Predictive geochemical mapping using environmental correlation

The distribution of chemical elements at and near the Earth's surface, the so-called critical zone, is complex and reflects the geochemistry and mineralogy of the original substrate modified by environmental factors that include physical, chemical and biological processes over time.Geochemical data typically is illustrated in the form of plan view maps or vertical cross-sections, where the composition of regolith, soil, bedrock or any other material is represented. These are primarily point observations that frequently are interpolated to produce rasters of element distributions. Here we propose the application of environmental or covariate regression modelling to predict and better understand the controls on major and trace element geochemistry within the regolith. Available environmental covariate datasets (raster or vector) representing factors influencing regolith or soil composition are intersected with the geochemical point data in a spatial statistical correlation model to develop a system of multiple linear correlations. The spatial resolution of the environmental covariates, which typically is much finer (e.g. ∼90 m pixel) than that of geochemical surveys (e.g. 1 sample per 10-10,000 km²), carries over to the predictions. Therefore the derived predictive models of element concentrations take the form of continuous geochemical landscape representations that are potentially much more informative than geostatistical interpolations.Environmental correlation is applied to the Sir Samuel 1:250,000 scale map sheet in Western Australia to produce distribution models of individual elements describing the geochemical composition of the regolith and exposed bedrock. As an example we model the distribution of two elements – chromium and sodium. We show that the environmental correlation approach generates high resolution predictive maps that are statistically more accurate and effective than ordinary kriging and inverse distance weighting interpolation methods. Furthermore, insights can be gained into the landscape processes controlling element concentration, distribution and mobility from analysis of the covariates used in the model. This modelling approach can be extended to groups of elements (indices), element ratios, isotopes or mineralogy over a range of scales and in a variety of environments.     

A note on “Origin of components in Chilean thermal waters” by

Risacher et al. (2011) have presented voluminous data on thermal waters of Chile that is quite appreciable; however, their work still falls short on several counts. The most notable shortcoming of the work is the presentation and treatment of data. The interpretations are based on questionable premises (viz., extent of seawater intrusion) and considerations (viz., using average chemical composition of rock types for geochemical modeling, considering volcanic rocks as the only rock type in contact with the geothermal fluids) and assumptions not always substantiated by facts (with proper references) could have been corroborated. Use of Cl/Br ratio for discrimination purpose is unconvincing, considering the uncertainty in the measurement of low (<1 mg/L) Br concentration.     

月球东海盆地综合解析与撞击初始条件的研究

东海是月球上最年轻的多环撞击盆地,关于其形成机制的研究很多,但成果大都基于正撞击的机制提出的,虽然有部分学者提出东海是斜撞击的,但缺乏具体撞击参数。本文通过多源数据融合,综合分析LRO影像数据、LOLA地形数据、M~3高光谱数据和IIM高光谱数据,对东海地区的地貌特征、物质成分进行了较为系统的解译,发现在东海中央熔融区存在一条与东海撞击方向垂直的中央隆起区域(中央隆起线),其也是中央熔融区粗糙部分与光滑部分的分界线,结合撞击坑成坑理论,认为其可能是撞击过程冲击波作用引起的堆叠作用形成的。同时利用GRAIL数据及对该地区的重力异常的成因进行了分析,认为异常是由于压强、温度及岩石粘度的改变引起局部莫霍面抬升和中央熔融物的形成而出现的,进而估算出熔融物占盆地内物质的25%,约为1.1×10~6km~3。同时,对GRAIL数据的剖面分析结果也支持了本文的斜撞击理论。最后,综合多方面的信息和撞击理论获取东海盆地构造分布图,并根据中央隆起线、溅射物及线性构造的分布特征等,提出东海盆地理论上是由一直径在50~100km的撞击体以10~30km/s的速度自东偏北约20°~30°方向以20°~30°的角度斜撞击月表而形成的。这可为研究更早期的月球撞击坑提供理论参考。     

The Coarse-Grained Lacustrine Slope Apron Deposits in the Moliqing Area, Yitong Basin, Northeast China

Overlapping gravity accumulation bodies were formed on the northwestern steep slope of the Shuangyang Formation in the Moliqing fault depression of northeast China. This study analyzed in detail the spatial distribution of the lithofacies and lithofacies associations of these accumulation bodies based on more than 600 m of core sections, and summarized 12 major types of lithofacies and three types of lithofacies associations: (1) the proximal zone consists of gravelly debris flows dominated by alluvial channel conglomerates; (2) the middle zone is dominated by various gravity flow deposits and traction flow deposits; and (3) the distal zone is dominated by mudstones with intercalations of sandy debris and turbidites. Combining with the grain size cumulative probability curves analysis, we determined the transformation of debris flows to sandy debris flows and to turbidity currents in the slope zone of the basin margin, and further proposed a lacustrine slope apron model that is characterized by (1) an inconstant multiple source (line source), (2) an alternation of gravity flow deposits and traction flow deposits dominated by periodical changes in a source flood flow system, and (3) the transformation of sandy debris flow deposits into distal turbidity current deposits. This sedimentary model may be applicable to other fault depressions for predicting reservoir distribution.     

