含铁闪锌矿热容的实验测定与分析

利用美国ＤｕＰｏｎｔ公司的９９００型差示扫描量热仪对３个含铁闪锌矿样品的热容进行了实验测定,并讨论了定压摩尔热容实验值与实验温度的关系。实验结果表明,在实验条件下,含铁闪锌矿的定压摩尔热容与纯闪锌矿的定压摩尔热容存在显著差异,Ｆｅ置换Ｚｎ是造成这种差异的主要原因。     

中条山—塔儿山成矿带C─Fe─Au矿床成矿系列及成矿模式

中条山—塔儿山成矿带属滨西太平洋成矿域华北断块金、银、铜、铅、锌、锰、铝土矿、金刚石成矿区中的３级成矿带，其中包括２个成矿系列、７个成矿亚系列和１１个矿床式。２个成矿系列具有成矿世代的“双层性”、成矿物质来源的二元性、成矿作用的三阶段和矿化带展布与地质构造单元的趋近性等一系列特征     

X射线荧光光谱法测定叶腊石中的铝铁钾钠

采用同一矿区已知成分含量的叶腊石配制标样系列，克服了粉末法测定叶腊石中Ａｌ２Ｏ３，Ｆｅ２Ｏ３，Ｋ２Ｏ，Ｎａ２Ｏ的矿物和粒度效应。分析结果准确度满足出口材料的检测要求。     

关于成矿系列的结构

成矿系列是一个自然系统,它由若干矿床成因类型组成。各矿床类型间的时空结构关系表现为各类型间的“共生性”、“过渡性”和“重叠性”;其物质结构关系表现为“互补性”.本文按系统论观点,分析了上述结构,提出长江中下游铁铜成矿系列的新模式,并指出研究成矿系列的结构对预测矿产的重要意义.     

Cathodoluminescence of authigenic albite

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).     

Intracrystalline fractionation of Fe in synthetic (Fe, Mg, Zn) - bearing staurolite: a Mössbauer spectroscopic study

⁵⁷Fe-Mössbauer spectra of eleven Fe-Mg-bearing staurolite samples, synthesized at 5, 20 and 25 kbar and 680°C, ranging in composition from x_Fe?=1.00 to x_Fe?=0.15, and of two Zn-Fe-bearing staurolite samples, synthesized at 20 kbar and 700°C with x_Fe?=0.10 and x_Fe?=0.32 were collected at room temperature. The spectra reveal that about 80% of Fe_tot (in case of Fe-Mg-bearing staurolite) and about 70% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the three subsites Fe1, Fe2 and Fe3 of the tetrahedral T2-site. The refinement of the spectra results in almost identical values for the isomer shift (IS) (±1.0 mm/s) but significantly different values for the quadropole splitting (QS) for the three subsites which is in accordance with the different distortions of these sites. About 8% of Fe_tot (in case of Fe-Mg-bearing staurolite) and 13% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the octahedral M4 site, while the remainder percents of Fe_tot indistinguishably occur as Fe²⁺ at the octahedral M1 and M2 sites of the kyanite-like part of the structure. Within the whole Fe-Mg-staurolite solid solution series the Mössbauer parameters QS of the sites M4 and (M1, M2) vary systematically with composition whereas IS remains constant. There is a high negative correlation of the total Mg-content with Fe-occupation of all the Fe-bearing sites indicating a continuous substitution of Fe²⁺ by Mg on all these sites. Synthetic Fe-staurolites show no increasing occupation of the octahedral sites by two-valent cations with pressure, as was assumed by several authors.     

