高压密闭消解-电感耦合等离子体质谱法测定海洋沉积物中稀土元素

样品用HNO3-HF高压密闭消解,电感耦合等离子体质谱测定海洋沉积物中15种稀土元素。研究了消解方法、酸体系和质谱干扰对稀土元素测定的影响。结果表明,相比于电热板消解和微波消解,高压密闭消解具有酸用量少、消解完全、消解过程损失少等优点;HNO3-HF体系能有效地分解海洋沉积物样品;利用干扰离子校正方程,能有效地校正Ba和轻稀土元素所形成的多原子离子干扰。15种稀土元素的方法检出限为3～15 ng/g。使用水系沉积物标准物质GBW 07309和GBW 07311、海底沉积物标准物质GBW 07313进行验证,测定值与标准值基本吻合,相对标准偏差和相对误差均低于5%。方法用于长江口沉积物样品的测定,精密度(RSD,n=6)小于5%,加标回收率为95.8%～104%。该方法检出限低,精密度和准确度高,适用于大批海洋沉积物样品的分析。     

Modeling the influence of settling velocity on cohesive sediment transport in Tanshui River estuary

Settling velocities of suspended cohesive sediment in estuaries vary over a range of several orders in magnitude. Variations in the suspended sediment concentration are often considered as the principal cause. Turbulence and the suspended sediment concentration, as well as other factors such as salinity, dissolved organic substances, flocculation ability, and the rate of floc growth affect setting velocities. A laterally–averaged finite difference model for hydrodynamics and cohesive sediment transport is developed and applied in the Tanshui River estuary, Taiwan. The model has been calibrated and verified with water surface elevation, longitudinal velocity, salinity, and cohesive sediment measured. The overall performance of the model is in qualitative agreement with the available data. The model is used to investigate the influence of settling velocity on cohesive sediment transport dynamics. The simulation indicates that the turbidity maximum zone is near Kuan–Du. When settling velocities increase the surface cohesive sediment concentration at Kuan–Du station trends to decrease and bottom cohesive sediment concentration increases. Both surface and bottom cohesive sediment concentrations decrease at Taipei Bridge and Pa–Ling Bridge. This implies that suspended sediment advected seaward and deposited. There is consequently a net seaward flux of suspended sediment near surface, and a net landward flux near the bed.     

Undular tidal bore dynamics in the Daly Estuary, Northern Australia

Measurements in the macro-tidal Daly Estuary show that the presence of an undular tidal bore contributed negligibly to the dissipation of tidal energy. No recirculation bubble was observed between a trough and the following wave crest in the lee waves following the undular bore. This differs to stationary undular bores in laboratory experiments at larger Froude numbers where a recirculation bubble exists. Secondary motions and the turbulence generated by the undular bore had no measurable influence on the sediment transport. This situation contrasts with the intense sediment resuspension observed in breaking tidal bores. The tidally averaged sediment budget in the Daly Estuary was controlled by the asymmetry of tidal currents. The undular bore may widen the river by breaking along the banks that it undercuts, leading to bank slippage. A patch of river-wide macro-turbulence of 3-min duration occurred about 20 min after the passage of the bore during accelerating tidal currents.     

南海东北部表层沉积中有孔虫的分布及其环境意义

为了探讨南海东北部表层沉积中有孔虫分布的规律，选取184个表层样进行分析，结果发现有孔虫的垂向分布与碳酸盐的溶解作用密切相关。在2300－2500m水深以下，浮游有孔虫丰度迅速减小，而底栖有孔虫占有孔虫全群的比值BF／（BF＋PF）以及底栖有孔虫胶结质壳类的百分含量则迅速增加，这三者随水深的变化在3400－3500m处有一明显的转变，被认为是南海东北部CCD面（碳酸盐补偿深度）所在的位置，且该研究区内碳酸盐补偿深度南部较北部深100m。浮游有孔虫水平分布除了受表层海水温度的的控制外，黑潮南海分支以及吕宋岛北端上升流区带来的富营养水体的存在也起很重要的作用。     

