三稀矿产资源新兴产业发展及政策建议

三稀矿产资源是战略性新兴产业发展的基础原料,广泛应用在国防、航天、高端电子设备、核工业、发光材料等高精尖技术领域。本文在系统收集国内外三稀矿产资源生产、消费领域、价格以及进出口资料的基础上,提出了促进三稀矿产资源新兴产业发展的政策建议     

关于新型测绘的探索

探索新型测绘的产生背景与科学内涵等问题,对新时期测绘地理信息事业转型升级与跨越发展具有重要意义。该文首先从经济社会发展需求、测绘发展新阶段、测绘地理信息转型升级、测绘地理信息跨越发展4个方面阐述了新型测绘产生的背景;其次,从新型测绘关系角度给出了新型测绘的内涵与架构,从范围、内容、技术手段、体制机制方面描述了新型测绘的特征;再次,从新型测绘目标出发,描述了新型基础测绘的内涵、要求与主要任务,地理国情监测的总体目标与主要任务,公共服务与应急测绘的新需求与主要任务;最后围绕测绘地理空间数据获取、处理、管理、分析、服务与应用主线,探讨了新型测绘需要着重研究的新理论、新方法、新技术装备,旨在为新型测绘的研究与发展奠定基础。     

A New Progress of the Proterozoic Chronostratigraphical Division

The Precambrian, an informal chronostratigraphical unit, represents the period of Earth history from the start of the Cambrian at ca. 541 Ma back to the formation of the planet at 4567 Ma. It was originally conceptualized as a "Cryptozoic Eon" that was contrasted with the Phanerozoic Eon from the Cambrian to the Quaternary, which is now known as the Precambrian and can be subdivided into three eons, i.e., the Hadean, the Archean and the Proterozoic. The Precambrian is currently divided chronometrically into convenient boundaries, including for the establishment of the Proterozoic periods that were chosen to reflect large-scale tectonic or sedimentary features(except for the Ediacaran Period). This chronometric arrangement might represent the second progress on the study of chronostratigraphy of the Precambrian after its separation from the Phanerozoic. Upon further study of the evolutionary history of the Precambrian Earth, applying new geodynamic and geobiological knowledge and information, a revised division of Precambrian time has led to the third conceptual progress on the study of Precambrian chronostratigraphy. In the current scheme, the Proterozoic Eon began at 2500 Ma, which is the approximate time by which most granite-greenstone crust had formed, and can be subdivided into ten periods of typically 200 Ma duration grouped into three eras(except for the Ediacaran Period). Within this current scheme, the Ediacaran Period was ratified in 2004, the first period-level addition to the geologic time scale in more than a century, an important advancement in stratigraphy. There are two main problems in the current scheme of Proterozoic chronostratigraphical division:(1) the definition of the Archean–Proterozoic boundary at 2500 Ma, which does not reflect a unique time of synchronous global change in tectonic style and does not correspond with a major change in lithology;(2) the round number subdivision of the Proterozoic into several periods based on broad orogenic characteristics, which has not met with requests on the concept of modern stratigraphy, except for the Ediacaran Period. In the revised chronostratigraphic scheme for the Proterozoic, the Archean–Proterozoic boundary is placed at the major change from a reducing early Earth to a cooler, more modern Earth characterized by the supercontinent cycle, a major change that occurred at ca. 2420 Ma. Thus, a revised Proterozoic Eon(2420–542 Ma) is envisaged to extend from the Archean–Proterozoic boundary at ca. 2420 Ma to the end of the Ediacaran Period, i.e., a period marked by the progressive rise in atmospheric oxygen, supercontinent cyclicity, and the evolution of more complex(eukaryotic) life. As with the current Proterozoic Eon, a revised Proterozoic Eon based on chronostratigraphy is envisaged to consist of three eras(Paleoproterozoic, Mesoproterozoic, and Neoproterozoic), but the boundary ages for these divisions differ from their current ages and their subdivisions into periods would also differ from current practice. A scheme is proposed for the chronostratigraphic division of the Proterozoic, based principally on geodynamic and geobiological events and their expressions in the stratigraphic record. Importantly, this revision of the Proterozoic time scale will be of significant benefit to the community as a whole and will help to drive new research that will unveil new information about the history of our planet, since the Proterozoic is a significant connecting link between the preceding Precambrian and the following Phanerozoic.     

