中国南极科学考察第24航次大气CO2遥感算法及其在第26航次中的应用分析

利用中国南极科学考察第24航次采集的大气CO₂浓度与AIRS的大气红外辐亮度进行统计回归,获取两者间的拟合关系。与该航次随机选取的60°S附近验证点比较,平均相对偏差为1.09%。同时,将拟合函数应用于对应第26航次同位置、近时间点的AIRS大气辐射值,其结果和第26航次走航数据进行比对,平均相对偏差为2.12%。对比同纬度下第24航次的精度,其精度有明显的下降,结果表明,利用统计回归的计算方式具有一定的局限性。     

A REGIONAL MODEL STUDY OF THE VARIATIONS AND DISTRIBUTIONS OF OZONE AND ITS PRECURSORS ON EASTERN ASIA AND WEST PACIFIC OCEAN REGIONS*

A simulated study of mechanism for variations and distributions of ozone and its precursors was made by using the three-dimensional regional Eulerian model.The results showed that the ozone production was controlled by NO_x,but there is a complicated nonlinear relation between them.The photochemical reactions controlled by solar radiation are the determinative factors affecting the variations of the surface ozone and its precursors.The relations of ozone and CO,PAN were studied.We compared the simulated and observed results during the PEM-WEST A in order to better understand the photochemical processes of ozone and its precursors.     

MEASUREMENTS OF REACTIVE NITROGEN SPECIES IN THE EASTERN CHINA DURING THE EXPERIMENT PEM-WEST A

Measurements of NO_x(NO+NO_2),HNO_3,particulate nitrate,and total odd nitrogen NO_y were made at Linatmosphere regional background station during the NASA GTE/PEM-WEST A in the fall of 1991.NO_x and Nwere measured using chemiluminescence detectors.HNO_3 and aerosol nitrate(NO_3~-)were collected by a filter systNO_x concentration exhibits a significant diurnal variation:maximum occurring in the evening and postsunrise wpeak occurring following sunrise.Unlike NO_x,NO_y does not show distinct diurnal variations.From the ratiosday/night NO_x concentration and the diurnal cycles of two kinds of weather conditions,it is clear thatphotochemical production of NO_x varies with solar radiation.NO_x is the major component of total odd nitroNO_y and NO_2 is the major portion of NO_x as well.The regional background concentrations of NO_x,NO_y,aerosoltrate(NO_3~-)and HNO_3 range from 4.77 to 7.02 ppb,9.24 to 10.95 ppb,0.33 to 2.38 ppb and 0.31 to 0.97 ppb in a dayaverage,respectively.In the eastern China,the biomass burning is an important local emission source of nitrospecies.The ratios of NO/NO_2,NO_x/NO_y,HNO_3/NO_y,NO_3~-/NO_y and HNO_3/NO_x are also discussed inpaper.     

天然气水合物发现区和潜在区气源成因

为探讨天然气水合物发现区的气源成因,对ODP 204航次4个站位58个沉积物样品进行5个温度点的生气量模拟实验,对各温度点产生的气体进行同位素测定。测试结果显示,在低温阶段（25 ℃、35 ℃、45 ℃）,甲烷的δ¹³C明显偏大,一般大于-40‰,显示出热解成因气的特征;而高温阶段（55 ℃）甲烷的δ¹³C为-75.5‰,显示出明显的生物成因气的特征。结合东沙海域天然气水合物潜在区气源成因的讨论,可以得出如下结论：天然气水合物的气源成因受控因素多,需要综合多种指标进行判别。     

