Paleoproterozoic metamorphism in the northern Fennoscandian Shield: age constraints revealed by monazite

ABSTRACT

We have identified two contrasting styles of Paleoproterozoic metamorphism in the northern part of the Fennoscandian Shield. The Karelia and Lapland-Kola Provinces, comprising Archean and overlying Paleoproterozoic supracrustal rocks, show a typical medium pressure Barrovian-style metamorphism with commonly found kyanite-bearing mineral assemblages and ITD (isothermal decompression) PT paths. In the juxtaposed Svecofennia Province metamorphism represents low pressure-high temperature Buchan style with garnet-cordierite migmatites and intercalated andalusite-cordierite and andalusite-staurolite schists and sillimanite-muscovite gneisses. The retrograde PT paths show only a moderate uplift during cooling.

U-Pb age determinations on monazite were made using the LA-ICP-MS from more than 80 samples from metasedimentary rocks. The sampling covered most parts of the Paleoproterozoic bedrock in Finland. The analyses reveal three peaks at c. 1.91 Ga, 1.86–1.88 Ga and at 1.79–1.81 Ga. The oldest, c. 1.91 Ga monazites are mostly found in the Lapland-Kola Province which is located in the northernmost Finland. In the Karelia Province where the Paleoproterozoic is underlain by Archean bedrock monazite yielded ages of 1.76?1.81 Ga with only a few older exceptions in samples showing a spread of ²⁰⁷Pb/²⁰⁶Pb ages from c. 1.92–1.81 Ga. The Karelia Province underwent tectonic thickening, where monazite ages of around 1.80 Ga mostly represent exhumation near the temperature maximum.

In the Svecofennia Province monazite ages vary from c. 1.89 to 1.78 Ga. In the Western Finland Subprovince the monazite ages in high-grade migmatites are mostly 1.86?1.88 Ga but within the older migmatite areas there are lower grade zones where monazite yields ages of c. 1.80 Ga. Some samples also show a spread of ²⁰⁷Pb/²⁰⁶Pb ages from 1.89?1.86 Ga to c. 1.78 Ga. In the Southern Finland Subprovince most ages are either 1.80?1.78 Ga, especially in the andalusite grade schists, or the sample shows a spread of ²⁰⁷Pb/²⁰⁶Pb ages from c. 1.88 to 1.78 Ga. Only in the eastern part of the Southern Finland Subprovince there are rocks which yield merely 1.86?1.89 Ga ages. Low pressure-high temperature metamorphism and lack of high or medium P/T rocks in the Svecofennia Province refers rather to accretionary than collisional processes.     

The effect of Holocene treeline fluctuations on the sediment chemistry of Lake Kilpisjärvi, Finland

The sediments of Lake Kilpisjärvi were described and analysed for element chemistry and pollen to study the effects of treeline fluctuations in the catchment. Lake Kilpisjärvi is one of the largest lakes in Finnish Lapland, with its catchment partly above the treeline and partly covered with mountain birch woodland. Although the presence of subfossil pine shows that the catchment was previously covered with mountain birch woodland during the Holocene, the present pine treeline has receded 70 km from the lake. Pollen analysis results show that pine immigrated to the area during the Atlantic chrone and that 7000 BP pine forests occupied much of the catchment. Pine started to decline around 3500 BP and vegetation in the catchment became more open. Alkaline and alkaline earth metals and some transition metals document the change from glaciolacustrine clay to more organic sediment. However, these geochemical trends give no indication of changes in erosion rate resulting from changes in catchment vegetation. These changes were detected by plotting suitable element ratios. In addition to the conventional Si/Al and Na/K ratios, the Ca _labile /Si ratio and especially the ratio of labile Ca to K were found to be useful. Of all the elements analysed, potassium showed the strongest reaction to changes in the balance between weathering and erosion. During the phase of denser forests, chemical weathering was dominant, whereas during phases of open catchment, physical erosion prevailed. The effects of changing climate and catchment vegetation were distinguished from other signals. For instance, iron and manganese were enriched at the top of the core due to diffusion and, at the same time, old precipitate layers persisted after burial to deeper levels in the sediment. These iron and manganese rich layers had an effect on the distributions of cobalt, zinc, and vanadium, showing increased concentrations of these elements. Other effects that made the interpretation of chemical records difficult were the effect of ongoing mineralization of organic matter in the top layers of sediment and the effect of biogenic silicon. Owing to the stable conditions of the lake, the desired chemical signals were detected, despite the masking trends.     

