原子吸收分光光度法快速测定铬铁矿中钙、镁、锰

通过在标液中加入相应的Sr来消除离子干扰,采用原子吸收分光光度法快速测定CaO、MgO、MnO的含量,方法经国家标准物质验证,其RSD<2%(n=6)。其结果与标准值相符。方法达到了准确、简便、快速、实用性强。     

GPS在轨卫星原子钟的稳定性分析

导航卫星星载原子钟的相位或频率数据,作为导航系统应用研究的基础,将直接影响导航系统时间尺度建立以及定位的精度和准确性。本文针对由IGS官网提供的四种GPS卫星钟的钟差数据,采用修正阿伦方差进行了稳定性分析,得到了一些有益的结论。     

近红外波段(900—2500 nm)水吸收系数测量

根据水在红外波段强吸收且吸收能力变化大的特点,在所提出可见光波段水吸收系数测量系统基础上增设了薄层水测量装置,使得测量水层厚度可在0.04—350 mm之间变化。在此基础上对厚度为0.04—150 mm的多个厚度水层进行了吸收系数测量,并对消除杂质影响后的测量数据进行了有效整合,得到900—2500 nm波段纯水吸收系数。由于确保了各波段数据均在仪器最佳探测区间取得,所得结果精度较高,且与被普遍接受的前期研究结果相一致,可作为相关定量遥感的基础数据。     

近红外大气吸收波段太阳辐射计定标

用通用大气辐射传输软件CART模拟了POM02太阳辐射计的1020nm、1627nm和2200nm等3个近红外通道的大气透过率特性。结果表明,前两通道处于大气非吸收波段,其透过率很好的遵从Beer-Lambert定律,而2200nm通道则有较强的吸收,吸收光学厚度随大气质量的变化服从指数分布,与Beer-Lambert定律有一定的偏差,其定标需采用改进的Langley法。通过选取好天的5个定标实例证明,采用改进的Langley法定标2200nm通道,可提高其透过率测量精度约3.8%。     

Experimental study of the effect of temperature on ion cluster formation using ion mobility spectrometry

Ion mobility spectrometry offers a robust and effective technique to study ion clusters in ambient conditions. Here, we have experimentally studied the influence of temperature on the positive ion cluster formation of 2-propanol vapor in air, along with parallel measurements for n-butyl acetate vapor in air. For both of these low proton affinity compounds in the ppm concentration range, temperatures below 0 °C tend to favor formation of dimers and trimers. The measurements indicate that approximate estimations for the fractions of these n-mers (n > 1) in the ion spectra, can be obtained by classical theory for ion induced nucleation. Presence of natural background vapors however slightly blurs the data, especially for the fraction of monomers, so that accurate prediction of the fractions of n-mers in the spectra would require more accurate information on the gas composition. The findings concerning thermal behavior of ions help to understand better ion phenomena also in field conditions.     

Source attribution of urban smog episodes caused by coal combustion

Stable weather conditions together with extensive use of coal combustion often lead to severe smog episodes in certain urban environments, especially in Eastern Europe. In order to identify the specific sources that cause the smog episodes in such environments, and to better understand the mixing state and atmospheric processing of aerosols, both single particle and bulk chemical characterization analysis of aerosols were performed in Krakow, Poland, during winter 2005.Real-time measurements of the bulk PM10 aerosol during a severe smog episode (PM10 mass > 400 µg m^− 3) showed a stable concentration of black carbon in the aerosol, and an increase in the sulphate and chlorine mass contributions towards the end of the episode. Chemical characterization of single particles further helped to identify residential coal burning as the main source that caused this severe smog episode, consisting of single particles with major signals for carbon with simultaneous absence of sulphate, chlorine and calcium. Particles from industrial coal combustion gained importance towards the end of that episode, after residential coal combustion was switched off, indicated by an increase of the percentage of sulphate and chlorine containing particles. Traffic was not a significant source during the severe smog episode. During a lighter smog episode, residential and industrial coal combustion was still predominant, with an increased contribution of traffic and processed/aged aerosols. On a clean day, particle classes containing nitrate were the most abundant. In addition, the aerosol was more internally mixed showing that there were more sources contributing to the total aerosol population.     

Gravitational lensing of anisotropic sources

In strong gravitational lensing, the multiple images we see correspond to light rays that leave the source in slightly different directions. If the source emission is anisotropic, the images may differ from conventional lensing predictions (which assume isotropy). To identify scales on which source anisotropy may be important, we study the angle δ between the light rays emerging from the source, for different lensing configurations. If the lens has a power-law profile   M ∝ R ^γ  , the angle δ initially increases with lens redshift and then either diverges (for a steep profile  γ < 1  ), remains constant (for an isothermal profile  γ= 1  ), or vanishes (for a shallow profile  γ > 1  ) as   z _l→ z _s  . The scaling with lens mass is roughly  δ∝ M ^1/(2−γ)  . The results for an Navarro–Frenk–White (NFW) profile are qualitatively similar to those for a shallow power law, with δ peaking at about half the redshift of the source (not half the distance). In practice, beaming could modify the statistics of beamed sources lensed by massive clusters: for an opening angle  θ_jet  , there is a probability as high as   P ∼ 0.02–0.07(θ_jet/0.5°)⁻¹  that one of the lensed images may be missed (for  2 ≲ z _s≲ 6  ). Differential absorption within active galactic nuclei (AGNs) could modify the flux ratios of AGNs lensed by clusters; a sample of AGNs lensed by clusters could provide further constraints on the sizes of absorbing regions. Source anisotropy is not likely to be a significant effect in galaxy-scale strong lensing.     

Radiative lifetimes and transition probabilities in Hf I and Hf III

Radiative lifetimes of nine odd levels in Hf III (5d6p z³P_0,1, z¹D₂, z³D_1,2,3, z³F_2,3,4) and of two odd levels in Hf I (5d6s²6p z³D_2,3) have been determined using Time-Resolved Laser-Induced Fluorescence. The investigated levels in Hf I were excited in a single-step process from the ground term (5d²6s² a³F), whereas in Hf III we started from either the ground term 5d² a³F or the low-lying 5d6s a³D term. For all of the investigated levels, the lifetimes have been measured for the first time. A multiconfiguration relativistic Hartree–Fock method, including core-polarization effects, has been used to compute radiative lifetimes of 15 Hf III levels, including those measured in this work. Transition probabilities for 55 transitions in Hf III are also given.