杭州湾枯季水沙若干特征分析

根据2014年1月及2017年2月杭州湾大、小潮水沙资料,计算了流速、含沙量、单宽潮量、单宽输沙量,进而分析了潮周期断面净潮量、净输沙量和区域冲淤分布。研究发现杭州湾涨、落潮平均流速比值整体较20世纪八九十年代增大,绝大部分区域大于1.0,涨潮流相对增强,澉浦南岸和金山北岸尤为显著。含沙量平面上分布澉浦、杭州湾南岸两个高值区(大潮大于3 kg/m³,小潮大于1.3 kg/m³)以及北岸湾口至乍浦之间的低值区(大潮小于2 kg/m³,小潮小于0.9 kg/m³),随潮汛变化显著,最大含沙量浓度通常滞后于急流时刻。各测站涨、落潮量和输沙量呈现“大涨大落”和“大进大出”的特征,造成杭州湾短时间尺度内的“大冲大淤”。大潮两涨两落金山与乍浦、乍浦与澉浦之间区域净输沙量可达几千万吨,净冲淤则在几百万吨。     

A bed‐load transport model for rough turbulent open‐channel flows on plane beds

Data from flume studies are used to develop a model for predicting bed‐load transport rates in rough turbulent two‐dimensional open‐channel flows moving well sorted non‐cohesive sediments over plane mobile beds. The object is not to predict transport rates in natural channel flows but rather to provide a standard against which measured bed‐load transport rates influenced by factors such as bed forms, bed armouring, or limited sediment availability may be compared in order to assess the impact of these factors on bed‐load transport rates. The model is based on a revised version of Bagnold's basic energy equation i_bs_b = e_bω, where i_b is the immersed bed‐load transport rate, ω is flow power per unit area, e_b is the efficiency coefficient, and s_b is the stress coefficient defined as the ratio of the tangential bed shear stress caused by grain collisions and fluid drag to the immersed weight of the bed load. Expressions are developed for s_b and e_b in terms of G, a normalized measure of sediment transport stage, and these expressions are substituted into the revised energy equation to obtain the bed‐load transport equation i_b = ω G ^3·4. This equation applies regardless of the mode of bed‐load transport (i.e. saltation or sheet flow) and reduces to i_b = ω where G approaches 1 in the sheet‐flow regime. That i_b = ω does not mean that all the available power is dissipated in transporting the bed load. Rather, it reflects the fact that i_b is a transport rate that must be multiplied by s_b to become a work rate before it can be compared with ω. It follows that the proportion of ω that is dissipated in the transport of bed load is i_bs_b/ω, which is approximately 0·6 when i_b = ω. It is suggested that this remarkably high transport efficiency is achieved in sheet flow (1) because the ratio of grain‐to‐grain to grain‐to‐bed collisions increases with bed shear stress, and (2) because on average much more momentum is lost in a grain‐to‐bed collision than in a grain‐to‐grain one. Copyright © 2006 John Wiley & Sons, Ltd.     

Empirical predictors of annual bed load travel distance,and implications for salmonid habitat restoration and protection

Measurements of annual travel distance (L_b) of bed load sediment at 16 locations in Alaska, the intermountain USA, west coast USA and Scotland are strongly correlated with bankfull channel width (r² = 0·86, p < 0·001). Travel distance of particles is probably limited by trapping in bars, which have a longitudinal spacing proportional to channel width. Increased abundance of woody debris reduces bar spacing and may reduce L_b. Longer cumulative duration of bed load transporting flows in a year appears to increase L_b. Other predictors of annual travel distance such as stream power per unit length, drainage area and bankfull discharge were less well correlated with L_b (r² ranging from 0·27 to 0·51). Stream power per unit bed area, basal shear stress and slope were not significantly related to L_b (r² < 0·05). Most correlations were improved when regressions were limited to data from the west coast USA. Travel distance estimates can be used to help identify reaches that may take longer to recover from large, short‐term increases in sediment supply. Published in 2001 by John Wiley & Sons, Ltd.     

河床沉积物非均质性影响下的潜流交换数值模拟

为了揭示河床沉积物非均质性对潜流交换的影响,构建了沙波地形作用下的地表水-地下水耦合模型,通过生成不同的渗透系数随机场,讨论了不同地表水动力过程和河床沉积物非均质性对潜流交换通量、交换空间及平均停留时间的影响规律。结果表明,所构建的地表水-地下水耦合模型能够准确刻画水沙界面附近流场,模型具有良好的适用性;均质或非均质河床沉积物情景下,水沙界面上的平均交换通量、停留时间与雷诺数之间均呈现幂函数关系,潜流交换深度则在地表水进入完全紊流之后趋于稳定。结果还表明,较强的河床沉积物非均质性能够有效增强水沙界面上潜流交换通量和空间交换频率,但会制约潜流交换空间并缩短水流在潜流带中的停留时间。