我国地质钻探现状和发展前景分析

我国经济社会发展已步入“新常态”。作为地质调查和矿产勘查工作重要技术支撑的地质钻探行业,资金投入显著减少,地质钻探工作量大幅下滑,常规钻探施工产能过剩;另一方面,地质钻探新的服务领域不断扩大,包括深部科学钻探,地热能及非常规能源勘查,海洋、灾害防治、生态环境、地外天体、极地方面的钻探等。如何应对地勘行业出现的问题,是全行业共同面对的挑战。在对当前及今后一段时期地质钻探工程面临的困难、挑战和机遇等进行调研分析的基础上,对我国地质钻探未来的发展前景进行了预测,认为地质钻探工作量将进一步减少,新领域、新业态的钻探工程及先进钻探技术和装备需求将进一步加大,更加贴近国家需求,更加注重环保理念。     

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.     

Hydrochemical characterization of groundwater in Balad district,Salah Al-Din Governorate,Iraq

The assessment of hydrochemical quality of groundwater is very important to explore its nature and usefulness. In this paper, groundwater quality evaluation is carried out in the Balad district, Salah Al-Din Governorate, Iraq. A total of 28 groundwater samples are collected from shallow tube wells and analyzed for various physicochemical parameters. Groundwater suitability for drinking is evaluated based on the World Health Organization (WHO) and Iraqi standards, and suitability of groundwater for irrigation is assessed based on various hydrochemical parameters. The results reveal that the dominant types of groundwater based on piper diagram are mixed CaMgCl and CaCl. Gibbs ratio indicates that the groundwater in the studied area is affected by the evaporation process. The cation-anion exchange reaction in the studied area demonstrates that 54% of the groundwater samples indicate a direct base (cation-anion) exchange reaction, while 46% of the groundwater samples indicating the chloro-alkaline disequilibrium. Furthermore, generally all of the groundwater samples are unsuitable for drinking and irrigation. Cluster analysis reveals two different groups of similarities between the groundwater samples, reflecting different pollution levels in the studied area.     

大数据环境下内蒙古浩布高地区铅锌多金属矿智能矿产预测研究

传统机器学习算法已广泛应用于矿产预测,但面对地质大数据的高维稀疏、不平衡小样本等特性仍缺乏有效处理和分析的方法,设计适合地质大数据特点的机器学习算法是智能矿产预测亟需解决的新问题。本文以内蒙古浩布高地区的铅锌多金属矿产预测为例,提出了一种面向地质大数据的半监督协同训练矿产预测模型。首先对研究区地质找矿信息和地球化学异常信息进行定量分析,提取断裂构造、二叠系地层、燕山期侵入岩、地层与岩体接触带、围岩蚀变及Pb、Zn、Sn、Cu地球化学异常共9种找矿因子。然后利用递归特征消除法优选找矿因子组合,不包括Sn异常在内的8个找矿因子组合被选为最优组合。最后,利用支持向量机和随机森林算法作为基分类器进行半监督协同训练矿产预测,绘制成矿概率分布图。ROC曲线和预测度曲线分析结果表明,半监督协同训练模型的AUC值和预测效率都高于随机森林和支持向量机模型。研究结果也为大数据环境下的智能矿产预测提供了一种新的思路。     

华北克拉通东缘金岭杂岩体岩浆源区及构造背景:来自岩相学、岩石地球化学及年代学的证据

金岭杂岩体由细粒黑云角闪闪长岩、中细粒黑云角闪闪长岩、中细粒黑云角闪二长闪长岩和细粒角闪二长闪长岩组成,是鲁西地区典型矽卡岩型富铁矿(金岭铁矿)控矿岩体。本次研究对细粒黑云角闪闪长岩和细粒角闪二长闪长岩进行了锆石LA‐ICP‐MS U‐Pb定年,其结果分别为129.2±3.2 Ma和132.8±1.2 Ma,表明该杂岩体的侵位时代为早白垩世。样品SiO2、K2O和Na2O含量分别介于54.17%~63.73%、1.92%~4.76%和3.10%~5.41%之间,K2O/Na2O为0.58~0.94,A/CNK为0.60~0.93,具有轻稀土富集,重稀土亏损的右倾型稀土配分模式,轻、重稀土分馏程度中等((La/Yb)N=9.94~23.49),Eu异常不明显(δEu=0.84~1.10),具中—弱负Ce异常(δCe=0.56~0.92)。样品以富集大离子亲石元素(Ba、K、U、Pb等)、亏损高场强元素(Nb、Ta、Ti)以及高Sr/Y为特征。金岭杂岩体为燕山晚期岩浆活动产物,属准铝质高钾钙碱性系列,岩浆主要来源于富集岩石圈地幔的部分熔融,并在岩浆上升侵位的过程中有地壳物质的同化混染。燕山晚期华北克拉通在古太平洋板块俯冲后后撤引起的板内伸展环境下,增厚陆壳减薄阶段,岩浆上侵就位形成金岭杂岩体。     

