库车坳陷下侏罗统岩石古应力场与砂岩储层性质

对库车坳陷下侏罗统野外定向岩石样品的岩石力学性质的测试结果表明,下侏罗统以压扁变形明显、拉伸变形较弱为特点。自侏罗纪以来,该区经历了至少4期古构造变形作用,其变形方式主要为近EW向的以脆性变形为主的褶皱变形作用。在平面上,该区明显地表现为东弱西强的构造挤压变形特征,并对砂岩的储层性质产生重要影响。东区平均古构造应力值为19．8～28．3MPa,对应的平均砂岩孔隙度为17．1％;西区平均古构造应力值为62．6～80．1MPa,对应的平均砂岩孔隙度为6．4％～4．6％。     

Cu3 N弹性和热力学性质的第一性原理研究

利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO₃结构Cu₃N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu₃N的弹性常数,Poisson比等,并分析出Cu₃N在零温零压下是稳定的. 通过准谐Debye模型计算Cu₃N的热力学性质,得到了Cu₃N的晶格常数、等压比热容、等容比热     

N掺杂SnO2材料光电性质的第一性原理研究

采用全电势线性缀加平面波(full potential linearized augmented plane wave method,简记为FP-LAPW)方法,基于密度泛函理论第一性原理计算分析N掺杂SnO₂材料,研究了在N替代O原子和N替代Sn原子情况下的电子态密度、电荷密度分布以及光学性质.研究表明N掺杂替代Sn较之N掺杂替代O原子的带隙要宽,都宽于SnO₂的本征带隙,且两种情况下N分别处于负氧化态和正氧化态,其介电函数谱也与带隙对应发生蓝移,从理论上指出     

退火对B掺杂纳米金刚石薄膜微结构和电化学性能的影响

采用热丝化学气相沉积法制备B掺杂纳米金刚石薄膜,并对薄膜进行真空退火处理,系统研究了不同退火温度对B掺杂纳米金刚石薄膜的微结构和电化学性能的影响.结果表明,当退火温度升高到800 ℃后,薄膜的Raman谱图中由未退火时在1157,1346,1470,1555 cm^-1处的4个峰转变为只有D峰和G峰,说明晶界上的氢大量解吸附量减少;并且D峰和G峰的积分强度比I_D/I_G值变为最小,即sp²相团簇     

Ecological classification of European transitional waters in the North-East Atlantic eco-region

A new methodology to classify European North-East Atlantic transitional waters into ecological types has been developed based on the most important hydrological and morphological features that are likely to determine the ecology of aquatic systems in transitional waters. Hydrological indicators help identifying if a transitional water area is dominated by fresh or sea water and/or by intertidal or subtidal areas, while morphological indicators allow an estimation of the complexity of the transitional water and the diversity of the habitats involved. Twelve transitional waters of the southern Bay of Biscay were classified using this methodology and the five hydro-morphological types obtained were validated with benthic macro-invertebrate data. Transitional waters with a complex morphology showed the highest values of species diversity, while those with a smaller tidal influence showed lower species diversity. The ‘Scrobicularia’ and ‘Abra’ assemblages, previously identified in the study area, were found to be related to different types of transitional waters. The ‘Abra’ assemblage only appeared in estuaries with a complex morphology and dominated by tidal influences, while the ‘Scrobicularia’ assemblage was detected in all the transitional waters except for a single coastal lagoon. This classification of transitional waters may therefore be useful to establish the biological reference conditions needed for European Directives.     

