Magmatic-dominated fluid evolution in the Jurassic Nambija gold skarn deposits (southeastern Ecuador)

The Jurassic (approximately 145 Ma) Nambija oxidized gold skarns are hosted by the Triassic volcanosedimentary Piuntza unit in the sub-Andean zone of southeastern Ecuador. The skarns consist dominantly of granditic garnet (Ad_20–98) with subordinate pyroxene (Di_46–92Hd_17–42Jo_0–19) and epidote and are spatially associated with porphyritic quartz-diorite to granodiorite intrusions. Endoskarn is developed at the intrusion margins and grades inwards into a potassic alteration zone. Exoskarn has an outer K- and Na-enriched zone in the volcanosedimentary unit. Gold mineralization is associated with the weakly developed retrograde alteration of the exoskarn and occurs mainly in sulfide-poor vugs and milky quartz veins and veinlets in association with hematite. Fluid inclusion data for the main part of the prograde stage indicate the coexistence of high-temperature (500°C to >600°C), high-salinity (up to 65 wt.% eq. NaCl), and moderate- to low-salinity aqueous-carbonic fluids interpreted to have been trapped at pressures around 100–120 MPa, corresponding to about 4-km depth. Lower-temperature (510–300°C) and moderate- to low-salinity (23–2 wt.% eq. NaCl) aqueous fluids are recorded in garnet and epidote of the end of the prograde stage. The microthermometric data (Th from 513°C to 318°C and salinity from 1.0 to 23 wt.% eq. NaCl) and δ¹⁸O values between 6.2‰ and 11.5‰ for gold-bearing milky quartz from the retrograde stage suggest that the ore-forming fluid was dominantly magmatic. Pressures during the early retrograde stage were in the range of 50–100 MPa, in line with the evidence for CO₂ effervescence and probable local boiling. The dominance of magmatic low-saline to moderately saline oxidizing fluids during the retrograde stage is consistent with the depth of the skarn system, which could have delayed the ingression of external fluids until relatively low temperatures were reached. The resulting low water-to-rock ratios explain the weak retrograde alteration and the compositional variability of chlorite, essentially controlled by host rock compositions. Gold was precipitated at this stage as a result of cooling and pH increase related to CO₂ effervescence, which both result in destabilization of gold-bearing chloride complexes. Significant ingression of external fluids took place after gold deposition only, as recorded by δ¹⁸O values of 0.4‰ to 6.2‰ for fluids depositing quartz (below 350°C) in sulfide-rich barren veins. Low-temperature (<300°C) meteoric fluids (δ¹⁸O_water between −10.0‰ and −2.0‰) are responsible for the precipitation of late comb quartz and calcite in cavities and veins and indicate mixing with cooler fluids of higher salinities (about 100°C and 25 wt.% eq. NaCl). The latter are similar to low-temperature fluids (202–74.5°C) with δ¹⁸O values of −0.5‰ to 3.1‰ and salinities in the range of 21.1 to 17.3 wt.% eq. CaCl₂, trapped in calcite of late veins and interpreted as basinal brines. Nambija represents a deep equivalent of the oxidized gold skarn class, the presence of CO₂ in the fluids being partly a consequence of the relatively deep setting at about 4-km depth. As in other Au-bearing skarn deposits, not only the prograde stage but also the gold-precipitating retrograde stage is dominated by fluids of magmatic origin.     

DDT in endangered Galapagos sea lions (Zalophus wollebaeki)

We characterize for the first time the presence of DDT and its metabolites in tropical Galapagos sea lions (Zalophus wolleabeki). ∑DDT concentrations in Galapagos sea lion pups sampled in 2005 and 2008 ranged from 16 to 3070 μg/kg lipid. Concentrations of ∑DDT in pups in 2008 averaged 525 μg/kg lipid and were 1.9 times higher than that (281 μg/kg lipid) detected in pups in 2005. These concentrations are lower than those reported in many pinnipeds elsewhere, comparable to those in Hawaiian monk seals, and higher than those in southern elephant seals. The health risk characterization showed that 1% of the male pups exceeded the p,p′-DDE toxic effect concentration associated with anti-androgenic effects reported in rats. The findings provide preliminary guidance on the relationship between DDT use and ecological impacts, serving as a reference point against which possible future impact of tropical DDT use can be assessed.     

Fossil Chondrichthyes from the central eastern Pacific Ocean and their paleoceanographic significance

The study of the chondrichthyan fauna from the Angostura, Onzole, Canoa and Jama formations, in the Neogene of Bordón and Manabí basins, Ecuador, reveals the presence of 30 taxa, including the deep water shark 2Chlamydoselachus landinii sp. nov. The assemblages are dominated by tropical shallow and deep water chondrichthyans, suggesting paleoenvironments associated with a short platform shelf bordering a deep margin. These assemblages are the most diverse shark and ray association known from the Tropical Central Eastern Pacific Ocean in the South American coastal basin, and provide new information on the paleoecology and paleodiversity of Neogene chondrichthyans.     

