Discriminating the long distance dispersal of fine ash from sustained columns or near ground ash clouds: The example of the Pomici di Avellino eruption (Somma-Vesuvius,Italy)

Ash samples from tephra layers correlated with the Pomici di Avellino (Avellino Pumice) eruption of Somma-Vesuvius were collected in distal archives and their composition and particle morphology investigated in order to infer their behaviour of transportation and deposition. Differences in composition and particle morphologies were recognised for ash particles belonging to the magmatic Plinian and final phreatomagmatic phases of the eruption. The ash particles were dispersed in opposite directions during the two different phases of the eruption, and these directions are also different from that of coarse-grained fallout deposits. In particular, ash generated during magmatic phase and injected in the atmosphere to form a sustained column shows a prevailing SE dispersion, while ash particles generated during the final phreatomagmatic phase and carried by pyroclastic density currents show a general NW dispersion. These opposite dispersions indicate an ash dispersal influenced by both high and low atmosphere dynamics. In particular, the magmatic ash dispersal was first driven by stratospheric wind towards NE and then the falling particles encountered a variable wind field during their settling, which produced the observed preferential SE dispersal. The wind field encountered by the rising ash clouds that accompanied the pyroclastic density currents of the final phreatomagmatic phase was different with respect to that encountered by the magmatic ash, and produced a NW dispersal. These data demonstrate how ash transportation and deposition are greatly influenced by both high and low atmosphere dynamics. In particular, fine-grained particles transported in ash clouds of small-scale pyroclastic density currents may be dispersed over distances and cover areas comparable with those injected into the stratosphere by Plinian, sustained columns. This is a point not completely addressed by present day mitigation plans in case of renewal of activity at Somma-Vesuvius, and can yield important information also for other volcanoes potentially characterised by explosive activity.     

The volcanic acidification of glacial Lake Caviahue,Province of Neuquen,Argentina

Lake Caviahue (northern Patagonia, Argentina) is a large glacial lake acidified by volcanic fluids from Copahue volcano. The lake and the feeding rivers were sampled annually from 1997 till early 2006, including the eruptive period of 2000. Lake Caviahue waters evolved over time, with the most concentrated waters in 2000 during the eruptive period, followed by gradual dilution that was interrupted by renewed acidification in 2003–2004. Inversion of the lake water data and application of a dynamic non-steady state model for the lake provides our best quantitative estimates for the variation in element fluxes over the 9-year period. The model flux results agree well with most of the measured fluxes. The Copahue hydrothermal system had gently declining element fluxes between 1997 and mid-1999, although the lake was still becoming more concentrated. About 2–3 months before the 2000 eruption, element fluxes increased strongly, but the hydrothermal fluxes almost shutoff directly after the main eruptive events. The fluxes of several elements recovered post-2001, with an increase in element fluxes in 2003–2004; the lake became more dilute between 2004 and 2006. The intrusion of new magma into the hydrothermal system just prior to the 2000 eruption led to enhanced water rock interaction, with higher concentrations of the rock forming elements in the fluids, and the hot spring flow rate increased as a result of the higher pressure in the reservoir. The fluids became saturated in alunite and jarosite, and they were already saturated with anhydrite. Precipitation of these minerals possibly led to a decreased permeability of the hydrothermal reservoir, leading to the strongly reduced element fluxes just after the eruption. In addition, K, Al and S were retained in the newly precipitated minerals as well, further diminishing their export. The acidification in 2003–2004 may have resulted from a new small intrusion of magma or resulted from seismic activity that created new permeability and fresh rock surfaces for water rock interaction. The volcano is a significant source of toxic trace elements such as F, As, B and Li as well as a nutrient (P) for the local watershed. Monitoring of the hydrothermal fluids in the river that drains Copahue, especially the S/Cl, Mg/Cl and Mg/K values as well as the magnitude of the element fluxes would provide the best information for eruption forecasting for this volcano.     

Kaguyak dome field and its Holocene caldera,Alaska Peninsula

Kaguyak Caldera lies in a remote corner of Katmai National Park, 375 km SW of Anchorage, Alaska. The 2.5-by-3-km caldera collapsed ~ 5.8 ± 0.2 ka (¹⁴C age) during emplacement of a radial apron of poorly pumiceous crystal-rich dacitic pyroclastic flows (61–67% SiO₂). Proximal pumice-fall deposits are thin and sparsely preserved, but an oxidized coignimbrite ash is found as far as the Valley of Ten Thousand Smokes, 80 km southwest. Postcaldera events include filling the 150-m-deep caldera lake, emplacement of two intracaldera domes (61.5–64.5% SiO₂), and phreatic ejection of lakefloor sediments onto the caldera rim. CO₂ and H₂S bubble up through the lake, weakly but widely. Geochemical analyses (n = 148), including pre-and post-caldera lavas (53–74% SiO₂), define one of the lowest-K arc suites in Alaska. The precaldera edifice was not a stratocone but was, instead, nine contiguous but discrete clusters of lava domes, themselves stacks of rhyolite to basalt exogenous lobes and flows. Four extracaldera clusters are mid-to-late Pleistocene, but the other five are younger than 60 ka, were truncated by the collapse, and now make up the steep inner walls. The climactic ignimbrite was preceded by ~ 200 years by radial emplacement of a 100-m-thick sheet of block-rich glassy lava breccia (62–65.5% SiO₂). Filling the notches between the truncated dome clusters, the breccia now makes up three segments of the steep caldera wall, which beheads gullies incised into the breccia deposit prior to caldera formation. They were probably shed by a large lava dome extruding where the lake is today.     