华北北缘东段开原地区三叠纪侵入岩年代学及岩石地球化学研究

本文报道了位于华北北缘东段开原地区尖山子岩体、宝兴岩体和树德屯岩体的岩相学、岩石地球化学及年代学特征,探讨了上述岩体的形成时代、岩石成因及其构造环境。锆石U-Pb定年结果表明,尖山子岩体形成于251±1.3Ma,宝兴岩体形成于235±1.3Ma,树德屯岩体形成于224±1.9Ma,说明开原地区三叠纪存在早三叠世、中三叠世和晚三叠世三个时期的岩浆活动。尖山子岩体以二长花岗岩为主,具高硅低镁特征,属钙碱性系列;富集大离子亲石元素Rb、K、Ba、Th,相对亏损Ta、Nb、P、Hf、Zr等高强场元素;δEu=0.55~1.87,(La/Yb)N=6.23~47.9,轻重稀土分馏明显,富集轻稀土,亏损重稀土。宝兴岩体以花岗闪长岩为主,Si O2含量变化较大(52.36%~74.06%),Al2O3含量(14.5%~17.34%),Mg O含量(0.61%~3.66%),属钙碱性系列;富集大离子亲石元素Rb、K、Ba、Th,相对亏损Ta、Nb、P、Ti等高强场元素;无明显的Eu异常,(La/Yb)N=6.81~25.6,轻重稀土分馏较明显,富集轻稀土,亏损重稀土。树德屯岩体以闪长岩为主,岩石具有低硅高镁特征,K2O/Na2O比值为0.33~0.76,显示富K贫Na特征,属钙碱性系列;富集大离子亲石元素Rb、K、Ba、Th,相对亏损Ta、Nb、P、Ti、Hf、Zr等高强场元素;无明显的Eu异常,(La/Yb)N=3.87~10.2,轻重稀土分馏不明显。上述岩石地球化学特征表明,尖山子岩体和宝兴岩体的原始岩浆起源于下地壳基性物质的部分熔融,树德屯岩体的原始岩浆起源于亏损的地幔楔。研究区三叠纪岩浆岩形成于造山阶段挤压环境下。华北北缘东段的挤压碰撞作用一直持续到晚三叠世(224Ma),而造山阶段向造山后阶段的构造转换(挤压地壳加厚向伸展垮塌的环境转换)发生于晚三叠世-早侏罗世(224~180Ma)期间。华北北缘东段中生代岩石圈减薄或破坏始于晚三叠世-早侏罗世(224~180Ma)期间。     

Generalised observations of wave characteristics on near‐horizontal shore platforms: Synthesis of six case studies from the North Island,New Zealand

Most field studies of wave processes on shore platforms in front of eroding cliffs focus on a single site, revealing aspects of wave dynamics at that location. Here, we analyse data from six platforms around northeastern New Zealand and describe the fundamental control of shore platform width, gradient and elevation on wave processes, including greater attenuation of short‐period waves at lower tidal stages and increases in longer period wave energy towards the cliff toe. These data suggest that empirical formulae developed from coral‐reef environments provide better predictions of wave height on platforms than formulae currently used in shore platform models.     

地震勘探技术在煤炭勘查中的应用与展望

地震勘探作技术为一种重要的勘探方法,可以经济、有效的发现资源和解决资源开采过程中遇到的构造、地层、岩性等问题。煤炭地震勘探发展过程中地震野外数据采集、地震数据处理和地震解释都取得了重大成就,目前煤炭地震勘探正进一步向高信噪比、高分辨率、高保真度、高清晰度、高精度、定量分析的方向发展,未来也必将在煤炭资源发现和矿井隐蔽致灾因素的探测中发挥重要作用。     

庐枞矿集区中东部七家山—马口地区深部找矿潜力分析

为调查庐枞矿集区中东部七家山—马口地区深部矿产资源潜力,利用小波变换方法提取深源重磁场,通过对垂向一阶导数Z与水平方向导数模S进行参数变换,突出深源重磁场的局部异常; 结合频谱激电(spectrum induced polarization,SIP)、可控源音频大地电磁测深(controlled source audio-frequency magneto tellurics,CSAMT)成果,在调查区深部查明了一条长大于3.0 km、宽大于0.5 km的高重低磁、低阻高极化异常带; 根据调查区内外已知铜矿(化)体分布规律,结合已知矿(化)体在深源重磁异常中的分布及钻孔(zk4601)钻探验证结果,认为上述异常带是铜多金属矿化蚀变带的反映,是寻找铜多金属矿的有利部位,具有较好的找矿前景。     

蒙脱石伊利石化的水热实验模拟

以蒙脱石为初始材料,通过水热实验模拟在不同温度压力条件下蒙脱石的伊利石化过程。利用X射线粉末衍射及X射线荧光光谱、红外光谱和扫描电镜等方法对样品的矿物物相、化学成分、晶体结构与微观形貌等进行分析,其结果表明:(1)蒙脱石至伊利石的转化受温度和压力条件的控制;(2)随着温度和压力的增高,蒙脱石伊利石化沿着蒙脱石-无序伊蒙混层-有序伊蒙混层-伊利石的转化序列进行转化;(3)水热实验模拟表明蒙脱石至伊利石的转化以溶解重结晶机制为主。实验结果不仅有助于了解埋藏与低级变质作用中的蒙脱石伊利石化过程,同时为研究断层活动所致断层泥中黏土矿物的转化及反演断层形成时温度压力条件提供基本参数。