Food production and climate protection—What abandoned lands can do to preserve natural forests

Approaches to reconciling food production with climatic and environmental protection often require agricultural intensification. The production of more food per unit of agricultural land through “sustainable intensification” is intended to enable the protection of natural ecosystems elsewhere (land sparing). However, there are problems associated with agricultural intensification; such as soil erosion, eutrophication or pollution of water bodies with chemicals, landscape homogenization and loss of biodiversity; for which solutions have not yet been found. Reuse of abandoned agricultural lands – which are abundant throughout the world – to address the rising demand for food is a potentially important alternative, which up to now has been widely ignored. To test the power of this alternative, equilibrium economic land allocation to various land-use practices by risk-avoiding tropical farmers in Ecuador was simulated. The reestablishment of pastures on abandoned cattle lands lowered prices for pasture products, and also triggered conversion of existing pasture into cropland. The resulting land-use change increased total annual food production in a moderate scenario from the current level of 17.8–23.1 petacalories (10¹⁵ calories), which amounted to a production increase of 30%. At the same time, there was a 19% reduction in the amount of payments to farmers required to preserve tropical forests – one of the world's greatest terrestrial carbon stores.     

Suspended sediment yield and metal contamination in a river catchment affected by El Niño events and gold mining activities: the Puyango river basin,southern Ecuador

The suspended sediment yield and the transfer of polluted sediment are investigated for the Puyango river basin in southern Ecuador. This river system receives metal (Cd, Cu, Hg, Pb and Zn) and cyanide pollution generated by mining, and is associated with large‐scale hydrological variability, which is partly governed by El Niño events. Field sampling and statistical modelling methods are used to quantify the amount of mine tailings that is discharged into the basin. Annual suspended sediment yields are estimated using a novel combination of the suspended sediment rating method and Monte Carlo simulations, which allow for propagation of the uncertainties of the calculations that lead to final load estimates. Geochemical analysis of suspended and river bed sediment is used to assess the dispersion and long‐term fate of contaminated sediment within the river catchment. Knowledge of the inter‐ and intra‐annual variation in suspended sediment yield is shown to be crucial for judging the importance of mining discharges, and the extent to which the resultant pollution is diluted by river flows. In wet years, polluted sediments represent only a very small proportion of the yield estimates, but in dry years the proportion can be significant. Evidence shows that metal contaminated sediments are stored in the Puyango river bed during low flows. Large flood events flush this sediment periodically, both on an annual cycle associated with the rainy season, and also related to El Niño events. Therefore, environmental impacts of mining‐related discharges are more likely to be severe during dry years compared with wet years, and in the dry season rather than the wet season. The hydrological consequences of El Niño events are shown to depend upon the extent to which these events penetrate inland. It is, thus, shown that the general conclusion that El Niño events can significantly affect suspended sediment yields needs evaluation with respect to the particular way in which those events affect a given catchment. Copyright © 2003 John Wiley & Sons, Ltd.     

Forest-Cover Change from Labor- and Capital-Intensive Commercial Logging in the Southern Chocó Rainforests*

Abstract

This article examines two key aspects of land-cover change in the south of the Chocó region. First, it assesses and compares the local impact on forest condition of labor-intensive and capital-intensive commercial logging. Second, it assesses the regional significance and permanency of these changes. Studies of land-cover change associated with commercial logging have focused almost exclusively on capital-intensive extraction and have assumed that after logging, degraded forests are transformed into agricultural cover. This study shows that both capital- and labor-intensive logging result in similar land-cover changes (i.e., forest degradation) if the timber sought is the same. However, labor-intensive loggers also seek timber species not sought by capital-intensive loggers, and this impact is statistically different from the impact of the extraction of the first group of species. Results also show that only a small fraction (20–30 percent) of the area logged is later converted to agricultural cover types. The persistence of logged forests means that up to 20 percent of the remaining forest cover could correspond to forests with significant and lasting levels of degradation. Furthermore, the different production requirements for each group of species also mean that there is a spatial differentiation in the impact of logging in the region. Logged forests are arranged into two consecutive corridors on each side of access routes (e.g., rivers). The first corridor corresponds to a narrow (approximately 1-km) band of high-intensity degradation. The second, broader (approximately 2-km) forest band, with lower levels of degradation, extends inland along first-tier corridors. A key factor determining the permanency of this land-cover pattern is the strong control local communities have over the land in the region. This limits the spread of patterns observed in other frontier areas, especially the conversion of logged forests into agricultural cover.     