Chemical evolution of thermal waters and changes in the hydrothermal system of Papandayan volcano (West Java,Indonesia) after the November 2002 eruption

Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772, only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano.     

New physical characterization of the Fontana Lapilli basaltic Plinian eruption,Nicaragua

The Fontana Lapilli deposit was erupted in the late Pleistocene from a vent, or multiple vents, located near Masaya volcano (Nicaragua) and is the product of one of the largest basaltic Plinian eruptions studied so far. This eruption evolved from an initial sequence of fluctuating fountain-like events and moderately explosive pulses to a sustained Plinian episode depositing fall beds of highly vesicular basaltic-andesite scoria (SiO₂ > 53 wt%). Samples show unimodal grain size distribution and a moderate sorting that are uniform in time. The juvenile component predominates (> 96 wt%) and consists of vesicular clasts with both sub-angular and fluidal, elongated shapes. We obtain a maximum plume height of 32 km and an associated mass eruption rate of 1.4 × 10⁸ kg s⁻¹ for the Plinian phase. Estimates of erupted volume are strongly sensitive to the technique used for the calculation and to the distribution of field data. Our best estimate for the erupted volume of the majority of the climactic Plinian phase is between 2.9 and 3.8 km³ and was obtained by applying a power-law fitting technique with different integration limits. The estimated eruption duration varies between 4 and 6 h. Marine-core data confirm that the tephra thinning is better fitted by a power-law than by an exponential trend.     

Dissolution/crystallization kinetics recorded in the 2002–2003 lavas of Stromboli (Italy)

On 28 December 2002, new vents opened on the flanks of Stromboli, just below the summit craters, interrupting the persistent activity of the volcano with a 7-month-long effusive eruption. We here report on the plagioclase size distribution (PlgSD) in lava samples collected following the chronology of the 2002–2003 eruption. Data reveal a linear PlgSD similar to that found in samples of normal Stromboli activity, indicating that the switch from Strombolian explosive to effusive activity is not associated with changes in texture. Nevertheless, the crystal size distribution slopes and intercepts exhibit slight sinusoidal temporal variations that are here ascribed to a magma supply mechanism able to induce “resonance” in the crystal size distribution, with an amplitude that depends on the supply rate.     

Sub-surface dynamics and eruptive styles of maars in the Colli Albani Volcanic District, Central Italy

Eruptive scenarios associated with the possible reactivation of maar-forming events in the Quaternary, ultrapotassic Colli Albani Volcanic District (CAVD) provides implications for volcanic hazard assessment in the densely populated area near Rome. Based on detailed stratigraphy, grain size, componentry, ash morphoscopy and petro-chemical analyses of maar eruption products, along with textural analysis of cored juvenile clasts, we attempt to reconstruct the eruptive dynamics of the Prata Porci and Albano maars, as related to pre- and syn-eruptive interactions between trachybasaltic to K-foiditic feeder magmas and carbonate–silicoclastic and subvolcanic country rocks. Magma volumes in the order of 0.5–3.1 × 10⁸ m³ were erupted during the monogenetic Prata Porci maar activity and the three eruptive cycles of the Albano multiple maar, originating loose to strongly lithified, wet and dry pyroclastic surge deposits, Strombolian scoria fall horizons and lithic-rich explosion breccias. These deposits contain a wide range of accessory and accidental lithic clasts, with significant vertical stratigraphic variations in the lithic types and abundances. The two maar study cases hold a record of repeated transitions between magmatic (i.e, Strombolian fallout) and hydromagmatic (wet and dry pyroclastic surges) activity styles. Evidence of phreatic explosions, a common precursor of explosive volcanic activity, is only found at the base of the Prata Porci eruptive succession. The quantitative evaluation of the proportions of the different eruptive styles in the stratigraphic record of the two maars, based on magma vs. lithic volume estimates, reveals a prevailing magmatic character in terms of erupted magma volumes despite the hydromagmatic footprint. Different degrees of explosive magma–water interaction were apparently controlled by the different hydrogeological and geological–structural settings. In the Prata Porci case, shifts in the depth of magma fragmentation are proposed to have accompanied eruption style changes. In the Albano case, a deeply dissected geothermal aquifer in peri-caldera setting and variable mass eruption rates were the main controlling factors of repeated shifts in the eruptive style. Finally, textural evidence from cored juvenile clasts and analytical modeling of melt–solid heat transfer indicate that the interacting substrate in the Prata Porci case was at low, uniform temperature (~ 100 °C) as compared to the highly variable temperatures (up to 700–800 °C) inferred for the geothermal system beneath Albano.     

