Dynamic,Mechanistic, and Thermodynamic Modeling of Zn(II) Ion Biosorption onto Zinc Sequestering Bacterium VMSDCM

The surface of the bacterial cells before the biosorption of Zn(II) ion has been found rough, heterogeneous, and non‐crystalline together with tremendous protrusions and negatively charged functional groups. The bacterium was characterized as rod shaped with Gram‐negative type of cell wall structure. In reaction dynamics, pseudo‐second‐order kinetics with higher linear correlation coefficient (R²) ranging between 0.97 and 0.99, lower sum of square errors (SSE) (0.035–0.081) and chi (χ²) (0.0013–0.009) provided a better explanation of sorption of Zn(II) ion on bacterium surface as compared to pseudo‐first‐order model. The removal of Zn(II) was governed by both film and intra‐particle diffusion at onset and later stage of sorption of metal ion on the surface of bacterial cells. The R² (0.92–0.94) for intra‐particle diffusion model was quite higher with lower values of SSE (9.56–16.33) and chi (χ²) (11.26–19.65) against the Bangham's model. The positive value of ΔH (16.628 × 10^?6 kJ/mol) and ΔS (5320.90 kJ/mol/K) showed that the biosorption of Zn(II) ion across liquid phase on bacterial surface was endothermic with increased randomness at solid–liquid interface. The negative values of ΔG demarcated the whole process as spontaneous in nature. In the present work, the distribution coefficient was found to be > 0.5 at various temperature ranges. At the attainment of equilibrium, the residual concentration of Zn(II) ion in liquid phase was around 0.6 mg/L, which was much below the limit described by United States Environmental Protection Agency (USEPA), i.e. 5 mg/L.     

汶川8.0级地震前地下流体长趋势变化特征讨论

通过对汶川M_S8.0地震震中周围地区震前地下流体长期观测资料的分析表明, 震前地下流体出现了长趋势变化, 其特征是时间早、 范围广, 具有协调性以及向未来震中迁移等特征, 形态主要为趋势转折、 破年变、 加速等, 其中大多数为趋势转折变化。 进一步对比研究地壳形变、 地下流体长趋势变化发现, 地壳形变和地下流体长趋势变化迁移特征一致, 地壳形变长趋势时间较早于地下流体长趋势变化时间, 形变出现张压变化与水位变化有比较密切的关系, 即形变大部分出现缓慢压性变化或张性减缓变化, 水位大部分出现缓慢上升或下降减缓变化。 最后讨论了地下流体长趋势变化机理。     

A study on the seismic performance of steel‐reinforced concrete frame‐concrete core wall high‐rise mixed structure by large‐scale shaking table tests and numerical simulations

This paper reports a study for the seismic performance of one large‐scaled (1/15) model of 30‐story steel‐reinforced concrete frame‐concrete core wall mixed structure. The study was implemented by both shaking table tests, in which the similarity ratio for lateral and gravitational accelerations was kept to 1:1, and numerical nonlinear dynamic analysis. The test observations presented herein include story displacement, interstory drift, natural vibration periods, and final failure mode. The numerical analysis was performed to simulate the shaking table test procedure, and the numerically obtained responses were verified by the test results. On the basis of the numerical results, the progressions of structural stiffness, base shear, and overturning moment were investigated, and the distributions of base shear and overturning moment between frame and core wall were also discussed. The test demonstrates the seismic performance of the steel‐reinforced concrete frame‐core wall mixed structure and reveals the potential overturning failure mode for high rise structures. The nonlinear analysis results indicate that the peripheral frames could take more shear forces after core wall damaged under severe earthquakes. Copyright © 2013 John Wiley & Sons, Ltd.     

A meta‐analysis of reef island response to environmental change on the Great Barrier Reef

