Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.     

基于放样原理的特种罐内测法容量计量技术

特种罐在能源的储备和运输中具有重要意义,在研究特种罐现有容量计量技术的基础上,自主创新提出了基于放样原理和测量机器人实现特种罐容量快速和精密计量的原理和方法。将特种罐容量计量转化为点位放样问题,较好地克服了全站仪现有测量技术的缺点,并利用软件实现了特种罐容量计量的数据采集、数据计算、数据修正和报表输出的一体化。通过实际测量数据,分析了该方法的测量精度和测量效率。     

微波消解在环境样品分析中的应用

微波消解是近年来兴起的一种样品分析手段,具有快速、高效、试剂用量少、样品不易被沾污、节约能源等优点。对当前微波消解技术在环境样品分析领域的应用和研究现状进行了综述,介绍了微波消解技术的基本原理、特点和设备,尤其对它在环境样品分析中的应用作了较为详细的介绍,并对该技术的应用前景进行了展望。     

基于空间信息技术的堰塞湖库容分析方法研究

快速准确计算堰塞湖库容,对了解地震堰塞湖险情具有重要的意义.利用遥感和地理信息系统等空间信息技术,提出了一种基于像素的三维水面的计算动库容的方法,能准确计算水面为曲面,包括动库容在内的总库容.该方法利用遥感影像提取水体边界线,与DEM求交后可得到带高程的边界点,利用空间插值技术获得三维水面,然后利用库容计算模型求解.同时,在分析该算法计算效率的基础上,提出了基于河流分段的库容计算优化算法,最后通过实验对比分析了该方法的合理性和优越性.     

中国西部环境与生态科学数据中心：面向西部环境与生态科学的数据集成与共享

国家自然科学基金委员会“中国西部环境与生态科学研究计划”自2001年启动以来,有力地推动了西部区域环境演化、陆地生态过程和人类活动对环境的影响等方面的研究,积累了丰富的基础数据。国家自然科学基金委员会“中国西部环境与生态科学数据中心”承担“西部计划”项目数据产出的收集、管理、集成,并面向西部环境与生态科学的各个领域提供科学数据服务。“西部数据中心”的总体框架是以“西部计划”和地球系统科学发展的科学需求为导向,建成以数据共享、知识积累、合作交流和数据科学为主要内容的集成平台,为“西部计划”多学科的交叉研究和成果的综合集成及地球科学发展的长远目标服务。以共建共享的指导思想集成针对西部环境与生态现状与变化的基础背景数据、环境与生态观测数据、模型数据集、数据工具及数据文档;并以完全与开放的数据共享原则为用户提供推送式数据服务。目前,“西部数据中心”已完成了数据共享平台、知识积累平台与合作交流平台的开发和集成,初步形成了科学数据平台,整理并发布了大量的西部环境生态科学所需的关键数据集。     

松辽盆地葡萄花油田北部鞍部地区成藏控制因素分析

在系统描述葡萄花油田北部鞍部地区构造特征和断裂体系的基础上,分析了烃源岩大量排烃期与构造形成时期的匹配关系、砂体分布、地层压力和断层封闭性对研究区成藏的控制作用。研究结果表明:烃源岩大量排烃期和构造形成时期良好匹配,地层压力低势区和在成藏时期断块边界断层侧向开启是成藏的有利条件,构造和砂体分布则是成藏的主要控制因素。研究区成藏条件较好,可作为有利扩边潜力区。     

辽宁省水资源承载能力的探讨分析

分析了辽宁省水资源的现状和开发利用程度,探讨了辽宁省水资源的承载能力。总结出辽宁省水资源严重短缺;水资源开发利用程度高;水资源供需矛盾突出;未来对水资源的需求量将不断增大,采取切实措施,实现水资源可持续利用,为辽宁的经济发展提供支撑,为东北老工业基地振兴战略的实施提供保障。     

Fluid Geochemistry as Indicator of Tectonically-Related,Deep Water Circulations in the Sardinian Rift-Campidano Graben (Italy): New Insights from Environmental Isotopes

The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO₃ and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO₂ contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ¹³C_TDIC values suggest the presence of two distinct CO₂ sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO₂ and He indicates an increased mantle signature in uprising CO₂-rich fluids.     

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.     

上海城市发展的环境问题及其对策研究

上海市的发展战略;空间布局模式和环境管理是文章讨论的三个主要问题。作者认为:(1)战略设想要立足于上海的发展,“开发浦东、振兴上海、服务全国、面向世界;”(2)新的空间布局模式应为“逐步形成新的CBD,强化和完善金融和服务功能”;(3)城市发展和环境建设要协调。文章着重讨论了上海城市发展中出现的环境问题及其治理的对策和措施。