重油凝胶色谱制备样品中痕量镍的分析研究

研究表明微波密闭消解法对重油凝肢色谱制各样品的前处理，不造成易挥发有机金属化合物的损失，对样品无污染。采用消解前定容，配合石墨炉二次进样富集样品，可以测定样品中低至10^—9级的镍。方法应用于镍在渣油中随相对分子质量分布分析中，标准样品对照数据吻合好，相对标准偏差(RSD，n＝11)为8％。     

全球海平面变化研究新进展

综述了近10年来海平面变化研究的主要成果,分析了影响海平面变化的主要因素,探讨了海平面变化研究中存在的一些问题。结果表明：①近10年全球平均海平面上升幅度大约为2.5~3.84 mm/a,热膨胀是引起海平面上升的主因;②海平面变化具有时空分布差异——西太平洋和东印度洋地区上升最快,其值高出全球平均值的10倍以上;大西洋与太平洋30~40°N地区季节变化最明显;③将海平面季节高值时段与北半球热带气旋出现时间进行对比,发现每年8~10月份,在20~50°N的西北太平洋与北大西洋沿岸地区出现海平面最高值与热带气旋相叠加的全球危险海岸带,该地带包括中国大陆东部、日本沿海地区、美国东部海岸带、墨西哥湾地区和加勒比海地区。     

塔里木盆地喀什凹陷克拉托天然气来源分析及聚气特征

塔里木西南喀什凹陷的克拉托天然气主要表现为原油的溶解气或者湿气,甲烷含量为74.59%~85.58%,克4井和克30井天然气则为较干的湿气。克拉托天然气的δ13C1值为-41.2‰~-40.6‰,δ13C2值为-30.0‰~-27.4‰。气源对比表明克拉托天然气主要源自具有混源母质特征的中侏罗统湖相烃源岩,不同于源自石炭系烃源岩的阿克莫木天然气。喀什凹陷的中-下侏罗统烃源岩主要是由于新近系的巨厚沉积才从未成熟—低成熟阶段进入成熟—高成熟阶段,生成的油气在克拉托背斜圈闭中聚集,虽也属晚期成藏,却具有连续聚气的特征。上新世末期,喀什凹陷的周缘开始抬升,早期油气藏受到破坏,形成了现今的地表油气苗或油砂。     

海洋细菌脂肪酸的气相色谱分析

以副溶血性弧菌VP-X-3为试验对象,利用气相色谱技术分析了其细胞脂肪酸的组成和含量,以色谱峰的数量、色谱峰高及脂肪酸含量作为评价指标,探讨了不同的皂化和甲酯化条件对细菌细胞脂肪酸测定结果的影响。结果表明:皂化和甲酯化条件都对细胞脂肪酸的组成和含量产生一定的影响。较低温度皂化处理利于增加色谱峰数量和色谱峰高。甲酯化温度过高容易破坏脂肪酸,尤其是长链脂肪酸和不饱和脂肪酸的结构。高温甲酯化条件下,时间越长,甲酯化效果越差。试验得到较为理想的气相色谱前处理条件:2 mol/L NaOH-甲醇溶液2 mL,70℃水浴10 min;10%(V/V)H2SO4-甲醇溶液2 mL,70℃水浴15 min。此条件下的色谱峰的数量多达29种,色谱峰高明显高于其他处理条件下的峰高。     

一种裂缝流体因子的提出及应用

为了解决各向异性下的流体识别问题,将纵波各向异性裂缝预测以及Russell的流体因子融合到直角坐标系中,提出了一种能够同时检测裂缝发育情况以及流体性质的新的裂缝流体因子(Factor of Fluid-filled Fracture,FFF),并通过一组岩性参数检验了裂缝流体因子在裂缝预测及流体识别中的有效性.在理论研究的基础上,选取松辽盆地某地区的火成岩裂缝及流体识别研究为应用实例.通过与测井流体及裂缝信息的对比验证,裂缝流体因子能够较为准确地预测研究区裂缝和流体的分布情况,且裂缝流体因子在单井上的计算结果与单井含气饱和度吻合度较高.此外,根据实际应用效果,指出裂缝流体因子在应用中的局限性:裂缝流体因子在平面成图时受地层厚度影响较大,且无法预测裂缝方向.     

GRAPES＿GFS中三维参考大气的研究：参考态构造和实际预报试验

GRAPES GFS(Global Regional Assimilation and PrEdiction System,Global Forecast System)采用基于等温大气构造的一维参考大气,前期的研究工作已在GRAPES_GFS的动力框架中引入了三维参考大气,并通过一系列理想试验检验了新方法的正确性以及计算精度。本部分研究工作,主要针对实际资料的预报试验,对比分析了不同三维参考态给定方法的优劣,并采用气候平均法,进行夏季两个月的四维变分循环预报试验。检验结果显示,使用三维参考大气后,模式的综合预报性能得到了提升,对流层高度场、温度场的预报偏差有所减小,长期积分过程中模式质量损失较为严重的问题也得到了明显的缓解。另外,通过动能谱的对比也可以看到使用三维参考大气后,模式在高层的能量耗散明显较小,能谱变化与观测更加吻合。     

Structural controls on the formation of BSR over a diapiric anticline from a dense MCS survey offshore southwestern Taiwan

