Combined use of spot samples and continuous integrated sampling in a study of storm runoff from a lowland catchment in the south of England

We have used two different sampling techniques to study the geochemical response of a small lowland rural catchment to episodic storm runoff. The first method involves traditional daily spot sampling and has been used to develop a standard end‐member mixing analysis (EMMA) of the relative contributions of ground water flow and surface runoff to the total stream flow. The second method utilizes a continuous sampling device, powered by an osmotic pump, to produce an integrated 24‐h sample of the stream flow. When combined with the EMMA results from the spot samples, analyses of the integrated samples reveal the presence of a third component that makes a significant contribution to the dissolved NO₃, Ca and K export from the catchment during the rising limb of the hydrographic profile of a storm event following a prolonged dry period. The storm occurred in the middle of the night, so that the response of the stream chemistry was not captured by the daily samples. We hypothesize that this third component is derived from the flushing of stored soil water that contains the geochemical signature of decaying vegetation. Copyright © 2011 John Wiley & Sons, Ltd.     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Seasonal,hydrological, and land management factors controlling dissolved organic carbon concentrations in the loch fleet catchments,Southwest Scotland

Dissolved organic carbon (DOC) was measured at hourly or two-hourly intervals during more than 30 events in one forested and two moorland subcatchments of the Loch Fleet catchment in southwest Scotland. The dominantly peaty soils in the catchments resulted in small discharge-related DOC variations within individual events, with a maximum range of about 2 mg 1^?1. Seasonal variations were larger with an amplitude of 8-9 mg 1^?1 and maximum concentrations in the summer months. The forested stream had the highest mean DOC, twice as large as the comparable moorland stream in the preliming phase. Applications of lime to the catchments increased stream DOC concentrations, with the largest increases in the moorland catchments.     

Concentration–discharge relationships reflect chemostatic characteristics of US catchments

Concentration–discharge relationships have been widely used as clues to the hydrochemical processes that control runoff chemistry. Here we examine concentration–discharge relationships for solutes produced primarily by mineral weathering in 59 geochemically diverse US catchments. We show that these catchments exhibit nearly chemostatic behaviour; their stream concentrations of weathering products such as Ca, Mg, Na, and Si typically vary by factors of only 3 to 20 while discharge varies by several orders of magnitude. Similar patterns are observed at the inter‐annual time scale. This behaviour implies that solute concentrations in stream water are not determined by simple dilution of a fixed solute flux by a variable flux of water, and that rates of solute production and/or mobilization must be nearly proportional to water fluxes, both on storm and inter‐annual timescales. We compared these catchments' concentration–discharge relationships to the predictions of several simple hydrological and geochemical models. Most of these models can be forced to approximately fit the observed concentration–discharge relationships, but often only by assuming unrealistic or internally inconsistent parameter values. We propose a new model that also fits the data and may be more robust. We suggest possible tests of the new model for future studies. The relative stability of concentration under widely varying discharge may help make aquatic environments habitable. It also implies that fluxes of weathering solutes in streams, and thus fluxes of alkalinity to the oceans, are determined primarily by water fluxes. Thus, hydrology may be a major driver of the ocean‐alkalinity feedback regulating climate change. Copyright © 2009 John Wiley & Sons, Ltd.     

Application of the SHETRAN basin‐scale,landslide sediment yield model to the Llobregat basin,Spanish Pyrenees

The first application of the SHETRAN basin‐scale, landslide erosion and sediment yield model is carried out for a major landsliding event in the upper 505 km² of the Llobregat basin, in the eastern Spanish Pyrenees, in November 1982. The model simulates the spatial distribution of shallow landslides and their sediment yield. Acknowledging uncertainty in the model parameter evaluation, the aim of the application was not to reproduce the observed occurrence of landslides as accurately as possible with one simulation, but to bracket the observed pattern with several simulations representing uncertainty in the key input conditions. Bounds on the landslide simulations were thus determined as a function of uncertainty in the vegetation root cohesion (used in the model factor of safety calculations). The resulting upper bound considerably overestimates the observed pattern (17 000 landslides compared with an observation of around 700), but it reproduces several of the principal clusters in the observed pattern. The lower bound contains around 500 landslides. The sediment yield estimates (2670–14 630 t km^?2) are comparable to measurements elsewhere in the Pyrenees for extreme events. The results demonstrate an ability to simulate the basin‐scale landslide response to a rainfall event and the resulting sediment yield. They also highlight the need for further research in setting the uncertainty bounds and in avoiding large overestimates of landslide occurrence arising in part from a current inability to model small‐scale controls for a basin of the given size. Copyright © 2006 John Wiley & Sons, Ltd.     

Laboratory simulation experiments on the solid-state greenhouse effect in planetary ices

Icy surfaces like the polar caps of Mars, comets, Edgeworth-Kuiper belt objects or the surface areas of many moons in the outer Solar System behave different than rock and soil surfaces when irradiated by solar light. The latter ones absorb and reflect incoming solar radiation immediately at the surface. In contrast, ices are partially transparent in the visible spectral range and opaque in the infrared. Due to this fact it is possible for the solar radiation to reach a certain depth and increase the temperature of the sub-surface layers directly. This internal temperature rise is called “solid-state greenhouse effect,” in analogy to the classical greenhouse effect in an atmosphere. It may play an important role in the energy balance of various icy bodies in the Solar System. Within the scope of a project conducted at the Space Research Institute of the Austrian Academy of Sciences in Graz the solid-state greenhouse effect was investigated experimentally and theoretically. A number of experiments with diverse materials, focussing mainly on layered samples with a surface cover consisting of transparent H₂O-ice, were performed. The samples were irradiated under cryo-vacuum conditions by a solar simulator. The temperature distributions inside the samples were measured and compared with the results of numerical model calculations. We found that the predicted sub-surface temperature maximum is very clearly measurable in glass beads samples with various particle size distributions, but can also be detected in transparent compact surface ice layers. However, in the latter case it is less distinct than originally expected. Measuring the effect by laboratory methods turned out to be a difficult task due to the shallow depth where the temperature maximum occurs.     

