Survey on PCDDs and PCDFs in sediments and soils in Ya-Er Lake area, China

INTRODUCTIONOverthepastseveralycars,considerableinteffethasbocenteIdontheenvir0nmentalbehaviouroftoxicandpersistritcomP0undssuchashalogenatalaromat-ies,inparticularthepolychiorinataldibopdioxins(PCDDe)andpolydil0rinateddi~fUtansrpCDFs).ManyofthesecomPounds,espedllythosewithahighdegere0fchiorinesubstitution,arehighlylipophiliccontawhnantSwithlowWhtersolubility,highre-sistancet0chdricaltransformationsandlowwhcrobiologhaldegradatfonpeatnnann,l988,Bromanetal.,l989,Hites,l990)whichexplain…     

Observations of the North Equatorial Current,Mindanao Current,and Kuroshio current system during the 2006/07 El Niño and 2007/08 La Niña

Two onboard observation campaigns were carried out in the western boundary region of the Philippine Sea in December 2006 and January 2008 during the 2006/07 El Niño and the 2007/08 La Niña to observe the North Equatorial Current (NEC), Mindanao Current (MC), and Kuroshio current system. The NEC and MC measured in late 2006 under El Niño conditions were stronger than those measured during early 2008 under La Niña conditions. The opposite was true for the current speed of the Kuroshio, which was stronger in early 2008 than in late 2006. The increase in dynamic height around 8°N, 130°E from December 2006 to January 2008 resulted in a weakening of the NEC and MC. Local wind variability in this region did not appear to contribute to changes in the current system.     

Magmatic evolution of Li–F, rare-metal granites: a case study of melt inclusions in the Khangilay complex, Eastern Transbaikalia (Russia)

We report compositions of homogenized quartz-hosted melt inclusions from a layered sequence of Li-, F-rich granites in the Khangilay complex that document the range of melt evolution from barren biotite granites to Ta-rich, lepidolite–amazonite–albite granites. The melt inclusions are crystalline at room temperature and were homogenized in a rapid-quench hydrothermal apparatus at 200 MPa before analysis. Homogenization runs determined solidus temperatures near 550 °C and full homogenization between 650 and 750 °C. The compositions of inclusions, determined by electron microprobe and Raman spectroscopy (for H₂O), show regular overall trends of increasing differentiation from the least-evolved Khangilay units to apical units in the Orlovka intrusion. Total volatile contents in the most-evolved melts reach over 11 wt.% (H₂O: 8.6 wt.%, F: 1.6 wt.%, B₂O₃: 1.5 wt.%). Concentrations of Rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe. The resulting trends of melt evolution are similar to those described by the whole-rock samples, despite petrographic evidence for albite- and mica-rich segregations previously taken as evidence for post-magmatic metasomatism.

Melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative Qz–Ab–Or system. However, melts trapped in the highly evolved pegmatitic samples from Orlovka deviate from the minimum melt composition and show compositional variations in Al, Na and K that requires a different explanation. We suggest that unmixing of the late-stage residual melt into an aluminosilicate melt and a salt-rich dense aqueous fluid (hydrosaline melt) occurred. Experimental data show the effectiveness of this process to separate K (aluminosilicate melt) from Na (hydrosaline melt) and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite.     

赤道东北太平洋沉积物中生物钡的分布特征

分析了赤道东北太平洋海域沉积物中Ba、Ti、Al和有机碳(Corg)的含量。研究表明,研究区沉积物中钡为0.198%~0.792%;采用标准陆源物质扣除法获得的生物钡(Babio)的含量为0.162%~0.764%,占沉积物中总钡含量的81.6%~96.5%,平均为88.7%,其在沉积物中的分布表现为上部一致,下部变化较大;有机碳(Corg)的含量为0.18%~0.58%,并表现为随沉积物深度的增加而降低。沉积物中Babio/Ti的比值表现为东区高于西区,且向高纬度降低的特点,而沉积物中Corg/Ti和Babio/Ti则表现为负相关关系,表明研究区沉积物中钡可能和上层海洋生产力的相关性不明显。     

近年来厄尔尼诺期间北赤道流输运的年际变化

为了研究近年来厄尔尼诺期间北赤道流输运的年际变化,本文利用海洋客观分析数据MOAA GPV(Grid Point Value of the Monthly Objective Analysis)以及P-vector方法计算了北太平洋绝对地转流,探讨了2001~2013年期间厄尔尼诺与北赤道流输运之间的关系。在此期间发生的4次厄尔尼诺事件中,北赤道流输运在2002~2003、2006~2007、2009~2010年的厄尔尼诺成熟期都出现了明显的增强,但是在2004~2005年的厄尔尼诺成熟期并没有明显的增强。进一步分析发现,在2002~2003年、2006~2007年、2009~2010年的厄尔尼诺成熟期,10°N以南的热带西北太平洋区域出现了负的海面高度异常和气旋式环流异常,这主要是由热带环流区域出现的西风异常和正的Ekman抽吸通过Rossby波西传到热带西太平洋区域所致;但是在2004~2005年厄尔尼诺成熟期,海面温度异常的分布明显不同,西风异常和正的Ekman抽吸异常明显北移,导致负的海面高度异常和气旋式环流异常出现在了10°N以北的西北太平洋区域,使得北赤道流输运在2004~2005年的厄尔尼诺成熟期没有明显的增强。     

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.     