综合大洋钻探计划311航次沉积物中自生黄铁矿及其硫稳定同位素研究

对综合大洋钻探计划(IODP)311航次652个岩心沉积物样品进行了自生黄铁矿颗粒筛选、显微形貌特征及其硫稳定同位素组成等初步研究。扫描电镜(SEM)照片显示黄铁矿以微球粒状和立方体状形貌产出,其成因与微生物作用和无机作用有关。黄铁矿的δ34SCDT值变化范围较大,从-35.4‰到+53.6‰,其成因与甲烷厌氧氧化作用(AOM)的关系密切。海水源为主的硫酸盐参与了沉积物上部的AOM过程,黄铁矿硫稳定同位素正偏的原因可能与较强的AOM作用和较多的残余硫酸盐参与有关。冷泉背景站位中黄铁矿的δ34SCDT值随着深度增加而增加,从浅表层的-35.83‰增加到深处的32.49‰,反映深处沉积物内黄铁矿形成过程中曾有过较多的残余硫酸盐参与还原,暗示其背景曾经是更高的甲烷通量和更强的AOM作用。研究结果提供了现代海洋天然气水合物背景下沉积物中自生黄铁矿及其硫稳定同位素特征记录,对于寻找我国海域天然气水合物资源,探索地史时期古海洋沉积物中甲烷事件记录具有重要的意义。     

Chemical composition of sediments from the subducting Cocos Ridge segment at the Southern Central American subduction zone

Subducted sediments play an important role in the magmatism at subduction zones and the formation of mantle heterogeneity, making them an important tracer for shallow crustal processes and deep mantle processes.Therefore, ascertaining the chemical compositions of different subduction end-members is a prerequisite for using subducted sediments to trace key geological processes. We reports here the comprehensive major and trace element analyses of 52 samples from two holes（U1414 A and U1381 C） dri...     

白令海Navarinsky海底峡谷地震剖面解译

第五次北极科学考察在北极区的白令海首次进行了高分辨率单道地震作业。Navarinsky峡谷头部测线BL11-12剖面中部识别出不对称沙波,陡的一面朝向陆架,波高约为9m、波长约为882m。结合站位U1345的沉积速率及站位U1344表层纵波速率推测沙波沉积可以追溯到中更新世(距今约0.258Ma),同时近陆架的洼地逐渐填平。将地层分为3个沉积层,分析沉积物变化情况,结合0.25Ma以来白令海海平面变化历史,推测最大海退事件对应的界面。结合沙波的地理位置及海平面变化情况,认为内波对沙波的形成起主要作用。     

Heat flow measurements on the Lomonosov Ridge, Arctic Ocean

Heat flow was measured on the Lomonosov Ridge during the 5th Chinese National Arctic Expedition in 2012. To derive the time-temperature curve, resistivity data were transformed to temperature by the resistivity- temperature program. Direct reading and linear regression methods were used to calculate the equilibrium temperature, which were regressed against the depth of the probes in sediment to derive the geothermal gradient. Then, heat flow was calculated as the product of geothermal gradient and thermal conductivity of sediments. The heat flow values on the basis of the two methods were similar （i.e., 67.27 mW/m2 and 63.99 mW/m2, respectively）. The results are consistent with the measurements carried out at adjacent sites. The age of the Lomonosov Ridge predicted by the heat flow-age model was 62 Ma, which is in accordance with the inference that the ridge was separated from Eurasia at about 60 Ma.     

Subduction initiation and ophiolite crust: new insights from IODP drilling

International Ocean Discovery Program (IODP) Expedition 352 recovered a high-fidelity record of volcanism related to subduction initiation in the Bonin fore-arc. Two sites (U1440 and U1441) located in deep water nearer to the trench recovered basalts and related rocks; two sites (U1439 and U1442) located in shallower water further from the trench recovered boninites and related rocks. Drilling in both areas ended in dolerites inferred to be sheeted intrusive rocks. The basalts apparently erupted immediately after subduction initiation and have compositions similar to those of the most depleted basalts generated by rapid sea-floor spreading at mid-ocean ridges, with little or no slab input. Subsequent melting to generate boninites involved more depleted mantle and hotter and deeper subducted components as subduction progressed and volcanism migrated away from the trench. This volcanic sequence is akin to that recorded by many ophiolites, supporting a direct link between subduction initiation, fore-arc spreading, and ophiolite genesis.