Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be… 相似文献
An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores. 相似文献
In the study of soil erosion, specifically on detachment of soil particles by raindrop impact, kinetic energy is a commonly suggested indicator of the raindrop's ability to detach soil particles from the soil mass. Since direct measurement of kinetic energy requires sophisticated and costly instruments, the alternative approach is to estimate it from rainfall intensity. The present study aims at establishing a relationship between rainfall intensity and kinetic energy for rainfalls in Central Cebu, Philippines as a preface of a wider regional investigation.
Drop size distributions of rainfalls were measured using the disdrometer RD-80. There are two forms of kinetic energy considered here. One is kinetic energy per unit area per unit time (KER, J m−2 h−1) and the other is kinetic energy per unit area per unit depth (KE, J m−2 mm−1). Relationships between kinetic energy per unit area per unit time (KER) and rainfall intensity (I) were obtained using linear and power relations. The exponential model and the logarithmic model were fitted to the KE–I data to obtain corresponding relationships between kinetic energy per unit area per unit depth of rainfall (KE) and rainfall intensity (I). The equation obtained from the exponential model produced smaller standard error of estimates than the logarithmic model. 相似文献
The biological phenomenon commonly referred to as maternal effect occurs whenever the environment exerts an influence upon the mother that is later expressed in characteristics of her offsprings. For example, the environmental conditions experienced by a mother plant during flowering and fruiting can modify the quality of her descendants (seeds), and even interrupt their development. Between-year variation in minimum temperature and the classic, between-year variation in precipitation represent an unpredictable environment for winter blooming plants in arid zones. In this study, we investigated the effect of maternal environment (temperature and precipitation) on seed size and seed quality in F. cernua, over a 5-year period. Results indicated that the proportion of filled seeds, as well as their size, increased with higher absolute minimum temperatures during seed formation, and that, to a lesser extent, both the precipitation occurred during the same period and the annual precipitation also have a positive influence on seed size. In this way, environmental conditions prevailing during seed formation exerted a strong maternal effect on the size and quality of seeds produced and, probably also, in the developmental possibilities of F. cernua seedlings. This effect was subject to important, between-year variation. 相似文献
This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis. 相似文献
The development of subgrain boundary misorientations with strain in dry, synthetic NaCl polycrystals, deformed at elevated temperature, has been investigated using electron backscattered diffraction (EBSD). At low natural strains, up to 0.5, average misorientations of subgrain boundaries increase with strain and a power law relationship exists between strain and average misorientations. The average misorientations are strongly influenced by grain orientation, suggesting that the misorientation–strain relationship may also be texture dependent in materials with high plastic anisotropy, like NaCl. A slight grain size dependency of the average misorientations was observed. The results indicate that with suitable calibration, average subgrain boundary misorientations may offer a method for estimating the strain accommodated by dislocation creep in NaCl and thus perhaps in other geological materials, although current theories for polycrystalline plasticity imply that misorientations may also depend on stress in some situations. 相似文献
The influence of cavern’s span on surrounding rock classification is getting more and more recognition along with large span underground working’s increasingly coming forth. The authors analyse the timbering expense of cavern in jointed rock mass, the radius of plastic loosened zone and the size effect of macroscopical mechanical parameters of rock mass. Based on the complexion of depressing of surrounding rock’s stability due to increment of cavern’s span, the authors pinpoint attaching importance to the influence of cavern’s span on surrounding rock classification; and suggest reckoning the factor of cavern’s span in surrounding rock classification scientifically by studying the size effect of rock mass’s physico-mechanical parameters. 相似文献
Buntsandstein deposits generated in a slowly subsiding basin on the western margin of the Iberian Chain are represented by a stratigraphic succession of fluvial deposits less than 100 m thick (conglomerates, sandstones, and shales). Diagenetic processes in sandstones can be grouped as eodiagenetic, mesodiagenetic, and telodiagenetic. Eodiagenesis can be associated with Muschelkalk, Keuper, and probably early Jurassic times. Mesodiagenesis is probably related to Jurassic times. Diagenetic chemical reactions suggest a maximum burial less than 1.5 km and low temperatures (<120°C). Patterns of porosity reduction by compaction and cementation suggest four diagenetic stages: (1) Loss of primary porosity by early mechanical compaction; (2) early cementation (K-feldspar and dolomite); (3) dissolution of cements; and (4) framework collapse by re-compaction. These stages are manifested by the presence of two types of sandstone. Type I sandstones present high intergranular volume (mean, 30%). Type II sandstones are characterized by high compactional porosity loss and exhibit low values of intergranular volume (mean, 16.9%). Type II sandstones are associated with the dissolution of cement and later re-compaction of type I sandstones. An intermediate telodiagenetic phase is deduced and related to the sharp unconformity between Lower Cretaceous sediments and the underlying sediments. This suggests that a mechanically unstable framework collapsed during the Cretaceous, generating type II sandstones. The analyzed diagenetic paths have a wide applicability on similar marginal areas of rift basins. 相似文献
A multi-layered aquifer, typical of riverbank alluvial deposits in Korea, was studied to determine the hydrologic properties.
The geologic logging showed that the subsurface of the study site was comprised of four distinctive hydrogeologic units: silt,
sand, highly weathered and fresh bedrock layers. The electrical resistivity survey supplied information on lateral extension
of hydrogeologic strata only partially identified by a limited number of the geologic loggings. The laboratory column tracer
test for the recovered core of the sand layer resulted in a hydraulic conductivity of 5.00×10−2 cm/s. The slug tests performed in the weathered rock layer yielded hydraulic conductivities of 4.32–7.72×10−4 cm/s. Hydraulic conductivities for the sand layer calculated from the breakthrough curves of bromide ranged between 2.08×10−3 and 2.44×10−2 cm/s with a geometric mean of 6.89×10−3 cm/s, which is 7 times smaller than that from the laboratory column experiment. The trend of increasing hydraulic conductivity
with an increase in tracer travel length is likely a result of the increased likelihood of encountering a high conductivity
zone as more of the aquifer is tested. The combined hydrogeologic site characterization using hydraulic tests, tracer tests,
and column test with geologic loggings and geophysical survey greatly enhanced the understanding of the hydrologic properties
of the multi-layered alluvial aquifer. 相似文献