宁芜盆地凹山和东山铁矿床流体包裹体和氢氧同位素研究

本文对宁芜地区凹山和东山铁矿床中的磷灰石流体包襄体进行了较为系统的测温研究,并测定了不同时期形成的磁铁矿、阳起石和石英的 H、O 同位素组成。凹山和东山铁矿磷灰石含有丰富的流体包裹体,原生气液包裹体包括早期细长管状、针状包裹体(类型Ⅱ)和晚期不规则状包襄体(类型Ⅰ);早期包裹体又可分为单一液相包裹体(类型Ⅱ-a)、气液两相(富气相)包襄体(类型Ⅱ-b)、气液两相(富液相)包裹体(类型Ⅱ-c)和气相、液相及固相多相包裹体(类型Ⅱ-d)四种亚类。包襄体中至少含有五种不同的子矿物。磷灰石包裹体记录了多个峰值温度,从600℃～800℃到～410℃和～270℃,分别对应于磷灰石(磁铁矿 透辉石)、阳起石和石英的形成。流体的盐度随温度的降低而逐渐减小,从高达～80%NaCl equiv。到<20%NaCl equiv。磷灰石形成时流体处于不均匀的状态,流体包裹体为非均一捕获。H、O 同位素研究显示成矿流体早期为演化的初始岩浆(水),在高温下形成了铁矿石;此后,成矿流体有可能与蒸发盆地卤水或大气降水发生混合;晚期则可能有较显著的大气降水加入。     

广西新元古代BIF的铁同位素特征及其地质意义

通过分析广西三江地区新元古代条带状含铁建造的Fe同位素和主量元素组成,对海水的氧化还原状态提供了制约,为富禄期的地球处于间冰期提供了证据。相对于标准物质IRMM-014,新元古代含铁建造不同条带全岩样品的δ57Fe值变化范围1.60‰～2.20‰,平均值为1.85‰,表明BIF样品富集铁的重同位素。条带状含铁建造主要由Fe2O3和SiO2组成,但却具有较高的Al2O3含量。这表明条带状含铁建造样品不是纯净的化学沉积物,而是具有一定的碎屑物质输入。碎屑输入量的不同引起深色和浅色条带之间铁同位素组成存在着0.4‰的差别。剔除碎屑的影响,新元古代BIF从海水中沉淀的赤铁矿δ57Fe的平均值在2‰左右,略高于太古代条带状铁建造的Fe同位素组成,这表明当时海水的氧逸度可能比太古代还低。这说明在富禄期绝大部分海洋仍旧被冰盖覆盖,只在局部出现融化。因此,富禄期的地球可能出于冰期的相对温暖阶段,而不是间冰期。     

Searching for ancient gold mines in Filippoi area,Macedonia, Greece,using Worldview-2 satellite imagery

The study area is located near the town of Filippoi, north of the city of Kavala in northern Greece, known from ancient times for its rich gold mines, situated inside hydrothermal alteration zones (Fe–Mn oxide minerals). A Very High-Resolution (0.5 m pixel size) image of Worldview-2 satellite was digitally enhanced, yielding target areas of potential ore existence and lineaments. Ground-truth that followed digital image processing, revealed abandoned ancient mines, slags and ore occurrences. Also, a number of lineaments delineated on the satellite image were verified as faults.     

Transformation of Fe （Ⅱ） and Fe （Ⅲ） in Enclosures of Dongshan Bay

根据2008年8月与11月在东山湾海域获得的调查资料对表层水中溶解态Fe（II）和Fe（III）含量、浮游植物叶绿素a、营养元素及其浓度等环境参数进行分析。结果表明,夏、秋季海水中Fe（II）浓度及其在总溶解铁中所占比例均与浮游植物叶绿素a呈正相关,其相关系数分别为0.7959、0.9219。现场围隔实验表明,海水中总溶解态Fe含量在24 h内有较大的变化,最大减少量达到17.4%。DS2站点海水中Fe（II）浓度及其在总溶解铁中所占比例随光照强度增加而增加。最高值与初始值相比较,叶绿素a较高的DS2站点海水中Fe（II）浓度增加较叶绿素a较低的DS5号站点高0.053μg/L。Fe（II）和Fe（III）加富实验研究了溶解态的Fe（II）和Fe（III）在海水中相互转化。高浓度的Fe（II）在海水中被氧化成Fe（III）,海水中浮游植物也会引发光还原作用使Fe（III）还原成Fe（II）。