A dense seismic reflection survey with up to 250-m line-spacing has been conducted in a 15 × 15 km wide area offshore southwestern Taiwan where Bottom Simulating Reflector is highly concentrated and geochemical signals for the presence of gas hydrate are strong. A complex interplay between north–south trending thrust faults and northwest–southeast oblique ramps exists in this region, leading to the formation of 3 plunging anticlines arranged in a relay pattern. Landward in the slope basin, a north–south trending diapiric fold, accompanied by bright reflections and numerous diffractions on the seismic profiles, extends across the entire survey area. This fold is bounded to the west by a minor east-verging back-thrust and assumes a symmetric shape, except at the northern and southern edges of this area, where it actively overrides the anticlines along a west-verging thrust, forming a duplex structure. A clear BSR is observed along 67% of the acquired profiles. The BSR is almost continuous in the slope basin but poorly imaged near the crest of the anticlines. Local geothermal gradient values estimated from BSR sub-bottom depths are low along the western limb and crest of the anticlines ranging from 40 to 50 °C/km, increase toward 50–60 °C/km in the slope basin and 55–65 °C/km along the diapiric fold, and reach maximum values of 70 °C/km at the southern tip of the Good Weather Ridge. Furthermore, the local dips of BSR and sedimentary strata that crosscut the BSR at intersections of any 2 seismic profiles have been computed. The stratigraphic dips indicated a dominant east–west shortening in the study area, but strata near the crest of the plunging anticlines generally strike to southwest almost perpendicular to the direction of plate convergence. The intensity of the estimated bedding-guided fluid and gas flux into the hydrate stability zone is weaker than 2 in the slope basin and the south-central half of the diapiric fold, increases to 7 in the northern half of the diapiric fold and plunging anticlines, and reaches a maximum of 16 at the western frontal thrust system. Rapid sedimentation, active tectonics and fluid migration paths with significant dissolved gas content impact on the mechanism for BSR formation and gas hydrate accumulation. As we begin to integrate the results from these studies, we are able to outline the regional variations, and discuss the importance of structural controls in the mechanisms leading to the gas hydrate emplacements.     

高石梯—龙王庙大气田发现与四川盆地震旦—寒武系油气地质特征及成藏

简单回顾了高石梯—龙王庙大气田发现历程。高石梯—龙王庙大气田是四川盆地中西部震旦系—寒武系重要的含气领域,近年来龙王庙组的天然气勘探获得重大新突破,基于前人的研究成果,梳理川中震旦系—寒武系勘探与研究进展认为:①高石梯—龙王庙大气田自形成以来,震旦纪晚期为其所处的乐山—龙女寺古隆起整体掀斜与雏形发育,寒武纪—奥陶纪为同沉积隆升期;②大面积发育震旦系灯影组碳酸盐岩缝洞型、寒武系龙王庙组白云岩孔隙型 2 套主要含气储集层,准同生白云石化和表生岩溶叠加改造形成相对高孔渗储集体,灯影组孔隙度为3%~4%、渗透率为(0.0054~9.03)×10-3 μm2,龙王庙组孔隙度为4%~5%、渗透率为(0.0005~78.5)×10-3μm2;③四川盆地震旦系—寒武系发育2类多套烃源岩,均为腐泥型,以生油为主,发育3套优质储层,储层厚度大、分布面积广;④震旦系—寒武系天然气为典型的干气,均为有机成因,其中灯影组天然气为混源气,震旦系—寒武系天然气以原油裂解气为主;⑤生储接触广泛,震旦系—下寒武统龙王庙组油气大面积富集的关键因素是古隆起演化与烃源岩演化匹配,大型鼻状隆起背景下发育的构造、岩性及复合型多种类型圈闭为油气聚集提供了良好的空间。     

天山乌鲁木齐河源1号冰川物质平衡特征

统计了天山乌鲁木齐河源1号冰川自1980年以来冰川表面的单点物质平衡,分析了不同季节物质平衡及其冰川变化特征。研究表明,1号冰川厚度较之1959年平均减薄了9 599 mm;1997—2002年为实际观测以来连续的强负物质平衡时段,平均物质平衡为-739.6 mm /a。物质平衡与气温、降水的相关分析显示：1号冰川物质平衡主要取决于夏季平均气温的高低,二者具有较好的反相关关系（相关系数为-0.72）,而与降水的关系相对较差。20世纪80年代末以来,1号冰川退缩速度明显增大,尤以2000—2002年为甚,西支冰川退缩速度为连续的高值(退缩速度分别为6.92 m/a、6.95 m/a和6.25 m/a);东支冰川的退缩速度与高度大于4 200 m的高度带区间的平均物质平衡值有较好的相关关系（相关系数为0.65）,表明了1号冰川进退的动力主要源于冰川积累区的物质平衡大小。     

Mass movements in cave sediments: investigation of a ∼40,000-year-old guano mudflow inside the entrance of the Great Cave of Niah, Sarawak, Borneo

The West Mouth of the Great Cave at Niah in Sarawak, northwest Borneo and the North Passage that leads to the West Mouth contain large deposits of guano. The main deposit, several metres thick in places, forms the sloping floor of the entire North Passage. A mass movement deposit identified in the West Mouth, having a volume of 600 m³, originated as a guano mudflow up the North Passage in the order of 40,000 years ago. This failure of the guano slope was investigated to determine whether particular conditions or events could be identified as the most likely causes. The physical, hydrological and geotechnical properties of samples of the material were determined so that the stability of the slope could be assessed. Stability analyses showed that shearing failure of the slope would require inputs of water to the slope in quantities for which no feasible explanation can be suggested. However, the properties of the guano are similar to those of loess, indicating a high susceptibility to ‘hydrocollapse’. Very shallow failure of the slope, possibly as several smaller mudflows, could therefore have occurred due to additional water in quantities that could realistically be supplied as rainwater spray, possibly with a seismic trigger. The climate must therefore have been wetter than it is at present. These findings have implications for the interpretation of sediment deposits in other relict caves.