Heat capacity of γ-Fe2SiO4 between 5 and 303 K and derived thermodynamic properties

A multi-anvil device was used to synthesize 24 mg of pure γ-Fe₂SiO₄ crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C _p) of γ-Fe₂SiO₄ was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured heat capacity data show a broad λ-transition at 11.8 K. The difference in the C _p between fayalite and γ-Fe₂SiO₄ is reduced as the temperature increases in the range of 50–300 K. The gap in C _p data between 300 and 350 K of γ-Fe₂SiO₄ is an impediment to calculation of a precise C _p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C _p and entropy of γ-Fe₂SiO₄ at standard temperature and pressure (S°₂₉₈) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol⁻¹ K⁻¹, respectively. The Gibbs free energy at standard pressure and temperature (ΔG° _f,298) is calculated to be −1,369.3 ± 2.7 J mol⁻¹ based on the new entropy data. The phase boundary for the fayalite–γ-Fe₂SiO₄ transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent with extrapolated results of previous experimental studies.     

闽江河口湿地资源动态变化的分形研究

本研究以分形理论为基础,并借助GIS、RS技术,利用1986年和2002年两期TM遥感影像,提取获得了1986年和2002年闽江河口湿地资源的空间信息,根据分形理论中分形维数和稳定性指数的物理意义,揭示了闽江河口湿地资源动态变化情况。研究表明:闽江河口的湿地类型具有分形结构.并且由于受到较强的人类活动的干预,湿地斑块的形状较为复杂,且稳定性较差。     

1989-2003年厦门市湿地动态变化分析

通过对厦门市1989年、1993年、1997年TM遥感影像和2003年ETM+遥感影像的解译分析统计,用单一土地利用动态度、转移矩阵等对1989-2003年厦门市湿地动态变化进行了分析,并进行了主要驱动力分析。结果表明:1989-2003年间,由于经济发展、人口增长以及农业生产比较利益的驱动和农业内部结构调整的影响,水库水塘、养殖、滩涂等湿地类型被非湿地侵占;养殖面积从1989年的4230hm2持续增加到2003年的9768hm2,主要是通过占用非湿地、滩涂、盐田和水库水塘增加的;红树林面积大幅度减少,从1989年的84hm2持续减少到2003年的17hm2,主要是由于养殖、非湿地的侵占以及遭受破坏变为滩涂。     

国内氢氧化镁阻燃剂的研究现状

综述了国内氢氧化镁阻燃剂的合成、表面改性及其应用,主要论述了近20年来国内在氢氧化镁阻燃剂研发方面取得的成果及发展方向,简单概述氢氧化镁阻燃剂的发展前景。     

Spheroidal oscillations of the Earth stimulated by the Sumatra-Andaman earthquake with CDSN data

The 0S2~0S54 spheroidal modes of Earth’s free oscillations, triggered by the great Sumatra-Andaman earthquake of 26 December 2004 are retrieved from VHZ data recorded by seven upgraded stations of China Digital Seismograph Network (CDSN). We compare these spheroidal modes with theoretical free oscillation spectra calculated from the Preliminary Reference Earth Model (PREM) and find a coincidence between their periods. Spectral splitting phenomenon is observed obviously in 0S2, 0S3, 0S4, 2S1 and 1S2 free oscillation modes. What is most noticeable is that the oscillation mode 2S1 is reported for the second time (the first time by Rosat et al) without any data stacking. We simulated the split singlet of 0S2 mode on seven CDSN stations based on general focal mechanism and seismic moment of the earthquake. The result shows that seismic moment of the earthquake can reach 1023 N.m. We also find that the recording of Earth’s free oscillations carries abundant information of source mechanism and earthquake location, which is applicable to the detailed study of source rupture parameters.     

Nonlinear seismic response analysis of arch dam-foundation systems- part II opening and closing contact joints

A time-domain method for the analysis of arch dam-foundation rock dynamic interaction during earthquake was proposed, and the dynamic relaxation technique was adopted to obtain the initial static response for dynamic analysis by [Du et al. (2005). The paper has been contributed to Bulletin of earthquake engineering]. In this paper, a nonlinear explicit method in time domain considering the opening and closing effect of contact joints on arch dam during earthquake is further proposed by introducing the dynamic contact force model into the method. The simulation accuracy of dynamic contact force model is verified by comparing its calculation result and test result of scale model on shaking table. Finally, the influence of joints on the seismic response of Xiaowan arch dam is studied by the proposed method and some conclusions are given.     

An Estimate of Global Mean Sea-level Rise Inferred from Tide-gauge Measurements Using Glacial-isostatic Models Consistent with the Relative Sea-level Record

This study is concerned with the influence of the glacial-isostatic adjustment caused by the last Pleistocene deglaciation on the present-day sea level. The viscoelastic deformation caused by the time-variable ice and ocean loads is simulated by computing the resulting perturbations for a spherical, self-gravitating, incompressible, Maxwell-viscoelastic earth model. The associated variation of the earth rotation is described in terms of the Liouville equation, which is solved by means of the MacCullagh formulae. This allows the determination of the vertical displacement and geoid height and, thus, the solution of the sea-level equation. We test several viscosity and ice models and evaluate them by comparison of the computed response with the Holocene relative sea-level record. Using the optimum combination of viscosity and ice models, we then estimate the influence of the last Pleistocene deglaciation on the tide-gauge measurements. A comparison between the observational and residual linear trends for the tide-gauge measurements shows a significant reduction of the variance and geographical variability for the latter, in particular for the formerly ice-covered regions of North America and Scandinavia. The favoured value determined for the global mean sea-level rise is (1.46±0.2) mm a⁻¹.     

带权约束参数平差在工程控制网优化中的应用

介绍用带权约束平差原理编制的工程控制网试验修正法设计和平差程序,并用于设计工程导线和平差变形观测控制网等实际工程的例子,据此提供一些结论和建议.     

GIS中地籍宗地面积的方差分量估计

探讨在地籍宗地数字化的面积处理问题中,把已知面积数据和数字化坐标同时作为观测值的面积处理方法.采用方差分量估计,解决已知面积数据参与平差时的权的确定.通过实例分析,认为采用条件平差方差分量估计方法来对宗地面积处理,能够更加合理地调整已有面积与由数字化坐标得到的面积值之间的差异.