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41.
外差激光雷达测量水体布里渊散射可行性研究 总被引:1,自引:0,他引:1
该文分析外差激光雷达测量水体布里渊散射的可行性。借助测量水体布里渊散射的频移 ,可得到水体声速或温度。文中利用两条 12 7I2 吸收线锁定激光输出频率 ,产生稳定的频差约为7.5 GHz发射激光和激光本振。通过对 12 7I2 吸收线稳定度、激光频率稳定度、系统信噪比和反演精度的分析和计算机模拟 ,得出水体深度 2 5 m以内水体布里渊散射频移的测量误差可以控制在2 .5 MHz以内 ,达到水中声速 0 .6 m/ s或温度 0 .1℃的测量精度。 相似文献
42.
厦门湾有色溶解有机物的光吸收特性研究 总被引:3,自引:0,他引:3
研究了厦门湾九龙江河口区、西海域、同安湾及东侧水道海水中有色溶解有机物(CDOM)的光吸收特性,分析了CDOM的河口行为,并讨论了CDOM光吸收特性与其荧光性质之间的关系。结果表明,厦门湾表层海水CDOM光吸收系数a(355)的水平分布表现为河口区最高、东侧水道最低、西海域和同安湾介于两者之间,底层水a(355)的分布与表层基本相似,表明陆源河流输入是厦门湾CDOM的主要来源;a(355)的垂直分布为表层高于底层,主要受水文和生物因素控制。厦门湾表层水CDOM光谱斜率S的平均值介于0.014—0.018nm-1,但河口低盐度区S值较小,反映陆源腐殖质的影响。a(355)在河口混合中呈保守行为,表明CDOM具有良好的保守性质。CDOM的吸收系数a(355)与其荧光强度之间表现为较好的相关关系,指示可以用灵敏度更高的荧光方法来研究CDOM的分布和行为。 相似文献
43.
J.G.P.W. Clevers L. KooistraM.E. Schaepman 《International Journal of Applied Earth Observation and Geoinformation》2008
Canopy water content (CWC) is important for mapping and monitoring the condition of the terrestrial ecosystem. Spectral information related to the water absorption features at 970 nm and 1200 nm offers possibilities for deriving information on CWC. In this study, we compare the use of derivative spectra, spectral indices and continuum removal techniques for these regions. Hyperspectral reflectance data representing a range of canopies were simulated using the combined PROSPECT + SAILH model. Best results in estimating CWC were obtained by using spectral derivatives at the slopes of the 970 nm and 1200 nm water absorption features. Real data from two different test sites were analysed. Spectral information at both test sites was obtained with an ASD FieldSpec spectrometer, whereas at the second site HyMap airborne imaging spectrometer data were also acquired. Best results were obtained for the derivative spectra. In order to avoid the potential influence of atmospheric water vapour absorption bands the derivative of the reflectance on the right slope of the canopy water absorption feature at 970 nm can best be used for estimating CWC. 相似文献
44.
45.
Lutz Nasdala Wolfgang Hofmeister Nicholas Norberg James M. Martinson Fernando Corfu Wolfgang Dörr Sandra L. Kamo Allen K. Kennedy Andreas Kronz Peter W. Reiners Dirk Frei Jan Kosler Yusheng Wan Jens Götze Tobias Häger Alfred Kröner John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ~ 840 μg g?1 U (Th/U ~ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn. 相似文献
46.
Taeko Shinonaga Helmuth Aigner Dilani Klose Peter Spinder Heinz Fröschl David Donohue 《Geostandards and Geoanalytical Research》2008,32(1):93-101
The recommended concentrations of 239Pu, 240Pu and 239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of 239Pu and 240Pu (239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of 242Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg?1, (28 ± 3) Bq kg?1 and (66 ± 4) Bq kg?1 are proposed as recommended values for 239Pu, 240Pu and 239+240Pu, respectively, and (9.5 ± 0.4) Bq kg?1 for 238Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg?1, (3.3 ± 0.4) ng kg?1 and (0.015 ± 0.003) ng kg?1 for 239Pu, 240Pu and 238Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study. 相似文献
47.
我国藻菌生物成因的金矿研究 总被引:1,自引:0,他引:1
生物成矿作用分为生物直接成矿作用和生物间接成矿作用,生物直接成矿作用的标志结构为生物有机胶体结构。生物间接成矿作用的标志结构为“矿交代生物”结构,我国陕西二台子-半仓沟金矿,四川东北寨金矿、川甘拉尔玛金矿和云南金厂金矿等均为典型为实例,矿石中普遍含有多种金属矿物生物结构,还含多种生物有机组分。成矿物质具有多源性特征,硫同位素具混合型特征,矿床成型机制可与“人工碳吸附系统”聚金机制相类比,含金层位可 相似文献
48.
F. Carrier B. Bourdon . Pili C. Truffert R. Wyns 《Journal of Geochemical Exploration》2006,88(1-3):266
Airborne gamma-ray spectrometry data (uranium, potassium and thorium contents) reveal geochemical heterogeneities within the monolithological Hyrôme watershed (ca. 150 km2) in the Armorican massif (western France). Our observations and computations provide important constraints on the spatial distribution and the associated magnitudes of chemical erosion processes at the scale of a small watershed. Two distinct, partially preserved, weathering profiles exhibit a strong correlation between regolith evolution and airborne-derived K/Th ratios, suggesting that the variability is linked to supergene processes. Using both airborne data and laboratory measurements on rock samples, the total net export of potassium has been estimated at 422 ± 50 kg/m2 and the chemical weathering rate of potassium at 17 ± 2 kg/km2/a. 相似文献
49.
Micro-spectroscopic investigations of highly heterogeneous waste repository materials 总被引:1,自引:0,他引:1
A.M. Scheidegger D. Grolimund C.R. Cheeseman R.D. Rogers 《Journal of Geochemical Exploration》2006,88(1-3):59
Assuring safe disposal and long-term storage of radioactive and toxic wastes corresponds to a primary environmental task of present societies. To improve any technical limitation, a mechanistic understanding of the processes governing the binding of heavy metals and radionuclides is required. In this study, the significance of synchrotron-based X-ray microprobes for elucidating the spatial distribution and the speciation of radionuclides in highly heterogeneous waste repository materials will be outlined. A case study on the uptake process of Co in cementitious engineered barrier materials exposed to microbial degradation will be presented. 相似文献
50.
Janet M. Hergt L. Paul Bédard Etienne Deloule Klaus Peter Jochum Kathryn L. Linge Paul J. Sylvester Matthias Willbold Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields. 相似文献