Reef islands on the Great Barrier Reef are influenced by a range of environmental factors. A meta‐analysis of 103 islands is presented to express variation in island size (area and volume) as a function of latitudinal and cross shelf gradients in regional oceanographic factors (exposure to incident waves, tidal range and tropical cyclone frequency) and local physical factors (position on the shelf, area, length and depth of supporting reef platform, vegetative cover). Models performed well for unvegetated sandcays (R² = 0.89), vegetated sandcays (R² = 0·72) and low wooded islands (R² = 0.78), with a moderate level of variation explained when all islands were simultaneously regressed (R² = 0.58). Future island dynamics were simulated for anticipated changes in cyclone regime, wave activity and sea level. For 38 islands mapped on the 1973 Royal Society and Universities of Queensland Expedition to the Northern Great Barrier Reef, change over the same 22 year period (1973–1995) was determined and the relative magnitude of observed and modelled changes was compared and found to be consistent through rank correlation analysis (Γ = 0.84 for unvegetated sandcays, Γ = 0.81 for vegetated sandcays). Simulations of island area or volume change from 2000 to 2100 indicated that under a 30% decrease in tropical cyclone activity, unvegetated sandcays continue to accrete at a lower rate, whereas all island types erode under a 38% increase in tropical cyclone activity. Vegetated sandcays initially accrete at higher levels of cyclone activity, entering an erosive state with a 60% increase in activity. Low wooded islands are unresponsive to environmental changes modelled. A sensitivity analysis of vegetated and unvegetated sandcays indicated that the presence of vegetation increases the tropical cyclone activity threshold at which islands begin to erode. Greatest sedimentary losses occur within the central band of high cyclone activity between Cooktown and Mackay. Copyright © 2015 John Wiley & Sons, Ltd.     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.     

Elastic fields in two joined transversely isotropic media of infinite extent as a result of rectangular loading

This paper presents the closed‐form solutions for the elastic fields in two bonded rocks induced by rectangular loadings. Each of the two bonded rocks behaves as a transversely isotropic linear elastic solid of semi‐infinite extent. They are completely bonded together at a horizontal surface. The rectangular loadings are body forces along either vertical or horizontal directions and are uniformly applied on a rectangular area. The rectangular area is embedded in the two bonded rocks and is parallel to the horizontal interface. The classical integral transforms are used in the solution formulation, and the elastic solutions are expressed in the forms of elementary harmonic functions for the rectangular loadings. The stresses and displacements in the rocks induced by both the horizontal and vertical body forces are also presented. The numerical results illustrate the important effect of the anisotropic bimaterial properties on the stress and displacement fields. The solutions can be easily implemented for numerical calculations and applied to problems encountered in rock mechanics and engineering. Copyright © 2011 John Wiley & Sons, Ltd.     

The Characteristics and Causes of Land Subsidence in Tanggu Based on the GPS Survey System and Numerical Simulation

Land subsidence is a severe hazard threatening Tanggu, a flat lowland area, and evidences of land subsidence can be seen throughout the city. A new reasonable GPS network was set up in this area from 2008 to 2010. The monitoring data show that land subsidence was serious and two main subsidence cones were obviously formed in the region. One emerged at Hujiayuan, with the maximum rate reaching 60 mm/a, and the influence region enlarged prominently from 2005 to 2010. The other one occurred at Kaifaqu, which became obvious only after 2005, and it showed a decreasing tendency with time. To analyze the causes of ground settlement, a correlation between groundwater withdrawal and land subsidence was firstly made. The results confirmed that over-exploitation of groundwater was the major cause for the severe settlement in Hujiayuan. Meanwhile, the subsidence of Kaifaqu was also related to groundwater withdrawal before 2005. However, the relationship became unconspicuous after 2005. To find the cause of this abnormity, a three-dimensional finite element numerical model, coupled with groundwater flow and subsidence, was built. The simulation results indicate that the subsidence induced by high-rise buildings is serious, but the affected range is limited and it also shows a decreasing trend with time, corresponding to the subsidence characteristics at Kaifaqu. Therefore, more attention should be paid to this hazard induced by engineering construction besides groundwater withdrawal, as more high-rise buildings are under construction in Tanggu.     

Integration of the life of field seismic data with the reservoir model at the Valhall Field‡

The frequent time‐lapse observations from the life of field seismic system across the Valhall field provide a wealth of information. The responses from the production and injection wells can be observed through time‐shift and amplitude changes. These observations can be compared to modelled synthetic seismic responses from a reservoir simulation model of the Valhall Field. The observed differences between the observations and the modelling are used to update and improve the history match of the reservoir model. The uncertainty of the resulting model is reduced and a more confident prediction of future reservoir performance is provided. A workflow is presented to convert the reservoir model to a synthetic seismic response and compare the results to the observed time‐lapse responses for any time range and area of interest. Correlation based match quality factors are calculated to quantify the visual differences. This match quality factor allows us to quantitatively compare alternative reservoir models to help identify the parameters that best match the seismic observations. Three different case studies are shown where this workflow has helped to reduce the uncertainty range associated with specific reservoir parameters. By updating various reservoir model parameters we have been able to improve the match to the observations and thereby improve the overall reservoir model predictability. The examples show positive results in a range of different reservoir modelling issues, which indicates the flexibility of this workflow and the ability to have an impact in most reservoir modelling challenges.     