Cenozoic continental arc magmatism and associated mineralization in Ecuador

Most of the economic ore deposits of Ecuador are porphyry-Cu and epithermal style gold deposits associated with Tertiary continental arc magmatism. This study presents major and trace element geochemistry, as well as radiogenic isotope (Pb, Sr) signatures, of continental arc magmatic rocks of Ecuador of Eocene to Late Miocene (~50–9 Ma, ELM) and Late Miocene to Recent (~8–0 Ma, LMR) ages. The most primitive ELM and LMR rocks analyzed consistently display similar trace element and isotopic signatures suggesting a common origin, most likely an enriched MORB-type mantle. In contrast, major and trace element geochemistry, as well as radiogenic isotope systematics of the whole sets of ELM and LMR samples, indicate strikingly different evolutions between ELM and LMR rocks. The ELM rocks have consistently low Sr/Y, increasing Rb/Sr, and decreasing Eu/Gd with SiO₂, suggesting an evolution through plagioclase-dominated fractional crystallization at shallow crustal levels (<20 km). The LMR rocks display features of adakite-type magmas (high Sr/Y, low Yb, low Rb/Sr) and increasing Eu/Gd and Gd/Lu ratios with SiO₂. We explain the adakite-type geochemistry of LMR rocks, rather than by slab melting, by a model in which mantle-derived melts partially melt and assimilate residual garnet-bearing mafic lithologies at deeper levels than those of plagioclase stability (i.e., >20 km), and most likely at sub-crustal levels (>40–50 km). The change in geochemical signatures of Tertiary magmatic rocks of Ecuador from the ELM- to the LMR-type coincides chronologically with the transition from a transpressional to a compressional regime that occurred at ~9 Ma and has been attributed by other investigations to the onset of subduction of the aseismic Carnegie ridge.The major districts of porphyry-Cu and epithermal deposits of Ecuador (which have a small size, <<200 Mt, when compared to their Central Andean counterparts) are spatially and temporally associated with ELM magmatic rocks. No significant porphyry-Cu and epithermal deposits (except the epithermal high-sulfidation mineralization of Quimsacocha) appear to be associated with Late Miocene-Recent (LMR, ~8–0 Ma) magmatic rocks. The apparent infertility of LMR magmas seems to be at odds with the association of major porphyry-Cu/epithermal deposits of the Central Andes with magmatic rocks having adakite-type geochemical signatures similar to LMR rocks. The paucity of porphyry-Cu/epithermal deposits associated with LMR rocks might be only apparent and bound to exposure level, or real and bound (among other possibilities) to the lack of development of shallow crustal magmatic chambers since ~9 Ma as a result of a prolonged compressional regime in the Ecuadorian crust. More work is needed to understand the actual metallogenic potential of LMR rocks in Ecuador.Editorial handling: J. Richards     

Geomorphic evidence of active deformation and uplift in a modern continental wedge-top–foredeep transition: Example of the eastern Ecuadorian Andes

The eastern Ecuadorian Andes appear as a fold-and-thrust belt adjacent to a continental foredeep represented by one of the world's largest tropical alluvial megafans, the Pastaza megafan, debouching into the Amazonian lowland. The apex of the Pliocene–Pleistocene megafan situated in the present-day wedge top (Subandean Zone) has been cut by an erosion surface, the western part of which has been uplifted of 500 m along the frontal thrust, forming a poorly dissected plateau, the Mera plateau. This erosion surface erased most of the previous fluvial landscape but preserved a large thrust-related anticlinal hinge deforming less erodible underlying strata, the Mirador fold and smaller-sized anticlines. This surface has been then incised by two antecedent major rivers, the Pastaza and the Napo, and few tributaries. The plateau edge is marked by a series of large scale gently sloping landslides clustered along a 70 km long concave eastward line associated with the frontal thrust fault. The newly formed immature rivers issued from the landslides or sourced within east-dipping remnants of the erosion surface downstream of the landslide line constitute the greatest part of the streams feeding the Ecuadorian Amazonian basin. At 70 to 100 km from the landslide line, the drainage abruptly changes from highly immature to mature with a well-defined hinge line representing the outer limit of landslide and tectonic control. The diversions of the Pastaza River indicate ongoing fold growth since at least the late Pleistocene in the Eastern Cordillera, and the early Holocene in the Mera plateau. The preserved terraces of the Pastaza valley are all degradational and are ascribed to periods of tectonic (seismic) activity alternating with periods of tectonic quiescence or decreased seismic activity rather than to climatic events. ¹⁴C dating of the plateau erosion surface and of the upper Pastaza terraces indicates that the minimum average incision rate since 18,000 years BP varies locally in the upper Pastaza valley from 0.5 to 0.67 cm year⁻¹ , increasing from 18,000 years BP to now. A comparison of these incision rates with fold-and-thrust fault uplift rates indicates that incision in the upper Pastaza valley was a result of rapid uplift (up to 1 cm year⁻¹) along the Mirador fold-and-thrust which caused a restoration of the local equilibrium profile of the upper reach, combined with smaller local fault uplift along the westernmost thrust faults. The uplift of the whole Mera plateau with respect to the upper Amazonian basin gives a minimum average uplift rate of 2.8 cm year⁻¹ since 18,000 years BP. The overall uplift of the Mera plateau and the Eastern Cordillera is likely to have been caused by a regional-scale low angle thrust ramp emerging as the frontal thrust fault.