芬兰北部克维特斯塔镍-铜-铂族元素矿床地质特征及矿床成因

位于芬兰北部中拉普兰绿岩带的克维特斯塔(Kevitsa)镍-铜-铂族元素矿床是世界上主要的岩浆镍-铜硫化物矿床之一。该矿床储量大,含丰富的镍-铜硫化物和铂族元素。对矿床产出环境、地质特征、矿床成因等进行了总结,结果表明：矿体主要赋存于克维特斯塔基性—超基性层状侵入体的超基性单元中。主要矿石类型为普通型和镍-铂族元素型2种,其中镍-铂族元素型矿石内橄榄石具极高的Ni含量。主要矿石矿物为磁黄铁矿、镍黄铁矿、黄铜矿、黄铁矿、针硫镍矿、红砷镍矿、砷镍矿、辉砷镍矿等,绝大部分铂族矿物包含在硅酸盐中和附着在硫化物颗粒边界。Re-Os、Sm-Nd、Sr及S同位素特征显示成矿岩浆为幔源,但受到地壳物质的混染作用。Pb同位素年代学结果表明克维特斯塔侵入体形成于古元古代。     

Consequences of coastal upwelling events on physical and chemical patterns in the central Gulf of Finland (Baltic Sea)

The consequences of a coastal upwelling event on physical and chemical patterns were studied in the central Gulf of Finland. Weekly mapping of hydrographical and -chemical fields were carried out across the Gulf between Tallinn and Helsinki in July–August 2006. In each survey, vertical profiles of temperature and salinity were recorded at 27 stations and water samples for chemical analyses (PO₄³⁻, NO₂⁻+NO₃⁻) were collected at 14 stations along the transect. An ordinary distribution of hydrophysical and -chemical variables with the seasonal thermocline at the depths of 10–20 m was observed in the beginning of the measurements in July. Nutrient concentrations in the upper mixed layer were below the detection limit and nutriclines were located just below or in the lower part of the thermocline. In the first half of August, a very intense upwelling event occurred near the southern coast of the Gulf when waters with low temperature and high salinity from the intermediate layer surfaced. High nutrient concentrations were measured in the upwelled water – 0.4 μmol l⁻¹ of phosphates and 0.6 μmol l⁻¹ of nitrates+nitrites. We estimated the amount of nutrients transported into the surface layer as 238–290 tons of phosphorus (P)-PO₄³⁻ and 175–255 tons of N-NO_x for a 12 m thick, 20 km wide and 100 km long coastal stretch. Taking into account a characteristic along-shore extension of the upwelling of 200 km, the phosphate-phosphorus amount is approximately equal to the average total monthly riverine load of phosphorus to the Gulf of Finland. It is shown that TS-characteristics of water masses and vertical distribution of nutrients along the study transect experienced drastic changes caused by the upwelling event in the entire studied water column. TS-analysis of profiles obtained before and during the upwelling event suggests that while welled up, the cold intermediate layer water was mixed with the water from the upper mixed layer with a share of 85% and 15%. We suggest that the coastal upwelling events contribute remarkably to the vertical mixing of waters in the Gulf of Finland. Intrusions of nutrient-rich waters along the inclined isopycnal surfaces in the vicinity of upwelling front were revealed. The upwelling event widened the separation of phosphocline and nitracline which in turn prevented surfacing of nitrate+nitrite-nitrogen during the next upwelling event observed a week after the upwelling relaxation. A suggestion is made that such widening of nutricline separation caused by similar upwelling events in early summer could create favourable conditions for late summer cyanobacterial blooms.     

