工业化以来海洋污染历史的分子（元素）地层学记录

本文介绍了运用高分辨率的分子（元素）地层学记录来研究海洋污染历史的原理和方法。通过实例,阐述了利用放射性同位素２１０Ｐｂ等定年的湖泊、河口沉积物以及冰芯、土壤记录来研究环境污染历史的最新进展,指出对近百年来高时间分辨率的近海海域污染历史研究对于评估海域环境负荷变化,预测海洋环境的发展具有十分重要的意义。     

Persistent organic pollutant, trace metal and radionuclide concentrations in bottom organisms of the Barents Sea and adjacent areas

On data of the Barents Sea and some regions of the Kara, White, Norwegian and Greenland Seas transregional study, carried out in 1991–1992, concentrations of various contaminants in benthic algae and invertebrates are defined. According to the results of two-way ANOVA the conclusion about the absence of spatial variability in concentrations of POP, TM and K-40 in the investigated shelf biota is done. Concentrations of the analysed substances in organisms and the differences in contaminant bioaccumulation by plants and animals of various taxons are presented in a form of a table. In spite of the discrepant information about the background level of contamination, given by different authors, the obtained data to a greater degree corresponds to the idea of the background concentration of contaminants in biota, than testify to the man-induced pollution of the investigated area.     

Forty years of anthropogenic radionuclides in surface seawater. Italian and Japanese data

The concentrations of man made radionuclides in surface seawater since early ′60s are here reported as measured in Italy and Japan. Most of the data refers to⁹⁰Sr and¹³⁷Cs, but occasionally the concentrations of⁸⁹Sr and¹³⁴Cs in some Italian samples are also given. The main sources of man made radionuclides were the global fallout produced by the nuclear weapon tests and the Chernobyl accident. The respective contributions to the contamination of surface seawater around both countries are discussed.     

The triggered origin of the solar system

The scenario of the triggered origin of the solar system suggests that the formation of our planetary system was initiated by the impact of an interstellar shock wave on a molecular cloud core. The strength of this scenario lies in its ability to explain the presence of short-lived radionuclides in the early solar system. According to the proposal, the radioactivities were produced in a stellar source, transported into the molecular cloud core by a shock wave and mixed into the collapsing system during the interaction between the shock wave and the core. We examine the viability of the scenario by presenting results from recent numerical simulations. The calculations show that molecular cloud cores can be triggered into collapse by the impact of a shock wave propagating at the velocity of 10–45 km s⁻¹. Some of the shock wave material incident on the core, typically 10–20%, can be injected into the collapsing system. The time scale of the process is ∼10⁴–10⁵ years, sufficiently short for the survival of the short-lived radioactivities. The simulations therefore confirm the viability of the scenario of the triggered origin of the solar system.     

Reconstructing the development of a gully in the Upper Kalaus basin,Stavropol region (southern Russia)

The Stavropol region of southern Russia is severely affected by human‐induced gully erosion. A lack of detailed information on the different stages of gully formation resulting from major agricultural expansion c. 100 years ago, is an obstacle for management and containment of these systems. In this study we combine measurements of particle‐bound radionuclides (¹³⁷Cs, ²¹⁰Pb_ex, ²²⁶Ra, ²³²Th and ⁴⁰K) and classical geomorphology to investigate and reconstruct the different phases of development of a gully during the last c. 100 years. We believe the ?rst phase (1) involved an initial incision into the bottom of a small valley (catchment area c. 1 km²) about 100 years ago. A short period of rapid growth was followed by a longer stage of gully stabilization. Subsequent phases were: (2) the period 1954–1960 – re‐incision in the lower gully reach was initiated by a high‐magnitude rainfall event, and a substantial amount of sediment was delivered to the gully fan; (3) c. 1960–1986 – the knickpoint retreated slowly, sediment was redeposited nearby, and the fan surface became stable; (4) 1986–1987 – a dam was built in the gully mouth and breached shortly after construction following 2 days of high rainfall, and substantial sediment accumulated in the gully above the dam and below the spillway channel on the fan surface; (5) 1987–1993 – the knickpoint retreat continued and the lower fan surface was stable until 1993 when the last signi?cant runoff event overlayed it with c. 10 cm of fresh sediment. These detailed reconstructions of gully development stages allow the contribution of high‐magnitude events to gully growth and regional sediment delivery to be assessed. They further guide management actions to prevent such dam failures in the future. Copyright © 2004 John Wiley & Sons, Ltd.     

Transport process of radionuclides in the East China Sea

Settling particles were collected from six stations at the Okinawa Trough and the East China Sea continental margin. Activities of U, Th, Pu isotopes and ^210Pb were determined for the particles to elucidate their transport processes. Surface sediment samples were also analyzed for their isotopes. There was a tendency for ^210Pb activities to increase almost linearly with depth from 72 m on the continental shelf edge to 1019 m in the Okinawa Trough. Increasing ^210Pb activities in settling particles with depth on the continental margin may be attributable to enhanced ^210Pb scavenging by particles and removal near the front. There also was a clear tendency for total mass fluxes and the radionuclide fluxes to increase with depth, with an especially large increase near the bottom. The ratio of the observed ^210Pb flux to the ^210Pb deficiency flux in the near-bottom traps ranged between 8.9 and 46. These high values show a strong ^210Pb excess which would be attributable to large advective import to the near-bottom and resuspended particles that have settled through the water column but have not been incorporated into the sediments. High variability of radionuclide fluxes occurred in very short time periods. Activities of ^238U, ^232Th, ^230Th, ^228Th, ^210Pb and ^239Pu＋^240Pu in settling particles were significantly higher than those in the underlying surface sediments.     

太阳系~(53)Mn-~(53)Cr同位素体系

短周期放射性核素的初始丰度和分布情况,已成为陨石学和天体化学的重要研究领域之一。已有研究证实地外天体中53 Cr的放射性母体为53 Mn。53 Mn的半衰期为3.7±0.4Ma,可对太阳系形成之后的20Ma内发生的事件进行精确定年。本文系统总结了已报道的碳质球粒陨石、普通球粒陨石、顽辉石球粒陨石和分异陨石中的53 Mn-53 Cr同位素体系数据,依据55 Mn/52 Cr值和53 Cr异常探讨了太阳系形成时53 Mn和53 Cr的初始分布情况、太阳系初始的53 Mn/55 Mn值,讨论了陨石中普遍存在的54 Cr/52 Cr值异常和碳质球粒陨石全岩的54 Cr和53 Cr异常值之间的正相关关系对53 Mn-53 Cr体系定年影响。     

GGR Biennial Critical Review: Analytical Developments Since 2012

Advances in the chemical, crystallographic and isotopic characterisation of geological and environmental materials can often be ascribed to technological improvements in analytical hardware or to innovative approaches to data acquisition and/or its interpretation. This biennial review addresses key laboratory methods that form much of the foundation for analytical geochemistry; again, this contribution is presented as a compendium of laboratory techniques. We highlight advances that have appeared since January 2012 and that are of particular significance for the chemical and isotopic characterisation of geomaterials. Prominent scientists from the selected analytical fields present publications they judge to be particular noteworthy, providing background information about the method and assessing where further opportunities might be anticipated. In addition to the well‐established technologies such as thermal ionisation mass spectrometry and plasma emission spectroscopy, this publication also presents new or rapidly growing methods such as electron backscattered diffraction analysis and atom probe tomography – a very sensitive method providing atomic scale information.