海绵内生真菌胞外多糖理化性质及自由基清除活性研究

从1株海绵内生真菌(Alternaria sp.)链格孢菌的发酵液中提取胞外多糖,对其进行Q Sepharose FF离子交换色谱分离纯化,得到2个组分JJY-W和JJY-S。运用各种化学方法及波谱方法对JJY-W和JJY-S的理化性质及结构进行分析,并对多糖清除自由基活性进行了评价。结果表明,JJY-W和JJY-S的分子量分别为1.4KD和1.8KD;JJY-W以半乳糖、葡萄糖为主,含有少量甘露糖,摩尔比为:甘露糖∶葡萄糖∶半乳糖=1∶2.5∶11。JJY-S以甘露糖、葡萄糖为主,含有少量半乳糖,摩尔比为:甘露糖∶葡萄糖∶半乳糖=3∶2∶1。JJY-W总糖含量为46.3%,未检测出糖醛酸,蛋白含量为2%。JJY-S总糖含量为52%,糖醛酸含量为6.1%,蛋白含量为14%。活性分析表明,2种多糖均具有一定的体外抗氧化活性,并随着浓度的增加清除自由基能力均增强,JJY-W清除DPPH自由基的活性要强于JJY-S,而JJY-S清除OH.自由基的活性要强于JJY-W。     

蒙脱石红移、蓝移及水化特征的谱学分析

对提纯蒙脱石、钠化蒙脱石、有机插层蒙脱石进行紫外-可见光学吸收谱分析、红外光谱分析,发现蒙脱石随着粒度的变化产生红移和蓝移现象。1631插层样品较钠化样品红移20 nm以上,而提纯的胶体粒子样品较1631插层样品SM G-1631红移80 nm;由于提纯蒙脱石样品粒度变细羟基伸缩振动吸收峰向高波数移动了1.69 cm-1,即蓝移了1.69cm-1。蒙脱石水化性能的XRD分析表明,蒙脱石吸水后晶层发生膨胀、剥离,脱水时分散后的晶层发生凝聚作用,即面-面结合作用,形成蒙脱石“定向性层状集合体”衍射峰的d值产生了相应的变化,这种凝聚作用是蒙脱石分散剥离的逆作用,但凝聚后形成的凝聚蒙脱石的衍射谱特征与原始蒙脱石的大不相同。蒙脱石红移、蓝移及水化特征的谱学分析研究丰富了天然纳米蒙脱石矿物材料晶体化学研究的内容,具有重要的理论意义。     

Macroscopic criteria for Green type porous materials with spheroidal voids: application to double porous materials

Combined effects of matrix plastic compressibility and void shape are investigated for ductile porous materials. To this end, a spheroidal volume containing a confocal spheroidal (prolate or oblate) void subjected to uniform strain rate boundary conditions has been first studied. A Green type matrix is chosen as a prototype for investigating effects of plastic compressibility. This is carried out by using a kinematics limit analysis theory from which a closed‐form expression of the macroscopic criterion is established for the considered class of materials. These results are then extended to ductile porous materials made up of a green matrix containing randomly oriented spheroidal voids. In the framework of a two‐step homogenization procedure, the obtained results are implemented to describe the macroscopic behavior of double porous materials involving spherical voids at the microscale and randomly oriented and distributed spheroidal voids at the mesoscale. For validation purpose, the new derived criteria are assessed and validated by comparing their predictions to available upper bounds and numerical data from literature. Copyright © 2017 John Wiley & Sons, Ltd.     

Numerical analysis of the effect of natural microcracks on the supercritical CO2 fracturing crack network of shale rock based on bonded particle models

The problem of predicting the geometric structure of induced fractures is highly complex and significant in the fracturing stimulation of rock reservoirs. In the traditional continuous fracturing models, the mechanical properties of reservoir rock are input as macroscopic quantities. These models neglect the microcracks and discontinuous characteristics of rock, which are important factors influencing the geometric structure of the induced fractures. In this paper, we simulate supercritical CO₂ fracturing based on the bonded particle model to investigate the effect of original natural microcracks on the induced‐fracture network distribution. The microcracks are simulated explicitly as broken bonds that form and coalesce into macroscopic fractures in the supercritical CO₂ fracturing process. A calculation method for the distribution uniformity index (DUI) is proposed. The influence of the total number and DUI of initial microcracks on the mechanical properties of the rock sample is studied. The DUI of the induced fractures of supercritical CO₂ fracturing and hydraulic fracturing for different DUIs of initial microcracks are compared, holding other conditions constant. The sensitivity of the DUI of the induced fractures to that of initial natural microcracks under different horizontal stress ratios is also probed. The numerical results indicate that the distribution of induced fractures of supercritical CO₂ fracturing is more uniform than that of common hydraulic fracturing when the horizontal stress ratio is small.