芬兰马斯塔瓦纳磁铁矿-钛铁矿矿床地质特征与成因

马斯塔瓦纳磁铁矿-钛铁矿床位于芬兰北部,属于芬诺斯堪迪亚地盾,辉长岩是主要的含矿岩体。矿石类型主要为钛磁铁矿,含矿岩石为含钛磁铁矿、钒钛磁铁矿辉长岩。浸染状矿石金属矿物以钛磁铁矿为主,次为钛铁矿。地球化学特征研究表明,马斯塔瓦纳矿床的Zr、Hf、U、Th在含矿辉长岩中含量非常稳定,均小于10×10-6,反映了岩浆成因的特征。由于马斯塔瓦纳矿床形成时构造环境不稳定,原始岩浆来不及长期彻底地分异,导致岩石的地球化学参数等均具有过渡特征。芬兰马斯塔瓦纳矿床的成岩成矿过程主要分为2个期次:成岩期(形成辉长岩体)和主成矿期(岩浆期形成铁矿)。初步研究表明,芬兰马斯塔瓦纳铁-钛-钒矿床与国内的"大庙式"和"攀西式"铁矿有所不同,2个国内矿床处于相对稳定的板内构造环境,而芬兰马斯塔瓦纳矿床产于特殊的造山带而非稳定的克拉通构造环境。     

Groundwater use and policy in community water supply in Finland

Selection between ground and surface water in community water supply has been one of the key strategic questions in Finland since the early 1900s. After some cities failed to find reliable groundwater sources, many turned to surface waters. Since the 1950s the use of groundwater and artificial recharged groundwater have continuously increased. Presently their use is promoted by the government and European water policy through technical advice and financial support. It is obvious that the share of groundwater and artificial recharged groundwater will increase in the future. This requires active public response and transparency in decision-making.

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Resumen Desde el principio de 1900 una de las preguntas estratégicas clave en Finlandia es la selección entre agua subterranea y de superficie para el suministro de agua de la comunidad. Muchas ciudades renunciaron al agua de superficie luego de haber fracesado en encontrar fuentes de agua subterránea confiables. Desde 1950 el uso de agua subterránea y de agua subterránea recargada artificialmente ha aumentado continuamente. Actualmente los políticas de agua del gobierno y de Europa promueven su uso por medio de asesoría técnica y apoyo financiero. Es obvio que la participación del agua subterránea y del agua subterránea recargada artificialmente va a aumentar en el futuro. Esto requiere una respuesta activa pública y transparencia en el proceso de toma de decisiones.

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Resumé Le choix parmi lutilisation de leau de surface ou de leau souterraine comme source dapprovisionnement en eau potable est, depuis le début des années 1900, une question stratégique en Finlande. Suite à léchec de certaines villes à sapprovisionner en eau souterraine, plusieurs se sont tournées vers leau de surface. Depuis les années 1950, lutilisation de leau souterraine et la recharge artificielle des aquifères est en constante croissance. Actuellement, leur utilisation est encouragée par le Gouvernement ainsi que par la politique européenne de leau qui fournit une expertise technique et un soutient financier. Il est évident que les proportions occupées par lapprovisionnement en eau souterraine et la recharge artificielle vont augmenter avec le temps. Ceci requiert une participation active du public ainsi que de la transparence lors du processus décisionnel.

     

Multiproxy evidence for the ‘Little Ice Age’ from Lake Hampträsk,Southern Finland

We studied a short sediment core from Lake Hampträsk, southern Finland, for evidence of the ‘Little Ice Age’ (LIA) in aquatic invertebrate communities. Subfossil chironomids, cladocerans, and chydorid ephippia were investigated, together with detrended correspondence analyses (DCAs) and loss-on-ignition (LOI). Our results show two cooler periods. The first cooling, indicated by increased numbers of chydorid ephippia and cold-water chironomid taxa, occurred ca. 1400 AD and the second, more drastic cooling, during the seventeenth century, when cold-water chironomids began to increase. Our data suggest that the cooling culminated around 1700 AD, when cold-stenothermic chironomids and chydorid ephippia attained maximal values and the LOI and diversity of invertebrates decreased to minimal values. After the LIA, the aquatic fauna appeared to respond to rising trophic state caused by enhanced land use in the catchment.     

Intraregional variability in chironomid-inferred temperature estimates and the influence of river inundations on lacustrine chironomid assemblages

Floodplain lakes are rarely analysed for fossil chironomids and usually not incorporated in modern chironomid-climate calibration datasets because of the potential complex hydrological processes that could result from flooding of the lakes. In order to investigate this potential influence of river inundations on fossil chironomid assemblages, 13 regularly inundated lakes and 20 lakes isolated from riverine influence were sampled and their surface sediments analysed for subfossil chironomid assemblages. The physical and chemical settings of all lakes were similar, although the variation in the environmental variables was higher in the lakes isolated from riverine influence. Chironomid concentration and taxon richness show significant differences between the two classes of lakes, and the variation in these variables is best explained by loss-on-ignition of the sediments (LOI). Relative chironomid abundances show some differences between the two groups of lakes, with several chironomid taxa occurring preferentially in one of the two lake-types. The variability in chironomid assemblages is also best explained by LOI. Application of a chironomid-temperature inference model shows that both types of lakes reconstruct July air temperatures that are equal to, or slightly underestimating, the measured temperature of the region. We conclude that, although there are some differences between the chironomid assemblages of floodplain lakes and of isolated lakes, these differences do not have a major effect on chironomid-based temperature reconstruction.     