大尺度平原城市精细汇水区分级划分研究

在城市内涝模拟研究中,汇水区划分是十分重要的环节,同时对大尺度平原城市进行汇水区精细划分也是研究者共同研究的技术难点。针对现有基于DEM流向分析的划分方法存在的无法正确反映实际城市复杂地形和流向问题,本文提出了一种顾及地类和流向,适用于大尺度平原城市的精细汇水区分级划分方法。首先,从城市自然地形和主干河流出发,进行一级宏观尺度划分;然后,依据城市主次干道,干渠和管网实现二级中观尺度划分;最后,在二级划分的基础上,结合流向和地类做精细的三级子汇水区微观尺度划分。本文选取东营市30 km²核心主城区进行了验证分析,研究结果表明,划分结果跟实际地物类型和真实流向相吻合,该方法对于大尺度平原城市具有良好的适用性。     

Stability of methane clathrate hydrates under pressure: Influence on outgassing processes of methane on Titan

We have conducted high-pressure experiments in the H₂O-CH₄ and H₂O-CH₄-NH₃ systems in order to investigate the stability of methane clathrate hydrates, with an optical sapphire-anvil cell coupled to a Raman spectrometer for sample characterization. The results obtained confirm that three factors determine the stability of methane clathrate hydrates: (1) the bulk methane content of the samples; (2) the presence of additional gas compounds such as nitrogen; (3) the concentration of ammonia in the aqueous solution. We show that ammonia has a strong effect on the stability of methane clathrates. For example, a 10 wt.% NH₃ solution decreases the dissociation temperature of methane clathrates by 14-25 K at pressures above 5 MPa. Then, we apply these new results to Titan’s conditions. Dissociation of methane clathrate hydrates and subsequent outgassing can only occur in Titan’s icy crust, in presence of locally large amounts of ammonia and in a warm context. We propose a model of cryomagma chamber within the crust that provides the required conditions for methane outgassing: emplacement of an ice plume triggers the melting (if solid) or heating (if liquid) of large ammonia-water pockets trapped at shallow depth, and the generated cryomagmas dissociate surrounding methane clathrate hydrates. We show that this model may allow for the outgassing of significant amounts of methane, which would be sufficient to maintain the presence of methane in Titan’s atmosphere for several tens of thousands of years after a large cryovolcanic event.     

The initial responses of hot liquid water released under low atmospheric pressures: Experimental insights

Experiments have been performed to simulate the shallow ascent and surface release of water and brines under low atmospheric pressure. Atmospheric pressure was treated as an independent variable and water temperature and vapor pressure were examined as a function of total pressure variation down to low pressures. The physical and thermal responses of water to reducing pressure were monitored with pressure transducers, temperature sensors and visible imaging. Data were obtained for pure water and for solutions with dissolved NaCl or CO₂. The experiments showed the pressure conditions under which the water remained liquid, underwent a rapid phase change to the gas state by boiling, and then solidified because of removal of latent heat. Liquid water is removed from phase equilibrium by decompression. Solid, liquid and gaseous water are present simultaneously, and not at the 611 Pa triple point, because dynamic interactions between the phases maintain unstable temperature gradients. After phase changes stop, the system reverts to equilibrium with its surroundings. Surface and shallow subsurface pressure conditions were simulated for Mars and the icy satellites of the outer Solar System. Freezing by evaporation in the absence of wind on Mars is shown to be unlikely for pure water at pressures greater than c. 670 Pa, and for saline solutions at pressures greater than c. 610 Pa. The physical nature of ice that forms depends on the salt content. Ice formed from saline water at pressures less than c. 610 Pa could be similar to terrestrial sea ice. Ice formed from pure water at pressures less than c. 100 Pa develops a low thermal conductivity and a ‘honeycomb’ structure created by sublimation. This ice could have a density as low as c. 450 kg m⁻³ and a thermal conductivity as low as 1.6 W m⁻¹ K⁻¹, and is highly reflective, more akin to snow than the clear ice from which it grew. The physical properties of ice formed from either pure or saline water at low pressures will act to reduce the surface temperature, and hence rate of sublimation, thereby prolonging the lifespan of any liquid water beneath.     

Rain infiltration and crust formation in the extreme arid zone of the Atacama Desert, Chile

A key question in understanding life on Mars under dry(ing) conditions is how arid soils respond to small levels of liquid water. We have conducted a series of simulated rain experiments in the hyperarid core region of the Atacama Desert. Rain amounts from 0.24 to 3.55 mm were applied in the early evening to the soil. We conclude that rain events of less than 1 mm do not saturate the surface, and the soil humidity at the surface remains below 100%. Rain events of 2 mm or more generate free water in the pore space of the soil surface, which may be necessary to support biological activity in the soil. The crust on the surface of the soil is a strong barrier to the diffusion of subsurface moisture and subsequent evaporation. Our results show that once the relative humidity in hyperarid soils begins to fall below 100% the rate of decrease is quite rapid. Thus, the precise value assumed for the limits of life or water activity, do not appreciably change the time of water availability resulting from small desert rains. The Atacama Desert results may be applied to models of (H₂O) wetting in the upper soils of Mars due to light rains, melting snow and heavy precipitating fog.