SIMULATING THE RESPONSE OF NON-UNIFORMITY OF PRECIPITATION EXTREMES OVER CHINA TO CO2 INCREASING BY MIROC_HIRES MODEL

The response of non-uniformity of precipitation extremes over China to doubled CO2has been analyzed using the daily precipitation simulated by a coupled general circulation model,MIROC_Hires.The major conclusions are as follows:under the CO2increasing scenario(SRES A1B),the climatological precipitation extremes are concentrated over the southern China,while they are uniformly distributed over the northern China.For interannual variability,the concentration of precipitation extremes is small over the southern China,but it is opposite over the northern China.The warming effects on the horizontal and vertical scales are different over the northern and southern part of China.Furthermore,the atmospheric stability is also different between the two parts of China.The heterogeneous warming is one of the possible reasons for the changes in non-uniformity of precipitation extremes over China.     

Determination of Rare Earth Elements and Thorium at Nanogram Levels in Ultramafic Samples by Inductively Coupled Plasma‐Mass Spectrometry Combined with Chemical Separation and Pre‐concentration

A method was developed for the determination of low‐level rare earth elements (REEs) and thorium in ultramafic samples by inductively coupled plasma‐mass spectrometry. The conventional method for the digestion of ultramafic rocks using HNO₃ and HF results in considerable amounts of insoluble fluorides because of the high contents of Mg (generally up to 24% m/m) in these rocks. In this study, we used H₃BO₃ as a complexing agent to break down the insoluble fluorides, and then separated the REEs from Fe and Mg major and Ba, Ca, Cr minor matrices by anion exchange and co‐precipitation, respectively. The whole procedural blanks estimated from sample‐free analyses ranged from 0.232 ng for Ce to 0.006 ng for Tm and Lu. Limits of detection for this method, defined as three times the standard deviation of these blank analyses, varied from 0.51 ng g^?1 for Ce to 0.03 ng g^?1 for Lu. The recovery of REEs using this technique, as determined using the standard addition method, ranged from 92.9% for Y to 102.0% for Er with 3% (RSD) variation. The method was validated using GAS (GeoPT‐12), JP‐1 and PCC‐1, and the results were comparable to literature values, elucidating the applicability to the determination of ultra trace REEs in ultramafic rocks.     

河南省主要河道径流年内分配规律探讨

基于河南省四大流域代表性河道控制站1950~2011年月径流序列,采用集中度Cd、集中期Cp、不均匀系数Cv等多指标分析方法,分析了各站径流年内分配特征和规律,并采用M-K趋势分析法,研究各站月径流序列变化趋势。结果表明:河南省自南向北各河流,月径流集中度和不均匀度有减小趋势,径流重心也逐次后移,且存在两个跳跃区间,黄河、伊洛河、卫河Cd、Cv处于低值区间,淮河干流及淮南支流、洪汝河、沙颍河、唐白河Cd、Cv处于高值区。1980年以后,各站径流集中度降低、集中期延后、不均匀系数变小。北部和西北部河流月径流呈显著减小趋势;南部河流4、5月份径流量有显著减小趋势,其它月份增加或减小的趋势不显著;中部、西南部河流各月径流量增加或者减小的趋势不显著。汛期径流总量,北部和西北部河流有显著减小趋势,其它河流增加或减少的趋势不显著。     

湖北省磷矿资源的空间富集规律及其产业布局

湖北省的磷矿资源储量居全国之首,矿床类型以元古宙海相沉积型磷块岩矿床为主,分布集中在五大区域,开发利用条件较好。虽然湖北的磷矿资源勘查近年取得了突破性的进展,但由于资源利用合理度欠缺、磷化工企业规模小、产业链不完善及产业集中度低等原因,对磷矿开发和磷化工产业的可持续发展构成了制约。磷矿资源的合理开发利用对建设磷矿开发及磷化工产业集群、保障国家粮食安全具有重要意义。因此,在勘查部署上,要根据成矿条件、空间富集规律和勘查开发现状,统一部署,分类开展工作;在产业布局上,以宜昌、保康、荆襄、黄麦岭4大磷化工基地为主体,新建鹤峰、黄梅磷肥基地,打造"一圈多点"式产业集群;在产业关联上,新建磷矿产地与现有磷化工基地之间形成以老带新、以新助老、空间互动的产业格局;在产品分工上,支持现有磷化工基地内的骨干企业兼并重组,提高产业集中度。     

不同浓度、pH值SDBS压裂液对页岩储层特性影响研究

在页岩储层压裂过程中,不同浓度、不同pH值的SDBS压裂液体系会直接影响页岩储层稳定性,进而影响造缝性能。通过实验分析了页岩储层在不同浓度、pH值的SDBS压裂液作用下的膨胀抑制性、润湿反转性能。实验结果表明：0.02%SDBS压裂液下页岩储层的膨胀变形最小、膨胀变形速率最慢,即膨胀抑制效果最好;0.03%SDBS压裂液下页岩的润湿性改造最好,接触角为30 °。pH值为8的SDBS压裂液对炭质页岩的膨胀变形和膨胀速率起到了最佳的抑制作用;pH值为9的SDBS压裂液对炭质页岩的润湿反转起到了最好的效果,接触角为31.6°。综合分析认为不同浓度、不同pH值的SDBS压裂液对页岩储层特性影响差异较大,说明在对页岩储层的开发利用中,调整SDBS浓度和pH值对提高页岩气开采效果是可行的。     

