高温高压下电解质溶液热力学性质的研究进展

高温高压下电解质溶液热力学性质的研究不仅对探讨地球内部流体的作用具有重要意义，而且在很多实际工业过程中也都有广泛应用。本综述了近10年来高温高压下电解质溶液热力学参数的实验测量和理论计算的进展，实验设备还有待进一步的改进和完善，以获得更高温度和压力下的数据，理论计算不仅有待于实验的发展，也与溶液的结构理论密切相关。     

中国科学院固体地球科学知识创新工程现状与发展态势

回顾了中国科学院国家知识创新试点工程实施以来特别是启动阶段3年里固体地球科学知识创新工程试点各项工作的进展情况，包括项目与经费、创新成果、人才吸引、科研竞争力提升、院地合作推进等方面，分析和总结了中国科学院固体地球科学知识创新工程现状，并展望了固体地球科学知识创新工程若干重要发展态势。     

Evaluation of the Reduction in Uncertainty Obtained by Conditioning a 3D Stochastic Channel to Multiwell Pressure Data

A stochastic channel embedded in a background facies is conditioned to data observed at wells. The background facies is a fixed rectangular box. The model parameters consist of geometric parameters that describe the shape, size, and location of the channel, and permeability and porosity in the channel and nonchannel facies. We extend methodology previously developed to condition a stochastic channel to well-test pressure data, and well observations of the channel thickness and the depth of the top of the channel. The main objective of this work is to characterize the reduction in uncertainty in channel model parameters and predicted reservoir performance that can be achieved by conditioning to well-test pressure data at one or more wells. Multiple conditional realizations of the geometric parameters and rock properties are generated to evaluate the uncertainty in model parameters. The ensemble of predictions of reservoir performance generated from the suite of realizations provides a Monte Carlo estimate of the uncertainty in future performance predictions. In addition, we provide some insight on how prior variances, data measurement errors, and sensitivity coefficients interact to determine the reduction in model parameters obtained by conditioning to pressure data and examine the value of active and observation well data in resolving model parameters.     

Spectroscopic evidence for pressure-induced phase transitions in diopside

 Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined. Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and 875 cm⁻¹ disappeared, while the mode at 324 cm⁻¹ split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15 GPa, a small (1 to 2 cm⁻¹) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes; and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place. Received: 14 November 2000 / Accepted: 9 January 2002     

淤积泥砂对水平地运动作用时刚性坝面动压力的影响

文章基于固体介质，流体介质，液固两相饱和介质的时域显示有限元波动分析方法，研究了可压缩库水条件下淤积泥砂对水平地运动作用时刚性坝面上动压力的影响，研究中分析了作为两相介质处理的淤积泥砂的饱和度、厚度、渗透系数和孔隙率对坝面动压力的影响，还比较了作为流程两相介质，单相固体介质、单相重流体介质处理的不同淤积泥砂层模型间的计算结果差异。     

The newest observational evidence on asymmetrical deformation of the Earth

IntroductionWhat is the shape of the Earth? Does it change continuously? It is a scientific question since the ancient times and is still being observed and explored at present. In 250 BC, Greek scholar Eratosthene supposed the shape of the Earth to be spherical according to the observations to the Sun and estimated the perimeter of the Earth to be 4 000 km (King-Hele, 1976) according to the camel-walking distance. Until the 16th century, the Earth was considered to be a very symmetrical …     

Cretaceous length of day perturbation by mantle avalanche

These last 10 years, numerical models of mantle convection have emphasized the role of the 670 km endothermic phase change in generating avalanches that trigger catastrophic mass transfers between upper and lower mantle. On the other hand, scientists have emphasized the concomitance of large-scale worldwide geophysical and tectonic events, which could find their deep thermal roots in the huge mass transfers induced by the avalanches. In particular, the paleontological records show two periods of length of day (l.o.d.) shortening between 420 and 360, and 200 and 80 Myr BP. This last event is synchronous with a strong true polar wander and a global warming of the upper mantle. In order to study the potential effects of the avalanche on the main component of the Earth’s rotation, the Liouville equation has been solved and the l.o.d. evolution has been calculated from the perturbations of the inertia tensor. The results show that the inertia tensor of the Earth’s is mainly sensitive to the global transfers through the 670 km discontinuity. The l.o.d. perturbations will be synchronous with the global thermal effects of the avalanche. These theoretical results allow proposing a self-consistent physical mechanism to explain periods of the Earth’s rotation acceleration. Within this context, the l.o.d. shortening during the Cenozoic and Cretaceous brings one more clue to the possible participation of a mantle avalanche in generating the concomitant large scale events which have occurred during this very particular period of the Earth’s history.     

Spatial and temporal variability of pore‐water pressures in residual soil slopes in a tropical climate

It is critical to understand and quantify the temporal and spatial variability in hillslope hydrological data in order to advance hillslope hydrological studies, evaluate distributed parameter hydrological models, analyse variability in hydrological response of slopes and design efficient field data sampling networks. The spatial and temporal variability of field‐measured pore‐water pressures in three residual soil slopes in Singapore was investigated using geostatistical methods. Parameters of the semivariograms, namely the range, sill and nugget effect, revealed interesting insights into the spatial structure of the temporal situation of pore‐water pressures in the slopes. While informative, mean estimates have been shown to be inadequate for modelling purposes, indicator semivariograms together with mean prediction by kriging provide a better form of model input. Results also indicate that significant temporal and spatial variability in pore‐water pressures exists in the slope profile and thereby induces variability in hydrological response of the slope. Spatial and temporal variability in pore‐water pressure decreases with increasing soil depth. The variability decreases during wet conditions as the slope approaches near saturation and the variability increases with high matric suction development following rainfall periods. Variability in pore‐water pressures is greatest at shallow depths and near the slope crest and is strongly influenced by the combined action of microclimate, vegetation and soil properties. Copyright © 2002 John Wiley & Sons, Ltd.     

华北地区部分井孔稀有气体异常研究

介绍了近年来华北地区宝龙等 3口井稀有气体的显著异常 ,并据其特征与井孔水位动态的关系 ,对稀有气体异常的成因进行了理论分析与实验研究。结果表明 ,水位下降 10 0mm ,岩层孔隙、裂隙中的气体体积膨胀 0 0 0 90 % (气体体积百分比 ,下同 )左右。由于地下水位大幅度下降 ,岩层孔隙压力减小 ,积聚在岩层孔隙、裂隙中的气体体积膨胀溢出 ,导致井孔地下水中稀有气体含量出现异常变化。这些异常是干扰因素所致 ,不是地震异