混合式球面退化剖分模型的设计与编码

为了解决球面退化四叉树格网(DQG)模型孔径较大、格网单元面积分布不均匀以及三角格网单元应用不完全四叉树剖分的问题,通过控制单元面积的思路设计了一种格网单元孔径更小、分布更均匀的四边形(中低纬地区)与三角形(高纬地区)的混合格网模型——混合式球面退化格网模型(MSDG);并对所有格网单元利用四叉树进行编码。通过对格网单元的几何属性统计分析发现,该格网模型的几何属性与DQG模型相比,其单元面积变化更小、分布更加均匀稳定。     

How landscapes change: Integration of spatial patterns and human processes in temperate landscapes of southern Chile

A comprehensive understanding of the patterns that occur as human processes transform landscapes is necessary for sustainable development. We provide new evidence on how landscapes change by analysing the spatial patterns of human processes in three forest landscapes in southern Chile at different states of alteration (40%-90% of old-growth forest loss). Three phases of landscape alteration are distinguished. In Phase I (40%-65% of old-growth forest loss), deforestation rates are < 1% yr⁻¹, forests are increasingly degraded, and clearance for pastureland is concentrated on deeper soils. In Phase II (65%-80%), deforestation reaches its maximum rate of 1-1.5% yr⁻¹, with clearance for pastureland being the main human process, creating a landscape dominated by disturbed forest and shrubland. In this phase, clearance for pastureland is the primary driver of change, with pastures expanding onto poorer soils in more spatially aggregated patterns. In Phase III (80%-90%), deforestation rates are again relatively low (<1% yr⁻¹) and forest regrowth is observed on marginal lands. During this phase, clearance is the dominant process and pastureland is the main land cover. As a forest landscape is transformed, the extent and intensity of human processes vary according to the existing state of landscape alteration, resulting in distinctive landscape patterns in each phase. A relationship between spatial patterns of land cover and human-related processes has been identified along the gradient of landscape alteration. This integrative framework can potentially provide insights into the patterns and processes of dynamic landscapes in other areas subjected to intensifying human use.     

Evaluation of alkene degradation in the detailed tropospheric chemistry mechanism, MCM v3, using environmental chamber data

The representation of alkene degradation in version 3 of the Master Chemical Mechanism (MCM v3) has been evaluated, using environmental chamber data on the photo-oxidation of ethene, propene, 1-butene and 1-hexene in the presence of NO_x, from up to five chambers at the Statewide Air Pollution Research Center (SAPRC) at the University of California. As part of this evaluation, it was necessary to include a representation of the reactions of the alkenes with O(³P), which are significant under chamber conditions but generally insignificant under atmospheric conditions. The simulations for the ethene and propene systems, in particular, were found to be sensitive to the branching ratios assigned to molecular and free radical forming pathways of the O(³P) reactions, with the extent of radical formation required for proper fitting of the model to the chamber data being substantially lower than the reported consensus. With this constraint, the MCM v3 mechanisms for ethene and propene generally performed well. The sensitivity of the simulations to the parameters applied to a series of other radical sources and sink reactions (radical formation from the alkene ozonolysis reactions and product carbonyl photolysis; radical removal from the reaction of OH with NO₂ and β-hydroxynitrate formation) were also considered, and the implications of these results are discussed. Evaluation of the MCM v3 1-butene and 1-hexene degradation mechanisms, using a more limited dataset from only one chamber, was found to be inconclusive. The results of sensitivity studies demonstrate that it is impossible to reconcile the simulated and observed formation of ozone in these systems for ranges of parameter values which can currently be justified on the basis of the literature. As a result of this work, gaps and uncertainties in the kinetic, mechanistic and chamber database are identified and discussed, in relation to both tropospheric chemistry and chemistry important under chamber conditions which may compromise the evaluation procedure, and recommendations are made for future experimental studies. Throughout the study, the performance of the MCM v3 chemistry was also simultaneously compared with that of the corresponding chemistry in the SAPRC-99 mechanism, which was developed and optimized in conjunction with the chamber datasets.     

