On the practice of estimating fractal dimension

Coastlines epitomize deterministic fractals and fractal (Hausdorff-Besicovitch) dimensions; a divider [compass] method can be used to calculate fractal dimensions for these features. Noise models are used to develop another notion of fractals, a stochastic one. Spectral and variogram methods are used to estimate fractal dimensions for stochastic fractals. When estimating fractal dimension, the objective of the analysis must be consistent with the method chosen for fractal dimension calculation. Spectal and variogram methods yield fractal dimensions which indicate the similarity of the feature under study to noise (e.g., Brownian noise). A divider measurement method yields a fractal dimension which is a measure of complexity of shape.     

岩体三维节点偶对分析及其应用

本文讨论了节点偶对分析的三维扩展。节点偶对分析是针对摩擦滑动节理单元的约束边界进行的序列矢量判定。在三维节理单元的分析中,几何约束和相应的力学判据极为复杂,采用节点偶对等效结合力方法才能迎刃而解。文中对三维转向节理模型的分析得到合理的结果,它表明本文所提出的方法可成功地应用于节理岩体的有限元分析。     

贵州和四川盆地云量的气候研究

贵州和四川盆地是我国云量最多的地区,素有“天无三日晴”和“蜀犬吠日”之说,盆地西缘的雅安古时还有“雅州天漏”的谚语。从全球日照百分率分布推知,川黔地区也是世界上天气最阴沉的地区之一。川黔之阴一向为国内外气象界所注意,本文根据1951—1980     

Astrophysical molecules of AlH and CaH: RKR potential and dissociation energies

The true potential energy curves for the electronic ground states of astrophysically important AlH and CaH molecules are constructed by the Rydberg-Klein-Rees method. Empirical potential functions, of three-parameters by Lippincott, of five-parameters by Hulburt and Hirsch-felder and, of electronegativity by Szöke and Baitz, are examined for the adequacy to represent the true curve. From the best-fitting function, the dissociation energiesD ₀ ⁰ of AlH and CaH molecules are estimated to be 2.99 ± 0.08 and 2.72 ± 0.06 eV respectively. The force constants indicate that these values are of correct magnitude.     

A preliminary stable isotope study on Mogok Ruby, Myanmar

The primary occurrence of ruby in the Mogok area, northern Myanmar is exclusively found in marble along with spinel–forsterite-bearing marble and phlogopite–graphite marble. These marble units are enclosed within banded biotite–garnet–sillimanite–oligoclase gneisses. Samples of these marbles collected for C–O stable isotope analysis show two trends of δ¹³C–δ¹⁸O variation resulting most likely from fluid–rock interactions. Ruby-bearing marble and phlogopite–graphite marble follow a trend with coupled C–O depletion, whereas spinel–forsterite-bearing marble follows a δ¹⁸O depletion trend with relatively constant δ¹³C values. Ruby formation might have resulted from CO₂-rich fluid–rock interaction, while spinel–forsterite-bearing marble was genetically related to CO₂-poor fluid–rock interaction. Both fluids may have arisen from external sources. Based on graphite Raman spectral thermometry, the estimated temperature for phlogopite–graphite marble, and probably ruby-bearing marble, was lower than 607 °C, and for spinel–forsterite-bearing marble, lower than 710 °C. Contrasting C/O diffusion between graphite/ruby/spinel/forsterite and calcite, local variations of isotopic compositions of newly formed minerals as a result of non-pervasive fluid infiltration, and open-system isotopic disturbance during cooling may have affected C-/O-isotopic fractionations between minerals. The estimated high formation temperatures for ruby and spinel/forsterite imply that the parental fluids may have been related to nearby igneous intrusions and/or metamorphic processes. Whether these two types of fluid were genetically related is unclear based on the present data.     

The geochemistry of gem opals as evidence of their origin

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.     

“Cretaceous black flysch” in the Pieniny Klippen Belt, West Carpathians: a case of geological misinterpretation

This is a critical assessment of the paper by Oszczypko et al. (2004: Cretaceous Research 25, 89–113), in which they tried to prove a mid-Cretaceous age for the Szlachtowa (“black flysch”) and Opaleniec Formations, in the Pieniny Klippen Belt, West Carpathians, both of which had previously been shown to be of Jurassic age. We argue that the mid-Cretaceous age assignment is a misinterpretation, primarily resulting from their field samples having been collected from some Cretaceous lithostratigraphic units, tectonically associated with the Jurassic formations, and/or from tectonic contact-breccias involving Jurassic and Cretaceous strata. In addition, we suggest that they have overlooked a number of significant palaeontological papers, published since 1962, which record the presence of in situ ammonites, aptychi, belemnites, thin-shelled bivalves (Bositra), gryphaeids, foraminifera, and ostracod assemblages, all indicating a Jurassic (mainly Aalenian), and not a Cretaceous, age for the Szlachtowa Formation, and also the in situ Jurassic (Bajocian) ammonites and thin-shelled bivalves (Bositra), Bositra-microfacies, and age-diagnostic foraminiferal assemblages of the Opaleniec Formation.Our presentation here of recently published dinocyst data from well-preserved assemblages further supports the Jurassic ages for the Szlachtowa (“black flysch”) and Opaleniec Formations.     

气相色谱法测定地下水中六六六结果的不确定度评定

依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。     

火试金法测定铜精矿中金含量结果的不确定度评定

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。     

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。