lysimeters were filled with soil with 95.8% sand. The results of the experiment were as follows.(i) The evapotranspiration from citrus tree was reduced after irrigation with saline water. Theevapotranspiration returns to normal after leaching. However it takes months to exhaust the saltfrom the tree. ( ii ) To estimate the impact of irrigation with saline water on the evapotranspirationfrom citrus trees, the reduction coefficient due to salt stress (Ks) was used in this experiment.Evapotranspiration under irrigation with saline water (ETs) can be calculated from evapotranspira-tion under irrigation with freshwater (ET) by the equation ETs = Ks× ET. Ks can be expressed as afunction of ECsw. (iii) The critical soil-water electrical conductivity (ECsw) is 9.5 dS/m, beyondwhich adverse effects on evapotranspiration begin to appear. If ECsw can be controlled at below9.5 dS/m, saline water can be safely used for irrigation.     

南北地震带强震复发间隔的估计

通过对南北地震带各主要断裂带历史强震的时空特点研究 ,试图寻找出带内各主要构造带强震的复发和填充特征 ,并在此基础上研究其差异性 ,对未来各带发生强震的危险性作出估计     

两个冰期-间冰期旋回的黄土记录及其古气候意义

北京邻区枣沟、斋堂和赤峰黄土－古土壤剖面粒度和磁化率变化在幅度和相位上都有明显的差异。在两个冰期－间冰期旋回，磁化率记录具有冰量变化模式，而粒度记录具有轨道周期特点，粒度和磁化率之间的相位关系在从冰期向间冰期转换和冰期向间冰期过渡的过程中，既有滞后也有超前的表现，很难单纯以成土作用来解释。由于黄土粒度主要反映粉尘源区环境和古风场强度的变化，而磁化率主要记录的是沉积区的成壤作用，反映夏季风的强度变化，因此剖面粒度和磁化率变化的不协调说明古风场和粉尘源区变化与粉尘沉积区气候变化之间不统一。这可能意味着控制夏季风强度变化和控制冬季风强度变化的机制存在差异。     

坝上高原安固里淖粒度年纹层与环境变化

在安固里淖湖心区获取一未扰动沉积物样柱，分析发现了由冬季风搬运物与湖心沉积共同形成的粒度年纹层，建立了纹层年表，恢复了安固里淖湖区8507aB.P，以来的环境变化过程。8507-5429aB.P。冬季风活动较弱，后期的所波动；5429-3244aB.P.冬季风活动较强，3244-2494aB.P。冬季风活动减弱；2494-1165aB.P。冬季风活动略有增强；1165aB.P以来，冬季风活动减弱。安固里小淖粒度年纹层反映的冬季风变化情况与我国北方地区同期的环境变化和海平面变化有很好的对应关系。