流动注射-光度法测定地质样品中痕量碘

利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1％,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1％,检出限为0.08×10~(-6)。测量速度50N/h。     

耐久性设计下水土腐蚀性评价体系的一种解决方案

水土腐蚀性评价标准与混凝土结构耐久性设计的防护标准是相互作用,相互影响的。本文通过2个地下水实例,比较了桩基础和地下室底板在不同规范体系下水土腐蚀性评价标准和防护标准的差异。腐蚀环境越严重,混凝土结构耐久性设计差异越大,因此,有必要统一水土腐蚀性评价标准和混凝土结构耐久性设计的防护标准。针对SO42-和CL-腐蚀性评价差异较大的情况,本文给出了干湿交替作用及其强度的定义,提出了一种统一水土腐蚀性评价指标及其分级的建议方案。干湿交替作用是指在固体表面能够形成液相水与气相水交替转换或持续转换的一种现象,干湿交替作用强度定义为固体表面液态水的相对蒸发速率和固体表层饱和度的乘积。     

南海东北部洋陆过渡区域地震折射波衰减特征

地震波衰减研究是了解岩石圈构造特征的有效方法.本文基于OBS2016-2测线的海底地震仪(OBS)数据, 首次对南海东北部洋陆过渡区域地震波衰减特征进行研究, 通过正演模拟获得该区域二维纵波衰减(Q_P)结构.结果表明, 下陆坡的上地壳存在一个宽约40 km, 厚度约为4~5 km的高衰减区, 其特征为低纵波和横波速度(V_P为5.5~6.3 km·s^-1和V_S为3.1~3.6 km·s^-1)以及较低的波速比(V_P/V_S为1.72~1.80), 对应较低的Q_P(280~410), 推测与断裂发育有关, 且受到火山活动的影响.洋陆过渡及洋壳区域的上地壳高衰减区具有低Q_P(300~400)和高V_P/V_S(1.90~1.96)特征, 可能对应较多的断裂发育及流体运移.洋陆过渡区域下地壳高速异常体表现为相对低的Q_P(550~600), 对应较高的V_P(7.0~7.8 km·s^-1)和V_S(3.5~3.8 km·s^-1)以及较高的V_P/V_S(1.85~1.96), 推测与蛇纹石化作用有关.蛇纹石化可能进一步增加岩石的孔隙度并导致更多的流体运移, 使得洋陆过渡及洋壳区域存在较高的地震波衰减.Q_P结构有助于我们分析南海大陆边缘的地震波衰减特征, 结合V_P、V_S以及V_P/V_S, 可以更好地了解该区域地质结构和岩石属性, 对进一步挖掘OBS数据信息有重要参考价值.

     

地震断错地貌

大地震产生的断错,能改变震前的地表形态,这种改造后新出现的地形景观称为地震断错地貌。地震断错地貌可分为地震断层崖、地震断错——挠曲崖、地震断错水系和地震断错台地四类。研究地震断错的相关堆积时,发现逆推断层崖也有崩积楔。提出的崩积楔发育模式与正断层崖的发育模式截然不同。     

多高层钢结构耐火性能的子结构分析模型与分析方法

基于整体钢结构在局部火灾下的反应规律,将高层钢结构的初始倒塌破坏类型进行了分类(中间柱初始倒塌、边柱初始倒塌以及梁柱同时倒塌),根据整体结构约束影响和荷载影响,提出局部火灾下多高层钢结构耐火性能分析的相应子结构分析模型及其分析方法。子结构模型的边界充分考虑周围约束的影响,尤其是周围梁和上层柱构件以及层数的影响。针对不同类型的子结构模型,通过建立相应的具体子结构有限元模型,合理考虑边界条件的影响。最后基于建立的数值模型,研究了子结构的火灾反应规律与破坏机理,并与整体结构的分析结果进行了比较,结果表明:子结构分析模型与分析方法可以合理准确地分析整体结构的耐火性能。     

岩石爆破损伤模型的比选与改进

归纳了目前应用较为广泛的爆破损伤模型关于损伤变量的定义方法,基于FORTRAN与LS-DYNA自定义接口,将5种典型的爆破损伤模型成功导入LS-DYNA。根据具体的工程实例,对5种爆破损伤模型计算的精确性进行了对比计算和验证。结果表明,KUS模型与RFPA模型对应的结果与实测值更接近。选取计算结果较为准确的KUS模型进行改进,考虑压缩损伤,并修正了宏观弹性常数的确定方法,建立了拉压损伤模型,并对该模型的计算精确性进行验证,结果表明,该拉压损伤模型可以更好地定量描述岩体爆破损伤范围。     

Seismic fracture evaluation of diaphragm joints in welded beam-to-box column moment connections

