珠江口盆地番禺4洼文昌组基于层序地层格架约束下的优质烃源岩预测

珠江口盆地番禺4洼“小而肥”,目前的探明石油地质储量已超出早期估算的地质资源量,早期对烃源岩的认识不足可能是其主要原因,尤其是对优质烃源岩的分布范围仍缺少精确刻画,在很大程度上限制了对该洼陷勘探潜力的认知。以该难点问题为切入点,利用最新钻井和地震资料,采取层序地层学开展了番禺4洼烃源岩的预测工作。通过地震资料上识别的各种反射特征,结合区内已有钻井资料识别的旋回特征,将番禺4洼文昌组划分5个三级层序,进而建立了等时地层格架。在此基础上,综合运用地震沉积学最新技术手段,精细揭示了番禺4洼文昌组文三段优质烃源岩的分布范围。研究结果表明,番禺4洼优质烃源岩分布面积较为广泛,尤其在北次洼和西次洼,优质源岩面积均超过了以往预期。这一研究成果对本区和珠江口盆地油气勘探具有一定指导意义。     

几种常用消毒剂对杂色鲍幼鲍的急性毒性试验

在常温静水的条件下,分别用高锰酸钾、菌毒净、聚维酮碘对杂色鲍(Haliotis diversi-color Reeve)幼鲍进行急性毒性试验。试验结果表明,毒性大小依次为高锰酸钾>菌毒净>聚维酮碘。高锰酸钾对幼鲍24,48 h的LC50分别为17.1,5.18 mg/L。菌毒净对幼鲍24,48h的LC50分别为105,46.5 mg/L。聚维酮碘对幼鲍24,48 h的LC50分别为530,218 mg/L。菌毒净、聚维酮碘是较为理想的消毒药物。     

氨氮胁迫对中华绒螯蟹(Eriocheir sinensis) 免疫功能的影响

在实验室条件下构建不同氨氮浓度环境和养殖时间的组间差异,研究氨氮胁迫对中华绒螯蟹免疫功能的影响。结果表明,中华绒螯蟹在NH 4-N3.0mg/L10天或1.0mg/L20天时,其血淋巴血细胞密度极显著地低于对照组(P<0.01)。NH4 -N2.0mg/L和3.0mg/L无论10天或20天,血细胞吞噬百分率均分别为显著(P<0.05)和极显著(P<0.01)地低于对照组。NH4 -N3.0mg/L10天或2.0mg/L20天,血细胞吞噬指数显著低于对照组(P<0.05)。NH4 -N1.0mg/L和2.0mg/L分别20天时,血清溶菌酶(LSZ)活力分别为显著(P<0.05)和极显著(P<0.01)地低于对照组。NH4 -N1.0—5.0mg/L10天时,血清酚氧化酶(PO)活力均极显著(P<0.01)下降;但NH4 -N1.0—4.0mg/L20天时,血清PO活力水平均比10天时有所上升。NH4 -N3.0—4.0mg/L10天或1.0—2.0mg/L20天,以及5.0mg/L10天或3.0—5.0mg/L20天时,超氧化物歧化酶(SOD)活力分别为显著(P<0.05)和极显著(P<0.01)地低于对照组。上述结果表明,随着氨氮胁迫浓度的增加和胁迫时间的延长,会引起中华绒螯蟹血细胞数量、血细胞吞噬能力、溶菌酶活力、酚氧化酶活力和超氧化物歧化酶活力等的逐渐下降,使机体非特异性免疫防御系统遭到损伤,同时机体清除自由基的能力下降,机体细胞和组织受到伤害甚至出现死亡。     

象山港潮波响应和变形研究 Ⅱ.象山港潮波数值研究

通过象山港水域的潮波运动数值模拟,分析了象山港M4分潮的生成和增长机制．结果说明,潮波传播中的非线性底摩擦效应是M4分潮生成和增长的主要控制因子,M4分潮在湾内的共振现象也起着重要的放大作用二平流效应在绝大部分区域中抑制了M4分潮的发展,只有在佛渡水道中一些岛屿周围极小区域内对M4分潮有增强作用．潮滩在湾内对M4分潮的影响极其微弱．     

水声学方法对黄河口水下底坡失稳现象研究

对黄河三角洲东北部地区的高分辨率水声学资料进行了综合研究。根据所记录的破坏土体变形程度、运动产生的平面形状和地貌特征形态,对土体失稳过程进行分类：浅表土体变形、塌陷凹坑、滑坡和沉积物重力流。结果表明：（１）浅表土体形变的变形程度最低,出现在研究区斜坡上部平滑海底,主要为绳网状泄水构造和表层拉张裂隙。（２）塌陷凹坑在研究区内广泛出现,是局部土体液化后发生了垂直沉降的结果。（３）滑坡多发生在水下斜坡的中上部,由弧形塌陷区、狭窄的冲沟通道和负地形沉积物堆积区组成。滑坡陡坎后缘发现拉张裂隙。（４）沉积物重力流是土体发生变形程度最大,搬运距离最长的土体破坏变形形式。局部区域多次受到沉积物重力流切割和充填作用。     

