井间地震串联滤波波场分离方法

本文根据井间地震波场响应以及多种波场分离方法的性能，采用基于Ｋ－Ｌ变换的特征向量滤波与中值滤波相结合的串联滤波方法分离井间地震观测到的上、下行反射波。数值计算结果表明：在波场分离过程中，由于同时综合考虑了地震波能量主分量分布以及反射波同相轴时差两个参数，使得分离效果明显、处理更为简便，具有滤波特征矢量的选取条件更为宽松、无需精确确定拉平轴的时间等特点。     

Observations of particle movement in a monitoring well using the colloidal borescope

The colloidal borescope consists of a set of lenses and miniature video cameras capable of observing natural particles in monitoring wells. Based on field observations of these particles, it appears possible to measure in situ groundwater velocity in a well bore. Field observations have shown that directional measurements using the colloidal borescope are generally in good agreement with expected flow directions. However, the magnitude of flow velocity is higher compared with values based on conventional test methods. High relative flow velocities, even after correction factors have been applied to compensate for well bore effects, are believed to be due to preferential flow zones in the surrounding aquifer. Low flow zones exhibit swirling multidirectional flow that does not allow for a linear velocity measurement. Consequently, groundwater flow velocities measured by the colloidal borescope in heterogeneous aquifers will be biased toward the maximum velocity values present in the aquifer. A series of laboratory experiments was conducted to assess the reliability of the instrument. Based on this work, a seepage velocity correction factor ( ) of 1–4 was found for quantifying groundwater seepage velocity in the adjacent aquifer from observations in a well bore. Laboratory measurements also indicate that preferential flow in the surrounding aquifer dominates flow in the well. Results of this work suggest the possibility of quantifying higher-flow velocities associated with preferential flow zones in the subsurface.     

一种新的流动注射在线共沉淀技术的研究及应用

建立了应用流动注射在线共沉淀分离富集火焰原子吸收法测定天然水样中痕量铬的价态分析方法。利用铬（Ⅲ）在碱性条件下与氢氧化镧形成共沉淀而与共存离子分离并得到富集，沉淀不需过滤，直接用稀盐酸从编织反应器（ＫＲ）中溶解并洗脱下来，用原子吸收测定。本体系的浓集倍率２２，检出限（３σ）０．８μｇ／Ｌ，相对标准偏差（ｎ＝１１）２．７２％，用水标样考察，分析结果与推荐值相符。该方法成功地用于天然水中铬的快速测定。     

地质样品中微量金银的在线分离富集方法

提出用ＶＳ－Ⅱ型强碱性阴离子交换纤维定量富集、硫脲解脱，流动注射在线分离富集—火焰原子吸收光谱法测定地质样品中痕量金银的分析方法。该方法检出限低，金为１．４μｇ／ｍＬ，银为０．３５μｇ／ｍＬ，相对标准偏差均小于２％，采样频率为１２０次／ｈ，用于地质样品中痕量金银的直接测定，结果令人满意。     

川陕丁家林金矿区探矿权的评估

为准确、客观估价丁家林金矿区探矿权价值，根据矿区地质报告中提交的储量级别、矿体控制程度和工程质量，确定了基础和可采储量、生产规模、矿山服务年限、贴现率、有关实物工作量等6项参数。综合运用贴现现金流量和重置成本法对探矿权进行评估，对达到详查程度的基础储量采用贴现现金流量法，控制程度低的资源量采用重置成本法，二者之和综合反映探矿权的价值。此方法适用于地质工作程度不均衡矿区的探矿权评估，贴现现金流量法要充分考虑储量的可信度和获利临界品位．重置成本法关键是准确确定有关的实物工作量。     

Seepage driving effect on deformations of San Fernando dams

In the process of flow deformation of an earth dam, the seepage force inside the dam plays a role as a driving force. The seepage force acts just like the gravitational force in terms of pushing soils away from their original locations after liquefaction is triggered. This paper draws attention to this seepage driving effect by presenting a set of fully coupled finite element analyses on the well-known San Fernando dams, with the objective of evaluating the impact of this seepage effect. The results indicate that while this effect is always there, its practical significance depends on a number of factors. In the case of the upper San Fernando dam, which experienced a significant, but restricted, downstream movement during the 1971 earthquake, the seepage driving effect was indeed significant. On the contrary, for the lower dam, which failed and slid into the upstream reservoir during the same earthquake, this seepage effect was relatively less pronounced. The detailed results of the analyses reveal the likely mechanisms of failure and deformation of the two dams and the likely cause behind the difference between their responses during the earthquake.     

岩层移动动态过程的离散单元法分析

采动覆岩动态发展过程受地质、采矿条件诸多因素的影响,是一个十分复杂的时空过程。通过离散单元法数值模拟,揭示了综放开采条件下采场上覆岩层动态发展规律,特别是覆岩离层缝隙的分布规律、发展形态、空间位置以及与地质采矿条件的关系,揭示了工作面推进过程中,采场上覆岩层中重新分布的应力大小、方向及其发展变化规律,该应力的存在和变化规律是确定井下开采方法、支护方式的依据。     

热液中铅、锌、银共生分异的热力学探讨

通过元素基本性质的对比以及热力学计算分析，探讨了热液中银、铅、锌的共生分异机制。在酸性至近中性条件下，氯配合物是它们在热液中的存在形式，其中锌氯配合物最稳定；在近中性到碱性条件下，硫氢配合物占主导地位，此时，银硫氢配合物相对最稳定。温度下降、[Cr]降低、pH升高及f(O2)降低，引起银、铅、锌配合物溶解度减小，发生沉淀分离；对于硫氢配合物，其稳定性主要受pH及还原硫浓度的影响。因此，配合物的不同存在形式以及配合物稳定性之间的差异，使得它们对热液条件的改变做出不同的响应，从而导致了热液中银、铅、锌在成矿过程中的共生分异。     

Plastic flow strength of jadeite and diopside investigated by microindentation hardness tests

Microindentation hardness tests were performed on jadeite and diopside, being end members of the omphacite solid solution series. At temperatures between 300 and 750 °C, the hardness of jadeite ranges from 7.4 to 8.5 GPa, that of diopside from 4.9 to 6.1 GPa. Jadeite is significantly stronger than diopside in the low-temperature plasticity regime. Normalization of the hardness-derived yield stress with respect to the shear modulus considerably reduces the strength contrast. The normalized Peierls stress is identical for jadeite and diopside. This indicates that jadeite and diopside belong to the same isomechanical group. The hardness-derived yield stress for jadeite as well as for diopside is used to estimate flow law parameters for the low-temperature plasticity regime.     

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.