Structurally controlled fluid flow associated with breccia vein formation

A breccia vein sampled from a shear zone in greenschist facies metapelites at Mount Isa, Queensland, Australia, shows a systematic variation in vein geometry that is related to the geometry of folding and faulting within the sample. Calcite vein-fill is coarse grained and equigranular, suggesting precipitation in a fluid-filled space. Partially folded veins suggest that veining occurred during folding and faulting. The breccia vein contains a central zone in which dilation has occurred simultaneously in all directions in the plane of section, implying that this was a zone of high fluid pressure and nearly isostatic differential stress during folding and faulting. From these observations, it can be inferred that the breccia vein was a zone of high permeability and a likely fluid channel during deformation. This hypothesis was tested by stable isotope analysis of veins and host rocks. The calcite veins have δ¹³C values of -11.1 ± 0.1% and δ¹⁸O values of 6-10%_o, whereas the host metapelite has δ¹³C values of -10.62 and -10.11% and δ¹⁸O values of 14-15%_o. These values are consistent with an igneous-derived, H₂O-dominated fluid that exchanged little oxygen with the host rocks, but derived much of its carbon from the wall rock. The isotopic disequilibrium between the veins and the wall rock confirms that the fluid was externally derived, and that the breccia vein acted as a channel for large-volume fluid flow within the shear zone.     

Stabilization of Bottom Hole Temperature With Finite Circulation Time and Fluid Flow

As an alternative to finite element or finite difference modelling, analytical solutions are derived by the method of Laplace transformation and numerical results obtained for several models of the bottom hole temperature stabilization. Included in the models are the finite circulation time, the thermal property contrast between the borehole mud and the surrounding formation, and the presence of radial or lateral fluid flow in the formation, all of which are found to have significant effects on the dissipation of the thermal disturbance induced by drilling.
The mud circulation is considered to have the effect of either maintaining the borehole mud at a constant temperature or supplying a constant amount of heat per unit length per unit time to the borehole. For small circulation times, the former reduces to the 'zero circulation' model in which the mud circulation creates an instantaneous temperature anomaly at the hole bottom; for small borehole radii, the latter reduces to the line source model and the traditional 'Homer plot'.
For typical drilling operations in which the bottom hole temperatures are measured several hours to several tens of hours after the hole is shut in, the new models generally predict higher equilibrium formation temperatures than does the Horner plot. However, predictions from the various models converge if the BHTs are taken after the hole has been shut in for a period which is greater than about five times the circulation period.     

A compact model for the planar rhomboidal 4-body problem

We obtain a compact model for the global study of the planar rhomboidal 4-body problem in a level of constant negative energy. This model is a variation of the non compact model obtained through a McGehee blow up transformation. but compactness permits to obtain results which are not clear in the other case.     

Spatial averaging of hydraulic conductivity under radial flow conditions

Steady-state radial flow in three-dimensional heterogeneous media is investigated using a geostatistical approach. The goal of the study is to develop a model of the relationship between corescale hydraulic conductivities measured at the wellbore and the conductivity of the surrounding drainage region as measured by a larger scale flow experiment such as a pump test. Conductivity at the point or core-scale is modeled as a stationary and multivariate lognormal spatial random function. Conductivity of the drainage region is obtained by a weighted nonlinear spatial average over the point-scale values within. This empirical spatial averaging process is shown to yield excellent approximations of true effective drainage region conductivities calculated using a numerical flow model. The geostatistical model for point-scale conductivity and the spatial averaging process are used to determine the first and second order ensemble moments of drainage region conductivity. In particular, an expression is derived for the conditional expectation of drainage region conductivity given point-scale values measured at the wellbore. The results are illustrated in a case study of a well from a sandstone oil reservoir where both core and transient-test conductivity data from the same interval are available for comparison.     

The radial structure of hot one-temperature accretion flows with advection

Considering nonthermal e^±-pair production, this paper is focused on the radial structure of hot one-temperature accretion flows with advection under the condition of small viscous parameter ( = 0.1) and low mass-accretion rates. Self-similar relations of hot flow with advection have been adopted. The authors have used a scheme, in which the two regions of accretion flow are calculated separately and then joined together. Some typical features of hot flow with advection have been confirmed, and several new results obtained: there exists a critical radius r_cr; the local cooling rate is inversely proportional to the square of the mass of the central object; the e^±-pair process affects significantly the radiation of hot flows with advection.     

Ab initio prediction of 29Si-NMR chemical shifts

The ability of several ab initio models to predict experimental ²⁹Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allytrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6–31G^*, B3LYP/6-31G^*, HF/6–311+G^**, B3LYP/6–311+G^** and MPW1PW91/6–311+G^** models respectively. The ²⁹Si chemical shifts calculated by GIAO method using HF/6–311+G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.