Factors controlling dissolved silica in coral reef surface water of Urasoko Bay, Ishigaki Island, Japan

From August 2006 to August 2007, the concentrations of dissolved silica (Si(OH)₄) were monitored in the surface water of Urasoko Bay and the mouth of the stream that runs into the bay. Urasoko Bay is located on the northern coast of Ishigaki Island, Okinawa, Japan, which is in a subtropical area of the North Pacific Ocean and is surrounded by a relatively poorly developed fringing reef. Added to these samples were freshwater from the upstream area and brackish water that exudes at the beach site, which were collected from April to June 2007. Rainwater samples were also collected during the study period. The concentration of Si(OH)₄ generally decreased from upstream to the bay site, and, on clear days, Si(OH)₄ data from all study sites (the bay, beach, stream mouth, and upstream) plotted against salinity fell on a single straight line. When the influence of rainwater was, the results were scattered below the straight line, which suggests dilution by rainwater with a much lower Si(OH)₄ concentration. These findings show that offshore seawater, rainwater, and upstream freshwater regulate the concentration of Si(OH)₄ in the surface water of Urasoko Bay.     

Spatiotemporal aspects of silica buffering in restored tidal marshes

Losses of pelagic diatom production resulting from silica limitation have not only been blamed for toxic algal blooms, but for the reduction in ability of coastal food webs to support higher trophic levels. Recent research has shown the importance of advective seepage water fluxes of dissolved silica (DSi) from freshwater marshes to pelagic waters during moments of riverine Si-limitation. In this study, we investigated the potential impact of recently installed new tidal areas along the Schelde estuary, located in former polder areas and characterized by so-called controlled reduced tidal regimes (CRT). Nine mass-balance studies were conducted in a newly constructed CRT in the freshwater Schelde estuary. During complete tidal cycles both DSi and amorphous silica (ASi) concentrations were monitored at the entrance culverts and in different habitats in the marsh. A swift DSi-delivery capacity was observed despite the shifted spatiotemporal frame of exchange processes compared to reference marshes. As silica-accumulating vegetation is not yet present, and difference with reference marshes’ deliveries is surprisingly small, we indicate diatomaceous debris and phytoliths to be the main silica source. Although further research is necessary on the driving forces of the different processes involved, restoration of former agricultural areas under CRT-regime provide the potential to buffer silica in the estuary.     

南海北部C4站柱状沉积中的孢粉组合及其古环境意义

对南海北部C4站柱状沉积剖面进行了高分辨率孢粉、藻类成分的分析和研究,同时测定了部分样品的AMS14C年代,划分了该站柱状沉积物地层时代,相应恢复了南海北部9 800 a B P以来植被、气候、环境的3个演替阶段.南海北部C4站从下至上可划分成3个孢粉组合带,依次为:1带(258～194 cm):以Pinus-Quercus(常绿)-Polypodiaceae-Pterdium-Pteris-Dicranopteris-Adiantum为主孢粉带;2带(194～94 cm):以Pinus-Quercus(常绿)-Pteridium-Polypodiaceae-Microlepia-Dicranopteris为主孢粉带;3带(94～4 cm):以Pinus-Pteridium-Polypodiaceae-Quercus(常绿)-Microlepia-Dicranopteris为主孢粉带.与3个孢粉带相对应的古植被阶段依次为:伴有针叶树的常绿阔叶、落叶阔叶混交林,热带半常绿季雨林,热带常绿阔叶、落叶阔叶混交林,与周边地区的植被演替相一致.由此可见,研究区经历了全新世早期气候转暖,中期气候炎热、干湿季明显、海平面上升以及晚期气候暖热、湿润3个古环境演变阶段.     

珠江口表层水中主要常量离子的研究

９９４年９月采集了珠江口表层海水水样,并对其溶解态的Ｋ＋、Ｎａ＋、Ｃａ２＋、Ｍｇ２＋、ＳＯ２－４、Ｃｌ等化学要素进行了测定。结果表明,珠江口调查海域表层水中溶解态的Ｋ＋、Ｎａ＋、Ｃａ２＋、Ｍｇ２＋、ＳＯ２－４主要受陆源淡水与外海水物理混合稀释的影响,与Ｃｌ具有良好的直线正相关;Ｃａ２＋／Ｃｌ、ＳＯ２－４／Ｃｌ明显高于大洋水相应比值,Ｎａ＋／Ｃｌ、Ｍｇ２＋／Ｃｌ略高,而Ｋ＋／Ｃｌ比大洋比值低;在与中国其它各主要河口表层水对应Ｃｌ比较中,珠江口的ＳＯ２－４／Ｃｌ较高,而Ｃａ２＋／Ｃｌ,Ｍｇ２＋／Ｃｌ比值居低;上述各主要常量离子和Ｃｌ的等值线均沿自北向南走向递增。     

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。