Steel box columns are widely used in steel building structures in Taiwan due to their dual strong axes. To transfer the beam-end moment to the column, diaphragm plates of the same thickness and elevations as the beam flanges are usually welded inside the box column. The electro-slag welding (ESW) process is widely used to connect the diaphragms to the column flanges in Taiwan because of its convenience and efficiency. However, ESW may increase the hardness of the welds and heat-affected zones (HAZs), while reducing the Charpy-V notch strength in the HAZ. This situation can cause premature fracture of the diaphragm-to-column flange welds before a large plastic rotation is developed in the beam-to-box column joints. To quantify the critical eccentricity and the effectiveness of fracture prediction, this study uses fracture prediction models and finite element model (FEM) analysis to correlate the test results. In this study, two beam-to-box column connection subassembly tests are conducted with different loading protocols and ESW chamber shapes. To implement a fracture prediction model, the material parameters are established from circumferential notched tensile tests and FEM analysis. Test results indicate that the fracture instances can be predicted on the basis of the cumulative plastic deformation in the HAZs. Analytical results indicate that fracture instances and locations are sensitive to the relative locations of the ESW joints and beam flange. Tests also confirm that the possible fracture of the diaphragm-to-column flange joints can be mitigated by enlarging the chamber of the ESW joint.     

Sliding mode fuzzy control: Theory and verification on a benchmark structure

A sliding mode fuzzy control (SMFC) algorithm is presented for vibration reduction of large structures. The rule base of the fuzzy inference engine is constructed based on the sliding mode control, which is one of the non‐linear control algorithms. In general, fuzziness of the controller makes the control system robust against the uncertainties in the system parameters and the input excitation, and the non‐linearity of the control rule makes the controller more effective than linear controllers. For verification of the present algorithm, a numerical study is carried out on the benchmark problem initiated by the ASCE Committee on Structural Control. To achieve a high level of realism, various aspects are considered such as actuator–structure interaction, sensor noise, actuator time delay, precision of the A/D and D/A converters, magnitude of control force, and order of control model. Performance of the SMFC is examined in comparison with those of other control algorithms such as H_{mixed 2/∞}, optimal polynomial control, neural networks control, and SMC, which were reported by other researchers. The results indicate that the present SMFC is efficient and attractive, since the vibration responses of the structure can be reduced very effectively and the design procedure is simple and convenient. Copyright © 2000 John Wiley & Sons, Ltd.     

基于ETABS的钢筋混凝土框架与楼梯共同工作性能分析

本文利用大型结构分析软件ETABS设计了4种包含和不包含楼梯的钢筋混凝土框架计算模型,分别采用底部剪力法、反应谱法和时程分析法对各模型进行了弹性阶段地震反应特性对比计算分析.结果显示:楼梯参与结构整体计算后,结构出现抗侧刚度明显增加、结构扭转振动显著、梯间框架柱剪力突变等现象;建议结构设计时采用包含楼梯的层间结构计算模型(M-4),使用振型分解反应谱法进行结构抗震分析计算.     

Reservoir Characteristics and Genetic Mechanisms of the Mesozoic Granite Buried Hills in the Deep‐water of the Qiongdongnan Basin,Northern South China Sea

Due to its structure,rock and mineral composition,fluid and other factors,the granite Buried Hill Reservoir is highly heterogeneous with a complex longitudinal structure and a reservoir space made up of a combination of dissolution pores and fractures.This paper is based on current understanding of tectonic evolution in the northern part of the South China Sea,in conjunction with the seismic phase characteristics.It is determined that the meshed fault system was formed by three stages of movement-tectonic compression orogeny during the Indochinese epoch,strike-slip compression-tension during the Yanshanian Period,early fracture extension activation during the Himalayan-which controlled the distribution of the Buried Hill Reservoir.Drilling revealed two types of buried hills,faulted anticline and fault horst,their longitudinal structure and the reservoir space type being significantly different.The mineral composition,reservoir space and diagenetic characteristics of the reservoir rocks and minerals were analyzed by lithogeochemistry,micro section and logging etc.,it thus being determined that the Mesozoic rocks of the Songnan Low Uplift in the Qiongdongnan Basin are mainly composed of syenogranite,granodiorite,monzogranite,which is the material basis for the development of the Buried Hill Reservoir.The content of felsic and other brittle minerals is more than 70%,making it easy for it to be transformed into fractures.At the same time,the weathering resistance of granodiorite and monzogranite is weaker than that of syenogranite,which is easily weathered and destroyed,forming a thick sand gravel weathering zone.With increasing depth of burial,weathering and dissolution gradually weaken,the deep acidic fluid improving the reservoir property of internal fractures and expanding the vertical distribution range of the reservoirs.The research results lay a foundation for the exploration of Buried Hill in the deep-water area of the Qiongdongnan Basin.