Chemical and spectroscopic characterization of dissolved humic substances in a mangrove-fringed estuary in the eastern coast of Hainan Island, China

Mangrove-derived dissolved organic matter(DOM) has an important effect on estuarine and coastal area on a large scale.In order to improve the understanding of origin,composition,and fate of DOM in mangrove-fringed estuarine and coastal areas,dissolved humic substances(DHS) were isolated from one mangrove pore-water sample and one near-shore seawater sample downstream the mangrove pore-water site in the eastern coast of Hainan Island,South China.Fulvic acids,humic acids and XAD-4 fractions were obtained from the two water samples by using a two-column array of XAD-8 and XAD-4 resins.Chemical and spectroscopic methods were used to analyze the features of these DHS.Compared to the mangrove pore-water DHS,the near-shore seawater DHS were found rich in 13 C with lower C/N ratios and more aliphatic compounds and carbohydrates,but less aromatic structures and carboxyl groups.As for the three fractions of the two DHS,XAD-4 fractions contain more aliphatics,carbohydrates,carboxyl groups,and enrich in 13 C with respect to both fulvic and humic acids.Photo-oxidation transformation and contribution from marine-derived DOM were considered as the main reasons resulted in the difference in compositional features for these DHS in this study.     

Effects of exposure to four endocrine disrupting-chemicals on fertilization and embryonic development of Barbel chub (Squaliobarbus curriculus)

The toxicities of 4 common endocrine-disrupting chemicals (EDCs), 17β-estradiol (E2), p,p′-dichlorodiphenyldichloro-ethylene (DDE), 4-nonylphenol (NP) and tributyltin (TBT), to sperm motility, fertilization rate, hatching rate and embryonic development of Barbel chub (Squaliobarbus curriculus) were investigated in this study. The duration of sperm motility was significantly shortened by exposure to the EDCs at the threshold concentrations of 10 ng L^?1 for E2 and TBT, 1 μg L^?1 for NP and 100 μg L^?1 for DDE, respectively. The fertilization rate was substantially reduced by the EDCs at the lowest observable effect concentrations (LOECs) of 10 ng L^?1 for E2 and TBT and 10 μg L^?1 for DDE and NP, respectively. Of the tested properties of S. curriculus, larval deformity rate was most sensitive to EDC exposure and was significantly increased by DDE at the lowest experimental level of 0.1 μg L^?1. Other EDCs increased the larval deformity rate at the LOECs of 1 ng L^?1 for E2, 10 ng L^?1 for TBT and 1 μg L^?1 for NP, respectively. Despite their decreases with the increasing EDC concentrations, the hatching rate and larval survival rate of S. curriculus were not significantly affected by the exposure to EDCs. The results indicated that all the 4 EDCs affected significantly and negatively the early life stages of the freshwater fish S. curriculus. Overall, E2 and TBT were more toxic than NP and DDE, while DDE might be more toxic to larval deformity rate than to other measured parameters. Thus, the 4 EDCs showed potential negative influences on natural population dynamics of S. curriculus. Our findings provided valuable basic data for the ecological risk assessment of E2, DDE, NP and TBT.     

基于SaaS的区域非职业体育赛事云服务平台的设计与实现

与传统软件架构模式相比,云计算具有综合成本较低、部署快速、规模调整灵活等优势,针对区域非职业体育赛事在信息采集、组织管理、赛果处理与发布等赛事运营、组织、管理等方面存在的不足,从平台构建的可行性、架构与功能等方面,讨论并实现了一种基于SaaS模式的非职业体育赛事云服务平台,最后从使用效益等方面总结该平台对于提升区域非职业体育赛事组织与管理所取得的促进作用。     

新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

基于高斯曲线拟合-FFT方法的南海风场反演

海面风场是海洋学的基本参量,获取海面风场对了解海洋的物理过程以及海洋与大气之间的相互作用至关重要。宽阔的海域面积及复杂的海面状况通常使南海海面上的风场信息很难被及时获取。ENVISAT ASAR是一种全天候全天时监测海面的微波雷达传感器,可实时获取海面风场数据。本文基于已有ASAR数据对南海海面风场进行反演实验,首先将结合高斯曲线拟合的FFT风向反演方法应用于南海风向反演,并参考Cross-Calibrated Multi-Platform （CCMP）风场数据去除180o方向模糊获得海面风向。然后,将高斯曲线拟合-FFT风向与传统的峰值-FFT风向进行对比,最后将准确率较高的高斯曲线拟合-FFT风向分别输入CMOD4模型和CMOD5模型获得海面风速大小。实验结果与CCMP参考数据的比较结果表明,在风条纹不明显的情况下,利用结合高斯曲线的FFT风向反演方法和CMOD4模型风速反演方法可有效地进行南海海面风场反演。该成果对利用SAR数据实时获取南海大面积海面风场信息,尤其是观测点缺乏海域的风场信息,具有重要的指导意义。     

过程定义语言XPDL,BPML和BPEL4WS的比较分析

BPML和XPDL及BPEL4WS都是基于XML的过程定义语言，提供了一个正式模型来表达企业商务过程中的可执行过程。从语言的功能、结构、实现细节等方面对XPDL、BPML和BPEL4WS进行了分析和比较，说明了3种语言各自的特点和适用范围。     

合作原则对大学英语四六级听力测试对话的指导

听力理解在英语四六级考试中占有重要的比例,提高听力水平既是教学的要求也是通过大学英语四六级考试的关键。因此在分析近年来大学英语四六级听力理解对话部分的难点的基础上,提出合作原则及相关理论对解答听力理解对话部分具有指导作用。     

机载激光点云与影像联合测图的技术进展和趋势

本文通过对激光点云与光学影像联合测图所涵盖的关键技术进展进行分析,重点指出目前激光扫描仪进行测绘生产所面临的主要挑战。结合激光扫描技术与光学影像融合后的数据特点与实际行业生产需求,简要探讨了未来激光测图技术发展的趋势及新产品体系构建设想,以期对激光扫描软硬件系统在相关行业应用推广中具有一定参考意义。     

三峡重庆地区钻孔应变资料可靠性检验与分析

对三峡重庆地区6个四分量钻孔应变资料进行可靠性分析,利用其增量观测数据进行相对标定,得到各站点测区的应变参数,并分析测区相对应变特征。结果表明,6个站点的钻孔应变观测资料是可靠的,其中1个站点测区面应变呈现张性变化,靠近三峡库首区的5个站点测区面应变呈现压性变化,测点主压应变方向与大范围构造应力场方向较为一致,表明三峡重庆地区呈现压性特征。     

"4D"数据在生态环境监测与评价中的应用

本文在阐述由DLG、DRG、DEM和DOM组成的4D产品的信息特征的基础上,深入分析了"4D"数据在生态环境监测与评价中的功能,包括生态环境的快速动态监测、三维生态景观的直观分析和表达、DLM与DCM相结合的生态模拟、多时空尺度的生态环境分析与评价等.并以云南省生态环境监测与评价为例,研究了其在生态环境监测与评价中的技术流程,并通过案例分析,生成了系列生态环境地图.