循环荷载下饱和粘土强度等效计算探讨

饱和粘土在不排水循环荷载作用下强度会发生衰减,建立在粘土地基上的建筑物和填土道路在地震过程中有时会遭受破坏。本文在超固结粘土不排水强度计算的基础上,引入循环荷载作用损伤因子,提出循环荷载作用下饱和粘土强度计算方法以及参数的确定方法。同时,分析了循环荷载作用下再固结系数对粘土强度增长的影响。通过试验验证,所提出的方法是合理的。该方法为循环荷载作用下粘土地基的强度和稳定性预测提供有效的途径。     

Changes in intensity of wind erosion at different stages of degradation development in grasslands of Inner Mongolia, China

Overgrazing by increasing numbers of livestock in the Horqin Sandy Land of Inner Mongolia, China, has led to extensive degradation of the region's sandy steppes. Degraded grasslands are generally classified into four main types: fixed (least degradation), semi-fixed (light degradation), semi-shifting (moderate degradation) and shifting (severe degradation) sandy lands, representing four stages of degradation development. An experiment was conducted in the Horqin Sandy Land to investigate changes in intensity of wind erosion at different stages of degradation development in sandy grasslands and determine the extent to which surface wind erosion was affected by surface-related soil and vegetation factors through their effects on surface roughness length and wind regimes. Daily wind erosion rate was monitored at four sites of degraded grassland over an erosive period from 1 April to 10 June in 2001. Soil and vegetation properties for these sites were also measured twice: one in mid-April prior to the establishment of vegetation and again in mid-June after the establishment of vegetation. Relationships between surface roughness length and soil and vegetation variables were examined at each of the two stages of vegetation development. This study shows striking differences in the intensity of surface wind erosion among sites. The daily wind erosion rate in the fixed sandy land was, on average, only about 1/5 of the rate in the semi-fixed sandy land, 1/14 of the rate in the semi-shifting sandy land and 1/47 of the rate in the shifting sandy land suggesting a much higher resistance of the fixed sandy land to wind erosion compared to other sites. Differences in rate of wind erosion between sites were attributed to between-site differences in soil and vegetation properties that exerted significant effects on wind regimes by altering surface roughness length. At the pre-establishment stage of vegetation, surface roughness length was determined by a combination of litter amount on the ground, soil surface hardness and soil moisture content, with litter amount explaining the greatest proportion of the variation. At the post-establishment stage of vegetation, the development of the surface roughness effects was mainly governed by vegetation characteristics (vegetation cover in particular), while the effects of soil surface hardness and soil moisture on surface roughness length are likely to be masked by vegetation effects. The findings suggest that better management practices of restoring vegetation in degraded grasslands are required to reduce soil erosion losses and achieve a sustainable livestock production in the Horqin Sandy Land, an ecologically fragile sandy land ecosystem.     

Sea transport of animal and vegetable oils and its environmental consequences

The increasing production––and therefore sea traffic––of vegetable oils has regularly led to spillages during the past 40 years. The accident of Allegra, on October,1st, 1997, in the English Channel gave rise to a spillage of 900 tonnes of palm nut oil. The drift of this solid vegetable oil was followed by aerial observations. Samples of oil were collected in order to analyse its chemical evolution. This study, associated with several bibliographic cases of pollution by non-petroleum oils, shows that drifting oils can mix with floating material to sink or form a crust. They can also be oxidized or disperse and/or be degraded by bacteria. They may also polymerise. The coating properties of vegetable oils act as crude oils to affect sea life, tourism and yachting. As a result, it is necessary to quickly collect the oil after a spillage, using usual equipment (booms and pumps).     

Degradation of Microbes for the Crude Oil Contaminants

Production and storage-transportation of crude oil can not only give rise to soil pollution but also destroy ecological environment. Degradation of microbes for oily soil was studied with the instnunent, Geofina Hydrocarbon Meter (GHM), by experimental analysis qualitatively and quantitatively in the paper. Analytical result showed that the crude oil could be considerably degraded by eating-oil microbes in oily soil and the number of eating-oil microbes increased while the working hours of oil-well rising. As a result, contaminated oil could be degraded more quickly by a lot of eating-oil microbes in the soil. At the same time, the degradation rate of contaminated oil increased gradually as the time went on. In addition, amount of gaseous component in the oily soil samples increased with degraded time and the microbes could selectively consume contaminated oil strongly, so biedegradation might alleviate the degree of contamination and destruction to the soil and environment in the process of oil product     