Preliminary sensitivity study of eruption source parameters for operational volcanic ash cloud transport and dispersion models — A case study of the August 1992 eruption of the Crater Peak vent, Mount Spurr, Alaska

Ash clouds are one of the major hazards that result from volcanic eruptions. Once an eruption is reported, volcanic ash transport and dispersion (VATD) models are used to forecast the location of the ash cloud. These models require source parameters to describe the ash column for initialization. These parameters include: eruption cloud height and vertical distribution, particle size distribution, and start and end time of the eruption. Further, if downwind concentrations are needed, the eruption mass rate and/or volume of ash need to be known. Upon notification of an eruption, few constraints are typically available on many of these source parameters. Recently, scientists have defined classes of eruption types, each with a set of pre-defined eruption source parameters (ESP). We analyze the August 18, 1992 eruption of the Crater Peak vent at Mount Spurr, Alaska, which is the example case for the Medium Silicic eruption type. We have evaluated the sensitivity of two of the ESP – the grain size distribution (GSD) and the vertical distribution of ash – on the modeled ash cloud. HYSPLIT and Puff VATD models are used to simulate the ash clouds from the different sets of source parameters. We use satellite data, processed through the reverse absorption method, as reference for computing statistics that describe the modeled-to-observed comparison. With the grain size distribution, the three options chosen, (1) an estimated distribution based on past eruption studies, (2) a distribution with finer particles and (3) the National Oceanic and Atmospheric Administration HYSPLIT GSD, have little effect on the modeled ash cloud. For the initial vertical distribution, both linear (uniform concentration throughout the vertical column) and umbrella shapes were chosen. For HYSPLIT, the defined umbrella distribution (no ash below the umbrella), apparently underestimates the lower altitude portions of the ash cloud and as a result has a worse agreement with the satellite detected ash cloud compared to that with the linear vertical distribution for this particular eruption. The Puff model, with a Poisson function to represent the umbrella cloud, gave similar results as for a linear distribution, both having reasonable agreement with the satellite detected cloud. Further sensitivity studies of this eruption, as well as studies using the other source parameters, are needed.     

长白山天池火山全新世大喷发挥发性气体释放量的分析和估算

火山喷发是地球上一种壮观的自然景象 ,火山喷发的同时一般都喷出气体 ,火山爆炸式喷发时巨量的气体被喷入空中 ,对全球气候造成较大影响。长白山天池火山于全新世发生过两次较大的爆炸式喷发 ,根据本文的分析和估算 ,后一次即天池火山公元 1199～ 12 0 1年的那次大喷发 ,逃逸到空中的挥发气体含量分别为 :CO2 约 (0 .31～ 1.5 6 )× 10 8t,S(主要是 H2 S和 SO2 )约 1.96× 10 7t,F2 约 7.86× 10 6 t,Cl2 约 (0 .78～ 6 .2 4)× 10 7t,对全球气候曾产生过重要影响     

Water chemistry of Lake Quilotoa (Ecuador) and assessment of natural hazards

A geochemical survey carried out in November 1993 revealed that Lake Quilotoa was composed by a thin (14 m) oxic epilimnion overlying a 200 m-thick anoxic hypolimnion. Dissolved CO₂ concentrations reached 1000 mg/kg in the lower stratum. Loss of CO₂ from epilimnetic waters, followed by calcite precipitation and a consequent lowering in density, was the apparent cause of the stratification.The Cl, SO₄ and HCO₃ contents of Lake Quilotoa are intermediate between those of acid–SO₄–Cl Crater lakes and those of neutral-HCO₃ Crater lakes, indicating that Lake Quilotoa has a ‘memory’ of the inflow and absorption of HC1- and S-bearing volcanic (magmatic) gases. The Mg/Ca ratios of the lake waters are governed by dissolution of local volcanic rocks or magmas, but K/Na ratios were likely modified by precipitation of alunite, a typical mineral in acid–SO₄–Cl Crater lakes.The constant concentrations of several conservative chemical species from lake surface to lake bottom suggest that physical, chemical and biological processes did not have enough time, after the last overturn, to cause significant changes in the contents of these chemical species. This lapse of time might be relatively large, but it cannot be established on the basis of available data. Besides, the lake may not be close to steady state. Mixing of Lake Quilotoa waters could presently be triggered by either cooling epilimnetic waters by 4°C or providing heat to hypolimnetic waters or by seismic activity.Although Quilotoa lake contains a huge amount of dissolved CO₂ (3×10¹¹ g), at present the risk of a dangerous limnic eruption seems to be nil even though some gas exsolution might occur if deep lake waters were brought to the surface. Carbon dioxide could build up to higher levels in deep waters than at present without any volcanic re-awakening, due to either a large inflow of relatively cool CO₂-rich gases, or possibly a long interval between overturns. Periodical geochemical surveys of Lake Quilotoa are, therefore, recommended.