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41.
Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230
Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream (pH 2.98-3.40), 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization. 相似文献
42.
Structural changes during dehydration and subsequent decomposition in thaumasite Ca3Si(SO4)(CO3)(OH)6·12 H2O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P63 space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass. 相似文献
43.
Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock
fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then
introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity
index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model
are analysed. The average number of intersections per fracture, Xf, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that
Xf is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity
index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a
practical example is used to demonstrate the method of computing the connectivity index. 相似文献
44.
蒋承菘 《中国地质灾害与防治学报》2006,17(3):96-97,102
文章提出另一类型地质灾害,即化学型地质灾害的定义及其分类。并认为化学型地质灾害不像物理型地质灾害那样发生瞬时灾害,而有一个延缓过程,但是一旦发生,难于挽救。化学型地质灾害体的主体是化学元素,开展地球化学调查,研究化学元素的赋存规律、土壤及沉积物承受各类元素的极限、各类元素活化的条件是揭示诱发化学型地质灾害机理的关键。因此要十分重视与加强化学型地质灾害的调查、研究、监测与治理工作。 相似文献
45.
提出快速获得航空影像并及时制作DOM、DLG的一种手段.介绍遥控飞艇数字摄影系统的工作原理,探讨存在的问题. 相似文献
46.
本文首次对藏南地区金和锑矿床(点)地质特征、成因类型和空间分布特点进行了总结,对金和锑成矿作用与中新生代构造一岩浆活动的关系进行了论证,对区域地壳演化过程中金和锑成矿动力学机制进行了讨论。该区的金和锑矿床(点)可按容矿围岩划分为:①变质岩为主要容矿围岩矿床(点),包括金和金一锑矿床(点);②沉积岩为主要容矿围岩矿床(点),包括金、锑、金一锑和锑多金属矿床(点);③火山岩为主要容矿围岩矿床(点),以金一银矿床为代表。根据金和锑矿床(点)空间分布特点和地质特点,将本区划分为4个矿化集中区:拉昂错一马攸木一帕羊金矿化集中区(A),然勒金和锑矿化集中区(B),洛扎一措美锑矿化集中区(C)和邛多江金一锑矿化集中区(D)。各矿化集中区内大多数金和锑矿床(点)与燕山晚期~喜马拉雅早期富碱火成岩具密切时空分布关系,它们是古板块对接碰撞期和碰撞期后大规模构造一岩浆活动的产物。近东西向挤压性和南北向张性断裂交汇部位以及富碱火成岩发育区是寻找金和锑矿床(点)的有利场所。 相似文献
47.
新疆雷暴天气过程分型 总被引:5,自引:0,他引:5
对新疆39a雷暴天气资料的普查,得到367次雷暴天气过程,归结出4种天气形势,雷暴天气由冷锋和中尺度高压造成。 相似文献
48.
工程场地的特征与工程地质分区 总被引:1,自引:0,他引:1
工程场地与城市在空间尺度上相去甚远 ,但工程场地所具备的与环境行为相近的共性 ,使其属性分析可以推广应用到城市建设所面对的整个工程地质环境。从这一意义上说 ,工程场地是整个城市宏观工程地质环境的微观单元 ,众多微观单元的组合构成了环境的宏观总体。为此 ,工程场地的三大属性特性、适宜性、稳定性 ,可以作为城市工程地质环境分析中分析方法的基础。从工程场地分析推广到城市工程地质环境分析 ,还将有助于保证城市工程地质环境分析的定量化水平。 相似文献
49.
The permeability of sedimentary rocks during triaxial compression tests was investigated to relate it to the complete strain–stress process. It was found that the permeability was not constant, but varied with the stress and strain states in the rocks. Prior to the peak strength, the permeability decreases with increasing load. A dramatic increase in permeability occurs during the strain softening period. In the present study, in situ measurements of fluid flow and pressure in floor strata was carried out in a double longwall mining face in the Yangzhuang colliery. These measurements show that both the strata pressure and the position with respect to the mining face influence the hydrogeologic properties. The permeability increased in the floor strata behind the mining face because those mining induced fractures opened as the strata pressure decreased. To better understand this change in hydraulic behavior around the mining faces, 3-D numerical modeling was carried out. The model provides the general picture of the stress distribution and failure zone both in the floor and roof strata. The field and model results demonstrate the importance of changes in the stress and strain states on the hydrogeology of a site. 相似文献
50.