An investigation of the relationship between uniaxial compressive strength and degradation for selected rock types

The relationship between uniaxial compressive strength and degradation was investigated for selected rock types, by using regression analyses to determine whether degradation was a useful predictor of compressive strength. In addition, the effects of aggregate particle size, number of hammer blows during the degradation test, engineering index properties, petrographic characteristics, and water saturation on the compressive strength-degradation relationship were evaluated. The results show that strong inverse relationships exist between compressive strength and degradation (measured on a 9.5-4.75-mm size aggregate) for sandstones and igneous/metamorphic rocks, but that no significant relationship exists for limestones/dolomites. The results also indicate a strong positive correlation between degradation and L.A. abrasion loss and can be used to establish a limit of allowable degradation for practical applications. Engineering index properties do not significantly affect the relationship between compressive strength and degradation but petrographic characteristics are important in explaining the strength and degradation behavior of the rocks studied. Water saturation decreases compressive strength and increases degradation to varying degrees.     

Störungen durch flüchtige Substanzen bei der Messung des biologischen Sauerstoffverbrauches mit dem Sapromat

Interferences by Volatile Substances in Measuring the Biological Oxygen Consumption Using the Sapromat Aerobic microbial degradation processes can be well monitored by means of the oxygen consumption. There are special analyzers for these measurements, such as the Sapromat produced by Voith GmbH Heidenheim, Germany. Interference occurs during investigations with (or in the presence of) volatile components of low water solubility, which appear in dissolved state or as an additional phase. Thus, the Sapromat records an apparent oxygen consumption without the participation of microorganisms which is in the order of usual BOD₅-values or even above them and is attributable to physico-chemical reasons and the measuring system used. The present paper points out this phenomenon and investigates the reasons. These are demonstrated and discussed. The results emphasize the urgency of blanks in order to detect abiotic effects using the Sapromat.     

Inhibition Concentration of Phenolic Substances under Different Cultivation Conditions. Part II: Impact of Dissolved Oxygen Concentration and Temperature on Degradation Kinetics

The degradation behaviour of a phenolic waste-water from coking containing easily utilizable carbon sources (volatile fatty acids), substances with toxic effects (phenols and phenolic compounds), and non-biodegradable organic substances (humic-like substances) by an adapted activated sludge is investigated depending on dissolved oxygen concentration (DO) and temperature. In addition, the degradation of an acetate model water with the same population was investigated. The investigations were carried out in a special respiration fermenter system by recording oxygen consumption in DO-static experiments. The oxygen consumption curves were subjected to linear regression analysis, and the maximum oxygen consumption rates were used for further calculations. Evaluation of the degradation kinetics was carried out with non-linear regression analysis via commercial software utilizing the Marquardt-Levenberg algorithm and which tested various kinetic models to obtain the best curve fit. It is shown that the dependence of growth on DO in acetate model water is well represented by Monod kinetics but by contrast can only be described in phenolic wastewater with acceptable goodness by Hill kinetics, modified by a maintenance term. The kinetic constants calculated for the mesophilic range (37 °C) are for the model water as follows: maximum specific growth rate = 0.218 h^?1, half saturation constant with respect to oxygen = 0.297 g L^?1, and for the waste-water: maximum specific growth rate = 0.387 h^?1, half saturation constant with respect to oxygen = 0.013 gL^?1 and maintenance coefficient for oxygen = 0.107 g g^?1 h^?1. For the thermophilic range (55 °C), a higher growth rate but a significant lower yield coefficient are to be observed. The kinetic constants calculated are: maximum specific growth rate = 0.8 h^?1, half saturation constant with respect to oxygen = 0.14 gL^?1 and maintenance coefficient for oxygen = 0.3 g g^?1 h^?1. Therefore, it can be concluded that the toxic effect of the biodegradable phenols causes a maintenance metabolism which leads to higher oxygen demand. The diminution of the limiting DO and the increased maintenance metabolism confirm the assumption that a higher maintenance metabolism leads to increased sensitivity with respect to the cosubstrate oxygen. It can be concluded that the experimental and mathematical methods used permit the maintenance metabolism with respect to oxygen caused by toxic substrates and milieu influences to be accurately determined.