Constraints on anthophyllite formation in thermally metamorphosed peridotites from southwestern Japan

Anthophyllite or another species of Mg‐amphibole commonly occurs in an intervening zone between the higher grade orthopyroxene zone and lower grade talc zone in progressively metamorphosed peridotites. However, the anthophyllite zone is absent in some of the thermally metamorphosed peridotite complexes in SW Japan despite the existence of the other zones. A comparative study presented here reveals similarities in rock composition and metamorphic pressure–temperature conditions at high‐grade zones between the metaperidotite complexes, and differences in the following respects. The metaperidotite complex that contains an anthophyllite zone has less abundant magnetite and olivine that is more homogeneous than the complex where the anthophyllite zone is absent. It is likely that the degree of cation diffusion in olivine crystals depends on duration of heat retention in metaperidotites during thermal metamorphism, which is supported by the variation in mineralogy of intrusive rocks and pelitic hornfelses surrounding the metaperidotites, and by calculations based on a simplified model of thermal conduction. The long duration of heat retention looks to be a necessary condition for the formation of anthophyllite crystals, which have a sluggish nucleation rate. In addition, the circulation of reducing fluids during prolonged metamorphism likely promoted the decomposition of magnetite and the growth of anthophyllite, into which iron is preferentially distributed. This study cautions about kinetic controls and redox conditions for anthophyllite formation in metaperidotites.     

The geochemical and Sr–Nd isotopic characteristics of Eocene to Miocene NW Anatolian granitoids: Implications for magma evolution in a post-collisional setting

Early Eocene to Early Miocene magmatic activity in northwestern Anatolia led to the emplacement of a number of granitoid plutons with convergent margin geochemical signatures. Granitoid plutons in the area are mainly distributed within and north of the suture zone formed after the collision of the Anatolide-Tauride platform with the Pontide belt. We present geochemical characteristics of three intrusive bodies in the region in order to identify their source characteristics and geodynamic significance. Among these, the Çataldağ and Ilıca-Şamlı plutons are located to the north and the Orhaneli pluton is located to the south of the IAESZ (Izmir-Ankara-Erzincan Suture Zone). The plutons are calc-alkaline, metaluminous, and I-type with compositions from granite to monzonite. They display clear enrichments in LILE and LREE and depletions in HFSE relative to N-MORB compositions and have high ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd ratios.The results of theoretical Fractional Crystallization (FC) model show that the samples are affected by fractionation of K-feldspar, plagioclase, biotite and amphibole. Assimilation and Fractional Crystallization (AFC) modeling indicates that the r value, the proportion of variable contamination to fraction, is high, indicating significant crustal contamination in the genesis of granitoid magmas. Combined evaluation of isotopic and trace element data indicates that the granitoids are the products of mantle-derived mafic magmas variably differentiated by simultaneous crustal contamination and fractional crystallization in lower to middle crustal magma chambers in a post-collisional setting.     

Crystallization Process of Calcium Sulfate Dihydrate in Gypsum Type Brine System

正1 Introduction Calcium sulfate deposition is one of the most important and serious problems faced by heat transfer equipment during operation(Pavlos et al.,1999;Liu et al.,1996).The crystallization of calcium sulfate is known as a major     

The Research Advance and Trend Analysis of the Crystallization Cleaning Technology of Salt Lake Brine Pump in China

正Salt Lake brine pump is one of the key equipment in salt lake brine extraction device.As the salt lake brine is a kind of high concentration solution with a variety of chemical constituents,the flow and agitation of saturated     

阜新-义县盆地义县旋回岩浆演化规律及成因探讨

岩石地球化学特征研究表明,阜新-义县盆地义县旋回火山岩属于同源钙碱性火山岩系,岩浆演化序列为基性→中性→中酸性→酸性。火山岩化学成分变化以岩浆结晶分异占主导地位,岩浆分异较好。火山岩形成于大陆边缘活动带,岩浆来源于壳源。     

扬子西缘丹巴水子乡辉石岩年代学和岩石成因研究SCIEI北大核心CSCD

扬子克拉通西缘在~260Ma发生短期内大规模峨眉山玄武岩溢流喷发。攀西地区发育的镁铁-超镁铁质岩被广泛认为是峨眉山大火成岩省的产物,但在北端松潘-甘孜岩区一直缺乏该类岩石的报道。本文首次报道扬子西缘丹巴水子乡单斜辉石岩的准确年龄,其锆石LA-ICP-MS U-Pb加权平均年龄为260.7±3.3Ma,表明其为峨眉山大火成岩省北端松潘-甘孜岩区镁铁-超镁铁质岩的组成部分。通过与攀枝花钒钛磁铁矿含矿岩体边缘相带苦橄岩和上部相带浅色辉长岩进行锆石微量元素对比显示,水子乡单斜辉石岩具有相近的高氧逸度,其ΔQFM为0~3,Ce_(N)/Ce_(N)平均为~30,该性质可能同样源自扬子西缘洋壳板片俯冲交代形成的较高氧逸度地幔源区。尽管如此,水子乡辉石岩体并未因高氧逸度而有明显的含钛磁铁矿饱和结晶,可能由其较低结晶分异程度造成。相比之下,攀枝花岩体经历了更高程度的含钛磁铁矿和斜长石分离结晶作用,伴随大规模的钒钛磁铁矿成矿。     