Discriminating between pore‐filling load and bed‐structure load: a new porosity‐based method,exemplified for the river Rhine

Sediments contained in the river bed do not necessarily contribute to morphological change. The finest part of the sediment mixture often fills the pores between the larger grains and can be removed without causing a drop in bed level. The discrimination between pore‐filling load and bed‐structure load, therefore, is of practical importance for morphological predictions. In this study, a new method is proposed to estimate the cut‐off grain size that forms the boundary between pore‐filling load and bed‐structure load. The method evaluates the pore structure of the river bed geometrically. Only detailed grain‐size distributions of the river bed are required as input to the method. A preliminary validation shows that the calculated porosity and cut‐off size values agree well with experimental data. Application of the new cut‐off size method to the river Rhine demonstrates that the estimated cut‐off size decreases in a downstream direction from about 2 to 0·05 mm, covariant with the downstream fining of bed sediments. Grain size fractions that are pore‐filling load in the upstream part of the river thus gradually become bed‐structure load in the downstream part. The estimated (mass) percentage of pore‐filling load in the river bed ranges from 0% in areas with a unimodal river bed, to about 22% in reaches with a bimodal sand‐gravel bed. The estimated bed porosity varies between 0·15 and 0·35, which is considerably less than the often‐used standard value of 0·40. The predicted cut‐off size between pore‐filling load and bed‐structure load (D_c,p) is fundamentally different from the cut‐off size between wash‐load and bed‐material load (D_c,w), irrespective of the method used to determine D_c,p or D_c,w. D_c,w values are in the order of 10^?1 mm and mainly dependent on the flow characteristics, whereas D_c,p values are generally much larger (about 10⁰ mm in gravel‐bed rivers) and dependent on the bed composition. Knowledge of D_c,w is important for the prediction of the total sediment transport in a river (including suspended fines that do not interact with the bed), whereas knowledge of D_c,p helps to improve morphological predictions, especially if spatial variations in D_c,p are taken into account. An alternative to using a spatially variable value of D_c,p in morphological models is to use a spatially variable bed porosity, which can also be predicted with the new method. In addition to the morphological benefits, the new method also has sedimentological applications. The possibility to determine quickly whether a sediment mixture is clast‐supported or matrix‐supported may help to better understand downstream fining trends, sediment entrainment thresholds and variations in hydraulic conductivity.     

Occurrence and Chemical Compositions of Amphiboles in Altered Dioritic Rocks of Laiwu Skarn‐Type Iron Deposit in West Shandong Area,China

The Laiwu Fe deposit is the largest skarn‐type deposit in West Shandong in China, with an estimated reserve of 290 Mt of iron ore. Here, we investigate the occurrence and chemical composition of amphiboles in altered dioritic rocks of this deposit. Three generations of amphibole group minerals were identified in these rocks. The first type (Type 1) is a hornblende with a generally euhedral crystal shape, 150–500 μm in size, and dominantly occurs in the host monzonite. The second type (Type 2) of hornblende occurs as fine grains (<100 μm) or concentric rims, less than 50 μm in thickness, around the Type 1 hornblende. The third type (Type 3) of amphibole is anhedral actinolite occurring along the boundary or the cracks of the Type 1 or 2 hornblende grains. The Type 1 hornblende has higher FeO (12.5–15.6 wt.%) and lower MgO contents (11.2–14.6 wt.%) than the Type 2 hornblende, which has an FeO content ranging from 8.8 to 10.5 wt.% and MgO content ranging from 14.2 to 17.1 wt.%. The Type 3 actinolite shows the lowest FeO (4.6–6.4 wt.%) and highest MgO (19.8–21.2 wt.%) contents. We infer that the Type 2 hornblende formed from Fe‐rich hydrothermal fluids released during rapid upwelling of the crystallizing magma. The fluids were relatively reduced and enriched in Fe. The Type 3 actinolite formed by coupled dissolution and reprecipitation, and its formation is one of the features denoting Fe‐enrichment events. Our study of these types of amphibole provides insights into the ore formation process.