西秦岭夏河—合作地区早子沟和加甘滩金矿床石英微量元素特征及意义

西秦岭造山带发育有大量三叠纪的金矿床,早子沟和加甘滩金矿床是其中最典型的两个矿床,其金资源量分别为116 t和154 t,均为特大型金矿床。早子沟、加甘滩金矿床均位于夏河—合作区域性逆冲推覆断裂以南。早子沟赋矿地层为三叠统古浪堤组,赋矿岩石为泥质板岩、条带状硅质板岩及粉砂质板岩;加甘滩矿区出露地层为三叠统隆务河组,金矿体赋存于长石石英变砂岩夹粉砂质板岩岩性段内。加甘滩金矿床的研究程度相对较低,属中低温构造蚀变岩型金矿床;早子沟金矿床研究程度较高,但是对它的成因仍有不同的认识。石英的微量元素地球化学特征能够提供成矿流体来源与演化的信息,通过对早子沟和加甘滩金矿床开展石英的微量元素地球化学特征研究,探讨其成矿流体来源、成矿条件以及石英微量元素对金矿床形成的指示,为西秦岭造山带金矿床成因研究提供重要的信息。早子沟和加甘滩金矿床不同类型矿石中石英具有相似的稀土元素球粒陨石标准化配分曲线,总体表现出轻稀土元素相对富集、重稀土元素轻微亏损的特征,而且轻稀土元素与重稀土元素分馏程度高,重稀土元素内部分馏程度弱。 早子沟金矿床成矿期热液石英中Rb与Li呈负相关,Rb与Cs呈正相关,而加甘滩金矿床热液石英中Rb与Li、Cs相关性不明显,表明早子沟金矿床石英中Li含量随流体含量的增加而减少,而Cs含量随流体含量的增加而增加。大多数样品具有Eu负异常和弱的Ce正异常,表明早子沟和加甘滩金矿床形成于还原环境,成矿温度较低。样品的(La/Yb)_N较大,反映成矿深度相对较浅。石英的Y/Ho值分别为25.14~30.14和23.40~28.94,指示成矿流体与地壳关系密切。大多数石英样品的Th/La和 Nb/La 值小于1,在大陆地壳标准化图解中具有明显的Sc负异常,Cr、W、Pb和U正异常,表明成矿流体富Cl^-,相对富集Cr、W、Pb和U等元素。结合大地构造背景分析,早子沟和加甘滩金矿形成于大陆边缘环境。     

中国钾盐矿产基地成矿规律与深部探测技术示范

本项研究得到国家“十三五”重点研发计划支持,系“深地资源勘探开采专项”2017年启动的重点项目之一,由中国地质调查局中国地质科学院矿产资源研究所牵头,来自自然资源部、中国科学院、教育部、大型石油国企等10家骨干单位以及多家协作单位参加,联合开展协同创新研究,充分体现“产研学用”密切融合。本项研究聚焦“特提斯东段中生代(三叠纪、侏罗纪)海相成钾作用与后期改造、青藏高原北部柴达木盆地深层富钾卤水迁移-分异-汇聚成矿机制”的关键科学问题和“深部含钾盐系‘双复杂’高精度地震成像技术、深部钾盐矿层(富钾卤水层)测井识别与地震预测技术”的关键技术问题,以柴达木西部和川东北两个重点成钾区为资源基地落脚点,兼顾其他含钾盆地研究,建立三维地质模型和成矿模型,完善海、陆相成钾理论,形成3 000 m以浅钾盐勘探成套技术能力,综合评价深部钾盐资源潜力,实施异常验证钻探,新发现1个大型钾盐资源基地,值得综合评价的有利成钾远景区3~4处,实现深部钾盐找矿突破和增储示范。值得强调的是,只有立足国内,突破海相,在中西部大中型叠合盆地古代海相蒸发岩地层中找到大规模海相可溶性固体钾盐矿床,方能从根本上扭转中国钾盐资源严重短缺的被动局面。令人欣慰的是,通过近10年的艰苦努力,我国海相钾盐取得了一系列成矿理论新认识和钾盐找矿新发现:创新提出了滇西南“二层楼”成钾模式,指出侏罗纪海相找钾新方向;在川东北宣汉普光地区发现三叠系海相可溶性“新型杂卤石钾盐矿”,开拓了四川盆地海相找钾新领域和新方向;在新疆库车地区发现埋深超5 000 m的钾石盐矿层,取得了库车坳陷海相找钾的实质性进展;创新提出“W型复底锅”成钾模式,在陕北奥陶纪海相盐盆发现厚层钾石盐矿化段,取得古陆表海型钾盐找矿重要新进展。至此,中国海相钾盐找矿崭露了突破的曙光。如何在这些新发现的基础上,进一步加大投入、深入研究,取得海相可溶性钾盐找矿的实质性突破,落实建成若干大型以上海相钾盐资源基地,将是“十四五”及以后时期中国钾盐的主攻方向。