南海北部含油气构造上方化探异常研究

在南海北部利用地球化学方法作为油气勘探的一种辅助手段。在6个航次中采集了沉积物、底层海水及海面大气样品，测定了近50种化探指标，并采用稳健统计方法进行了数据处理和异常圈定。化探结果在油气藏上方发现了清晰的、具不同指标组合的综合化探异常，与邻近空构造形成鲜明的对照。圈闭顶部的块状异常和圈闭周绿的环状、半环状异常是下伏油气藏的良好指示，而剖面上呈锯齿状、平面上呈线状的异常则与断裂带有关。实践表明，建立已知油气藏上方的化探异常模式及解剖已知空构造上方的地球化学特征对于指导本区或邻区的化探异常评价是十分必要的。     

Accumulation of organic and inorganic carbon in Pliocene–Pleistocene sediments along the SW African margin

The Ocean Drilling Program Leg 175 recovered a unique series of stratigraphically continuous sedimentary sections along the SW African margin, an area which is presently affected by active coastal upwelling. The accumulation rates of organic and inorganic carbon are a major component of this record. Four Leg 175 sites (1082, 1084, 1085, 1087) are chosen as part of a latitudinal transect from the present northern to southern boundaries of the Benguela Current upwelling system, to decipher the Pliocene–Pleistocene history of biogenic production and its relationship with global and local changes in oceanic circulation and climate. The pattern of CaCO₃ and C_org mass accumulation rates (MARs) over 0.25-Myr intervals indicates that the evolution of carbon burial is highly variable between the northern and the southern Benguela regions, as well as between sites that have similar hydrological conditions. This, as well as the presence over most locations of high-amplitude, rapid changes of carbon burial, reflect the partitioning of biogenic production and patterns of sedimentation into local compartments over the Benguela margin. The combined mapping of CaCO₃ and C_org MARs at the study locations suggests four distinct evolutionary periods, which are essentially linked with major steps in global climate change: the early Pliocene, the mid-Pliocene warm event, a late Pliocene intensification of northern hemisphere glaciation and the Pleistocene. The early Pliocene spatially heterogeneous patterns of carbon burial are thought to reflect the occurrence of mass-gravitational movements over the Benguela slope which resulted in disruption of the recorded biogenic production. This was followed (3.5–3 Ma) by an episode of peak carbonate accumulation over the whole margin and, subsequently, by the onset of Benguela provincialism into a northern and a southern sedimentary regime near 2 Ma. This mid and late Pliocene evolution is interpreted as a direct response to changes in the ventilation of bottom and intermediate waters, as well as to dynamics of the subtropical gyral circulation and associated wind stress.     

White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

地震勘探在不同地质条件下的新应用

20世纪末，地震勘探技术在油气勘探、煤田勘探、工程勘探等多方面的应用都有了突飞猛进的发展。总结了近年来地震勘探在岩性、沉积相、构造体系等不同地质条件下的应用实例，用以说明地震勘探的多用性及其强大的生命力。     

油田水动力系统与油气藏的形成

油田水中存在“沉积承压水”和“地表渗入水”两个相对独立而又相互作用的水动力系统,前者由上覆地层重量所引起的地静压力以及地静压力等引起的异常孔隙流体压力所形成,具有内循环承压式水交替特征,后者为大气降水和地表水向储集层的渗入而形成,以外循环渗入或水交替为特征。这两大系统（尤其是前者）的作用在很大程度上控制了含油气盆地中油气的运移、聚集和保存,油气聚集区主要位于水文地质带中的交管阻滞一停滞带内,沉积交替强度的低值区是油气富集区,沉积水的离心流使凹陷中的油气围绕凹陷中心呈带状分布。     

半封闭海湾潮间带部分围垦后纳潮量计算的商榷——以胶州湾为例

传统的海湾(泻湖)纳潮量计算方法不能精确地反映潮间带被部分围垦后纳潮量的实际情况,本考虑围堤的影响,将纳潮量分解为堤基以下的“梯形”区和堤基以上的“矩形”区两部分之和,在理论上更加严密。根据改进后方法算出的胶州湾近期纳潮量比传统方法算出的纳潮量大15％左右。可见,半个多世纪以来胶州湾的纳潮量只减少了约15％．而不是传统方法得出的约25％。     