Hydraulic parameter estimations of a 2D model validated with sedimentological findings in the point bar environment

There have been a number of flume tests of flow round bends with idealized geometry and recently hydraulic simulations of such experiment. However, studies of hydraulic models in natural river bend are rather limited because of greater complexity of the flow characteristics and lack of detailed data. In this article, we study how 2D hydraulic model and raster‐based hydraulic parameter calculations predict flow characteristics on the natural point bar environment. We will compare calculations of various hydraulic parameters (velocity, bed shear stress and stream power) by the 2D model and the associated sedimentology of the point bars. As a result of comparison, the usability of the 2D model for flow‐form‐product relationship predictions will be evaluated in natural river bend environment. The study shows that the 2D model can be generally utilized to predict the flood‐generated flow‐form‐product relationship in coarse‐grained and structurally complex point bar environments with sand‐dominated bedload. For example, point bar sections submerged in water depths greater than 50 cm showed a relatively good match laterally between the model and sedimentological estimations. Furthermore, this approach allows us to estimate flood processes on a local scale in similar point bar environments with width–length ratio. The flow direction estimates of the 2D model coincided relatively well with the sedimentological estimations on the bar head. However, flow directions on the downstream section could not be modelled because the 2D model cannot handle the helicoidal flow of the river bend. Copyright © 2010 John Wiley & Sons, Ltd.     

Geochemical and thermodynamic modeling of the petrogenesis of A1-type granites and associated intermediate rocks: A case study from the central Fennoscandian Shield

The origin of ferroan A-type granites in anorogenic tectonic settings remains a long-standing petrological puzzle. The proposed models range from extreme fractional crystallization of mantle-derived magmas to partial melting of crustal rocks, or involve combination of both. In this study, we apply whole-rock chemical and Sm-Nd isotopic compositions and thermodynamically constrained modeling (Magma Chamber Simulator, MCS) to decipher the genesis of a suite of A1-type peralkaline to peraluminous granites and associated intermediate rocks (monzodiorite-monzonite, syenite) from the southwestern margin of the Archean Karelia craton, central Finland, Fennoscandian Shield. These plutonic rocks were emplaced at ca. 2.05 Ga during an early stage of the break-up of the Karelia craton along its western margin and show trace element affinities to ocean island basalt-type magmas. The intermediate rocks show positive ε_Nd(2050 Ma) values (+1.3 to +2.6), which are only slightly lower than the estimated contemporaneous depleted mantle value (+3.4), but much higher than average ε_Nd(2050 Ma) of Archean TTGs (–10) in the surrounding bedrock, indicating that these rocks were essentially derived from a mantle source. The ε_Nd(2050 Ma) values of the peralkaline and peraluminous granite samples overlap (–0.9 to +0.6 and –3.2 to +0.9, respectively) and are somewhat lower than those in the intermediate rocks, suggesting that the mafic magmas parental to granite must have assimilated some amount of older Archean continental crust during their fractionation, which is consistent with the continental crust-like trace element signatures of the granite members. The MCS modeling indicates that fractional crystallization of mantle-derived magmas can explain the major element characteristics of the intermediate rocks. The generation of the granites requires further fractional crystallization of these magmas coupled with assimilation of Archean crust. These processes took place in the middle to upper crust (∼2–4 kbar, ∼7–15 km) and involved crystallization of large amounts of clinopyroxene, plagioclase and olivine. Our results highlight the importance of coupled FC-AFC processes in the petrogenesis of A-type magmas and support the general perception that magmas of A-type ferroan granites become more peraluminous by assimilation of crust. They further suggest that variable fractionation paths of the magmas upon the onset of assimilation may explain the broad variety of A-type felsic and intermediate igneous rocks that is often observed emplaced closely in time and space within the same igneous complex.