1991—1992年ENSO事件的特征

根据美国国家海洋大气局气候分析中心（ＣＡＣ）和中国气象局气候监测公报所提供的海－气资料，综合分析了１９９１－１９９２年ＥＮＳＯ事件的形成、发展过程。这次ＥＮＳＯ事件的主要特点是：①在ＥＮＳＯ事件爆发前一年内热带太平洋海气特性频频呈现异常，暖水堆积在赤道中太平洋（５°Ｎ－５°Ｓ，１６０°Ｅ－１６０°Ｗ）约１２个月，然后自西向东传输，爆发１９９１－１９９２年ＥＮＳＯ事件。②对ＥＮＳＯ事件作出响应的西太     

The circulation of the eastern tropical Pacific: A review

During the 1950s and 1960s, an extensive field study and interpretive effort was made by researchers, primarily at the Scripps Institution of Oceanography, to sample and understand the physical oceanography of the eastern tropical Pacific. That work was inspired by the valuable fisheries of the region, the recent discovery of the equatorial undercurrent, and the growing realization of the importance of the El Niño phenomenon. Here we review what was learned in that effort, and integrate those findings with work published since then as well as additional diagnoses based on modern data sets.Unlike the central Pacific, where the winds are nearly zonal and the ocean properties and circulation are nearly independent of longitude, the eastern tropical Pacific is distinguished by wind forcing that is strongly influenced by the topography of the American continent. Its circulation is characterized by short zonal scales, permanent eddies and significant off-equatorial upwelling. Notably, the Costa Rica Dome and a thermocline bowl to its northwest are due to winds blowing through gaps in the Central American cordillera, which imprint their signatures on the ocean through linear Sverdrup dynamics. Strong annual modulation of the gap winds and the meridional oscillation of the Intertropical Convergence Zone generates a Rossby wave, superimposed on the direct forcing, that results in a southwestward-propagating annual thermocline signal accounting for major features of observed thermocline depth variations, including that of the Costa Rica Dome, the Tehuantepec bowl, and the ridge–trough system of the North Equatorial Countercurrent (NECC). Interannual variability of sea surface temperature (SST) and altimetric sea surface height signals suggests that the strengthening of the NECC observed in the central Pacific during El Niño events continues all the way to the coast, warming SST (by zonal advection) in a wider meridional band than the equatorially trapped thermocline anomalies, and pumping equatorial water poleward along the coast.The South Equatorial Current originates as a combination of equatorial upwelling, mixing and advection from the NECC, and Peru coastal upwelling, but its sources and their variability remain unresolved. Similarly, while much of the Equatorial Undercurrent flows southeast into the Peru Undercurrent and supplies the coastal upwelling, a quantitative assessment is lacking. We are still unable to put together the eastern interconnections among the long zonal currents of the central Pacific.     

中、低纬度地区电离层不同层结间的耦合对夜晚F区不规则结构的影响

电离层不规则结构的形成和演化与电离层等离子体不稳定性密切相关 .长期以来 ,在中低纬区扩展 -F现象的研究中 ,没有考虑电离层上下层结之间的相互作用 .本文从理论上全面探讨了在中纬度地区 ,E区可变的Pedersen电导率和Hall电导率 ,与F区可变的Pedersen电导率的共同作用对F区梯度漂移不稳定性的影响 ,导出了存在这种耦合时电离层梯度漂移不稳定性的统一表达式 .这一耦合理论不但解释了实际观测中发现的 ,在某些地方电离层F区顶部的不稳定性发生率要高于F区底部这一现象 ;同时还表明 ,电离层E区与F区的耦合对F区夜晚梯度漂移不稳定性的形成不仅会有阻碍作用 ,同时还使得中、低纬度地区的扰动增长具有了方向的选择性 .该理论的一个重要结论是 ,F区中某一地区能否发展出梯度漂移不稳定性 ,并不完全由当地电离层F区的状态决定 ,同一根磁力线连接的、位于不同纬度地区的E区层结对其发展和演化也会有相当大的影响 .     

南海上层经向翻转环流的低频变化

The low-frequency variability of the shallow meridional overturning circulation(MOC) in the South China Sea(SCS) is investigated using a Simple Ocean Data Assimilation(SODA) product for the period of 1900–2010. A dynamical decomposition method is used in which the MOC is decomposed into the Ekman, external mode, and vertical shear components. Results show that all the three dynamical components contribute to the formation of the seasonal and annual mean shallow MOC in the SCS. The shallow MOC in the SCS consists of two cells: a clockwise cell in the south and an anticlockwise cell in the north; the former is controlled by the Ekman flow and the latter is dominated by the external barotropic flow, with the contribution of the vertical shear being to reduce the magnitude of both cells. In addition, the strength of the MOC in the south is found to have a falling trend over the past century, due mainly to a weakening of the Luzon Strait transport(LST) that reduces the transport of the external component. Further analysis suggests that the weakening of the LST is closely related to a weakening of the westerly wind anomalies over the equatorial Pacific, which leads to a southward shift of the North Equatorial Current(NEC) bifurcation and thus a stronger transport of the Kuroshio east of Luzon.