西天山哈拉达拉辉长岩的Fe-Ti富集机制及其构造意义

特克斯哈拉达拉辉长岩体是西南天山出露规模最大的层状基性-超基性侵入杂岩体,其富含Fe-Ti氧化物(含量高达15%)。哈拉达拉辉长岩中的橄榄石具有较低的Fo值(64~75),斜长石主要为中-拉长石,单斜辉石相对低Mg^#(0.66~0.87),属于次透辉石或普通辉石,总体上显示出较高的岩浆演化程度。Fe-Ti氧化物以钒钛磁铁矿为主(TiO₂=0.8%~20.6%;V₂O₃=0.10%~0.83%),常与钛铁矿呈矿物对共生或出溶钛铁矿。晚期的云母矿物均围绕他形的Fe-Ti氧化物生长,主要为富MgO的金云母,少量属于黑云母;大部分云母成分富含F、Cl(F+Cl高达3.14%),指示岩浆形成于贫水环境。哈拉达拉辉长岩体的主量元素成分变化很大(Mg^#=0.48~0.73),橄榄辉长岩主要受橄榄石和斜长石的结晶分异/堆晶作用影响,而辉长岩的成分变化主要受控于斜长石和Fe-Ti氧化物的堆晶作用。哈拉达拉岩体的Fe-Ti氧化物主要为岩浆正常结晶分异作用的结果,该体系具有较低氧逸度、贫水的特点,其地幔源区的熔融程度较高,可能是塔里木地幔柱在天山造山带这一构造薄弱带的早期岩浆活动。     

湖北黄陵球状花岗闪长岩的发现及其岩相学特征

在扬子陆块核部黄陵地区发现具球状构造的花岗闪长岩。岩石产于新元古代斑状花岗闪长岩与石英闪长岩之间,出露面积极小。球状花岗闪长岩岩体由主岩、球状体及球间基质三部分组成,球状体呈圆形、椭圆形及不规则状,由球核和同心球壳组成,球体大小多为5~12cm。依据球壳及球核的差异,可大致分为具有多壳层同心结构、具单壳层结构、无明显壳层结构3种类型的球状体。单壳层球壳由角闪石、黑云母等暗色矿物含量高的暗色层组成,具放射状构造;多壳层球壳由含角闪石、黑云母等暗色矿物的暗色层和基本不含或含少量暗色矿物、以斜长石为主的浅色层组成韵律层,具梳状、放射状构造;球核成分可以是同源岩浆组分,也可以是异源捕虏体。单壳层球体,球核、球壳、基质的斜长石牌号依次为36、32、26,酸性程度不断增加,内部呈放射状生长,反映其可能由内向外经岩浆结晶作用形成。初步认为多壳层球体球壳富韵律的变化为富含气水热液的岩浆在动荡的环境下结晶形成,球壳中矿物结晶顺序可能由外向内,核部结晶时间相对更长。     

东天山红包山-碱泉-带镁铁超镁铁质岩体的地球化学特征与岩石成因

红包山-碱泉一带镁铁-超镁铁质岩体位于东天山卡瓦布拉克地区,岩体呈脉状或透镜状产出,出露面积约8km2。岩石类型主要为纯橄榄岩、橄榄岩、单辉橄榄岩等。地球化学数据表明,该区岩体具高Mg#的特征,属镁质超基性岩。岩石稀土元素为平缓右倾型配分模式,稀土元素总量(0.96×10-6~10.02×10-6)较低,轻重稀土元素组间分馏较强((La/Yb)N=2.14~4.08),δEu变化于0.63~1.08,可能与斜长石的结晶有关。微量元素蛛网图表明,岩石具富集大离子亲石元素Rb、Sr和高场强元素U、Pb及LREE,而亏损高场强元素Nb(Ta)、Hf、Ti的特征。主微量元素等地球化学相关图解说明,红包山-碱泉一带岩体原生岩浆为幔源的钙碱性玄武质岩浆,成岩作用以岩浆结晶分异为主导,并受到壳源物质的同化混染作用。     

内蒙古乌拉盖苏木球状酸性浅成岩的发现及其岩相学特征

在大兴安岭乌拉盖地区发现酸性浅成球状岩石组合。球状岩石由主岩、球状体和球间基质组成。依据球状体球壳及球核的差异,可分为无壳层球粒、单壳层球状体和多壳层球状体3 种类型。无壳层球粒分布于碱性流纹斑岩和微细粒花岗岩中,直径0.5~2mm,无核,由放射状长英质和铁质纤维及针柱状碱性闪石相间分布构成。单壳层球状体分布于碱性流纹斑岩中,直径0.5~2cm,内部具放射状、扇形结构,由多个球粒相互连接构成,外壳较薄,表现为针柱状碱性闪石沿球状体切向方向环绕。多壳层球状体分布于碱性流纹斑岩中,直径2~8cm,球状体由内、中和外部层构成：内部层具圈层结构,由长英质和暗色矿物隐晶集合体及角闪石组成;中部层由大量叠瓦式、雨滴状气孔杏仁体及其间的长英质隐晶集合体组成;外部层为云朵状、棉絮状、放射状长英质隐晶集合体组成。初步认为本套球状岩石为张性环境下岩浆结晶作用形成,晚期气水热液活动强烈,球状体中矿物结晶顺序由内向外。