考虑滑脱效应和温度场的煤层气渗流数值模拟

由于煤层气的解吸热效应,煤层气的运移过程是一个非等温过程。因此,温度场对煤层气渗流有着重要的影响。前人在研究煤层气渗流规律的研究中并没有同时考虑滑脱效应和温度场因素的影响,而在实际的深部开采中综合考虑滑脱效应和温度场的影响对研究深部煤层气运移规律有着重要的意义。因此本文建立了考虑滑脱效应及温度场的煤层气渗流数学模型,利用有限元数值方法研究了考虑滑脱效应和温度场耦合的煤层气运移规律;研究了考虑滑脱效应和温度场对压力场分布的影响;对考虑滑脱效应及温度场因素的煤层气产量进行了预测。得出了随着温度的升高煤储层的压力在降低,温度的升高对煤层气的产量有着负面的影响这一重要结论。     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Paleoproterozoic accretion in the Northeast Siberian craton: Isotopic dating of the Anabar collision system

Geochronological database considered in the work and characterizing the Anabar collision system in the Northeast Siberian craton includes coordinated results of Sm-Nd and Rb-Sr dating of samples from crustal xenoliths in kimberlites, deep drill holes, and bedrock outcrops. As is inferred, collision developed in three stages dated at 2200–2100, 1940–1760, and 1710–1630 Ma. The age of 2000–1960 Ma is established for substratum of mafic rocks, which probably originated during the lower crust interaction with asthenosphere due to the local collapse of the collision prism. Comparison of Sm-Nd and Rb-Sr isochron dates shows that the system cooling from ≈700 to ≈300°C lasted approximately 300 m.y. with a substantial lag relative to collision metamorphism and granite formation. It is assumed that accretion of the Siberian craton resulted in formation of a giant collision mountainous structure of the Himalayan type that was eroded by 1.65 Ga ago, when accumulation of gently dipping Meso-to Neoproterozoic (Riphean) platform cover commenced.     

Multi-reference evaluation of uncertainty in earth orientation parameter measurements

Uncertainties in polar motion and length-of-day measurements are evaluated empirically using several data series from the space-geodetic techniques of the global positioning system (GPS), satellite laser ranging (SLR), and very long baseline interferometry (VLBI) during 1997–2002. In the evaluation procedure employed here, known as the three-corner hat (TCH) technique, the signal common to each series is eliminated by forming pair-wise differences between the series, thus requiring no assumed values for the “truth” signal. From the variances of the differenced series, the uncertainty of each series can be recovered when reasonable assumptions are made about the correlations between the series. In order to form the pair-wise differences, the series data must be given at the same epoch. All measurement data sets studied here were sampled at noon (UTC); except for the VLBI series, whose data are interpolated to noon and whose UT1 values are also numerically differentiated to obtain LOD. The numerical error introduced to the VLBI values by the interpolation and differentiation is shown to be comparable in magnitude to the values determined by the TCH method for the uncertainties of the VLBI series. The TCH estimates for the VLBI series are corrupted by such numerical errors mostly as a result of the relatively large data intervals. Of the remaining data sets studied here, it is found that the IGS Final combined series has the smallest polar motion and length-of-day uncertainties.     

2003年 8月 21-22日辐合气流暴雨天气过程总结

本文综合应用天气图、静止卫星云图、物理量诊断场,分析了 2003年 8月 21～ 22日黑龙江省大范围强降水过程.分析了乌拉尔山阻高、副热带高压和冷暖空气在暴雨天气过程中的作用.得出有预报指示意义的特征.并对日本传真图的降水预报能力进行了检验分析.在暴雨预报中也具有一定的预报意义.     

新疆冰雹天气过程的基本特征

通过对新疆39a冰雹天气资料的普查，得到76次系统性冰雹天气过程和1279次局地冰雹天气过程，局地冰雹天气的发生远远多于系统性雹天气。冰雹天气过程与地形密切相关，主要发生在山区，冰雹天气以1天为主，多发生于夏季，系统性冰雹天气均由中尺度高压造成。     

多年冻土地区L型挡土墙土压力(冻胀力)的分析与试验

为适应多年冻土区土体冻胀过程所产生的较大变形的特性, 缩短施工进程, 减少扰动时间, 在青藏铁路格拉段选择了一个试验工点进行了L型悬臂挡墙的初步验证性试验研究. 通过对L型挡墙的受力模式分析, 确定了对粗颗粒填料不考虑冻胀力的土压力设计控制值. 通过与现场实测土压力分布规律的对比, 探讨了土压力与冻胀力的关系.     

变化中的地球所面临的挑战:全球变化的科学理解(英文)

简要介绍了变化中的地球所面临的挑战 ,并在描述地球系统科学近年来所取得成就的基础上给出了全球变化的科学理解。同时也简要介绍了世界正在面临的主要环境问题 ;描述了气候系统研究所达成的共识、面临的挑战及所取得的研究进展 ;并从大气、海洋和陆地间的CO2 交换、转换、不确定性等方面阐述了碳循环 ;然后 ,简单描述了全球水循环研究进展 ;最后 ,展望了在变化的地球中生存所要面临的挑战与机遇。     

浅议学科交叉与地球系统科学

以整体系统的观念认识地球 ,强化学科间的交叉与渗透 ,是 2 1世纪初地球科学发展的主题。各国都十分重视推动学科交叉研究 ,并将学科交叉分为Modidisciplinary、Interdisciplinary、Transdiscipli nary三个层次。地球系统科学的两大前沿为“地球系统的联系”和“地球系统的演化” ,2 1世纪地球科学的突破在于地球系统变化理论的形成。笔者指出 :目前 ,我们的观念还跟不上地球科学的发展 ,尤其是“学科交叉”的理念不强 ,缺乏地球系统科学的思维 ,但我们有开展地球系统科学研究的有利条件     

H2O-CH4-H2-CO2-CO-O2在高温、高压和高密度条件下的状态方程

为了计算高温，高压和高密度流体的热力学性质，提出了一个具有19个参数的维里型状态方程，其中参数与温度间的函数关系采用由Sutherland位能函数导出的维里系数近似式。除临界点附近以外，在已报道的pVT数据所覆盖的大部分超临界区域内，该方程均可适用。用该方程对H2O，CH4，H2，CO2，CO和O2等流体pVT关系的计算结果令人满意，其中pVT上限分别为：91-610GPa,1.6-11.0cm^3/mol,4000-5000K。计算体积的平均偏 小于0．8％，最大偏差小于5．4％。