我国陆上大中型气田分布规律与有利勘探区带优选

“八五”、“九五”期间我国天然气探明储量幅度增长,大中型气田分布规律的深化研究密切关系到天然气储量的增长势头。克拉通盆地下层序古隆起控气理论和上层序非构造圈闭控气机理是克拉通大中型气田富集分布的基本规律,前陆盆地是我国富气盆地类型之一,其冲断带下盘大型造圈闭群、前缘斜坡岩性尖灭区带与浅层次生气藏、前缘隆起上的断块圈闭群等是该类盆地有利的天然气富集区带。依据充分的地质资料,结合我国天然气勘探实际,提     

山东胜利油田海洋石油勘探开发现状及前景分析

胜利油田海上勘探区 ,位于渤海湾南部的极浅海海域 ,其范围为 :西起四女寺河口 ,经套儿河口、老黄河口、新黄河口、小青河口 ,东到潍河口 ,海岸长 4 1 4km,胜利矿产登记线内面积 4 870 km2 ,水深一般 0～ 5m,最深 1 8m。截止 2 0 0 0年年底 ,已完成二维地震 71 3 6.1 km,三维地震 1 588.58km2 ,完钻探井 1 0 2口 ,测井解释油气层井 87口 ,试油 85口 ,其中 74口获工业油流 ,6口获低产油流。发现了埕岛、埕北 3 0、新滩 3个油田 ,在明化镇组、馆陶组、东营组、沙河街组、中生界、上古生界、下古生界、太古界中发现了 8套含油层系 ,6种类型的油气藏 ,已探明含油面积 1 45.8km2 ,石油地质储量 3 860 9万 t;控制含油面积57.5km2 ,石油地质储量 894 8万 t,其中埕岛油田是渤海域发现最早的亿吨级油田 ,目前已建成 2 1 6万 t年生产能力 ,累积产油 1 0 57万 t。根据两轮资源评价及勘探实践的认识 ,与本区有关的 8个生油凹陷 (岐口、沙南、渤中、埕北、桩东、青东、莱州湾、潍北 )总资源量约 1 2 .0亿 t,目前已找到探明加控制石油地质储量为 4 .75亿 t,仍有较大的勘探开发潜力。今后将对 8个构造带 (埕子口、埕岛、埕北 3 0、长堤、垦东、青东、青坨子、潍北 )进行勘探 ,落实探明储量 ,进一步投入开发 ,为胜利油田     

Nutrients and zooplankton composition and dynamics in relation to the hydrological pattern in a confined Mediterranean salt marsh (NE Iberian Peninsula)

The role of the hydrological regime in the nutrients and zooplankton composition and dynamics has been analysed in five lagoons of La Pletera salt marshes (NE Iberian Peninsula) during a complete hydrological cycle (2002–2003). Two of the lagoons have their origin in the old river mouths while the other three were recently created in the framework of a Life Restoration project. This fact has also allowed us to study the effect of the lagoon age on nutrient and zooplankton composition and dynamics. The salt marsh hydrology is determined by a prolonged period of confinement without water inputs, irregularly interrupted by sudden water inputs due to flooding events (sea storms or intense rainfalls). While the dynamics of oxidized nitrogen compounds in the lagoons depends on the water inputs variability within each hydrological cycle, the internal load of phosphorus, total nitrogen and organic matter is related more to the cumulative mechanisms during the confinement periods. Accumulation processes may be easily related to lagoon age, since old lagoons have higher content of nutrients and organic matter, suggesting that these lagoons progressively accumulate nutrients during the successive confinement events. This is the usual case for most Mediterranean salt marshes without an artificially manipulated water regime. The zooplankton community in La Pletera integrates the effects of both the hydrological regime and the lagoon age since the former determines the temporal pattern of the main zooplankton species and the latter explains differences in composition and structure between old and new lagoons.