TSC大孔螯合树脂对金铂钯的吸附特性及其在岩矿分析中的应用

本文研究了TSC大孔螯合树脂对贵金属Pt(Ⅳ)、Pd(Ⅱ)、Au(Ⅲ)和贱金属Cu(Ⅱ)、Pb(Ⅱ)、Zn(Ⅱ)、Fe(Ⅲ)、Al(Ⅲ)等的吸附特性。测定了树脂在不同酸度下对Au(Ⅲ)、Pt(Ⅳ)、Pd(Ⅱ)的饱和吸附容量。研究结果表明,该树脂可从稀HCl、稀王水溶液中定量吸附Au(Ⅲ)、Pt(Ⅳ)、Pd(Ⅱ),而贱金属离子则不被吸附。吸附在树脂上的Au、Pt、Pd可被5％硫脲溶液洗脱,洗脱液中的Au、Pt、Pd可分别用火焰和无火焰原子吸收法测定。标准加入回收率为97—107％。通过对MGI-Au-07,MCM-02标准样品和其它样品的测定,说明应用本法可获得满意的结果。     

Processes controlling solubility of biogenic silica and pore water build-up of silicic acid in marine sediments

Dissolution experiments in batch and flow-through reactors were combined with data on sediment composition and pore water silicic acid profiles to identify processes controlling the solubility of biogenic silica and the build-up of silicic acid in marine sediments. The variability of experimentally determined biogenic silica solubilities is due, in part, to variations in specific surface area and Al content of biosiliceous materials. Preferential dissolution of delicate skeletal structures and frustules with high surface areas leads to a progressive decrease of the specific surface area. This may cause a reduction of the solubility of deposited biosiliceous debris by 10–15%, relative to fresh planktonic assemblages. Dissolution of lithogenic (detrital) minerals in sediments releases dissolved aluminum to the pore waters. This aluminum becomes structurally incorporated into deposited biogenic silica, further decreasing its solubility. Compared to Al-free biogenic silica, the solubility of diatom frustules is lowered by as much as 25% when one out of every 70 Si atoms is substituted by an Al(III) ion.The build-up of silicic acid in pore waters of sediments with variable proportions of detrital matter and biogenic silica was simulated in batch experiments using kaolinite and basalt as model detrital constituents. The steady-state silicic acid concentrations measured in the experiments decreased with increasing detrital-to-opal ratios of the mixtures. This trend is similar to the observed inverse relationship between asymptotic pore water silicic acid concentrations and detrital-to-opal ratios in Southern Ocean sediments. Flow-through reactor experiments further showed that in detrital-rich sediments, precipitation of authigenic alumino-silicates may prevent the pore waters from reaching equilibrium with the dissolving biogenic silica. This agrees with data from Southern Ocean sediments where, at sites containing more than 30 wt.% detrital material, the pore waters remain undersaturated with respect to the experimentally determined in situ solubility of biogenic silica.The results of the study show that interactions between deposited biogenic silica and detrital material cause large variations in the asymptotic silicic acid concentration of marine sediments. The production of Al(III) by the dissolution of detrital minerals affects the build-up of silicic acid by reducing the apparent silica solubility and dissolution kinetics of biosiliceous materials, and by inducing precipitation of authigenic alumino-silicate minerals.     

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Application of the honey-bees mating programming (HBMP) algorithm to sediment concentration modelling

Abstract

The honey-bees mating programming (HBMP) algorithm is introduced as a novel tool for predicting suspended sediment concentration for the Mad River catchment near Arcata, USA. The paper also applies gene expression programming (GEP) as a comparison and shows that these two approaches can the produce transparent, nonlinear relationships between the independent and dependent variables. Some modifications have been made to the HBMP algorithm to improve its capability and efficiency. The results achieved from this method and GEP are compared with two different sediment rating curves based on regression techniques. The findings show that the results from both the HBMP and GEP methods are promising and outperform the results obtained from the sediment rating curves.

Editor D. Koutsoyiannis; Associate editor L. See     

Estimating time parameters of overland flow on impervious surfaces by the particle tracking method

Abstract

Travel time and time of concentration T_c are important time parameters in hydrological designs. Although T_c is the time for the runoff to travel to the outlet from the most remote part of the catchment, most researchers have used an indirect method such as hydrograph analysis to estimate T_c. A quasi two-dimensional diffusion wave model with particle tracking for overland flow was developed to determine the travel time, and validated for runoff discharges, velocities, and depths. Travel times for 85%, 95% and 100% of particles arrival at the outlet of impervious surfaces (i.e. T_t85, T_t95, and T_t100) were determined for 530 model runs. The correlations between these travel times and T_c estimated from hydrograph analysis showed a significant agreement between T_c and T_t85. All the travel times showed nonlinear relationships with the input variables (plot length, slope, roughness coefficient, and effective rainfall intensity) but showed linear relationships with each other.

Editor D. Koutsoyiannis; Associate editor S. Grimaldi