高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素

An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.     

两种海洋微藻硝酸还原酶活性测定方法的比较研究

对6种常见海洋微藻的硝酸还原酶活性测定方法进行了初步研究。确立了离体法和活体法的提取(振荡)时间及酶促反应时间,分别为:5 min,30 min(离体法)和6 min,10 min(活体法),并对2种方法进行了对比。结果表明:在本文条件下,离体法较活体法更适于进行塔玛亚历山大藻(Alexandrium tamarense)、强壮前沟藻(Amphidinium carterae)、中肋骨条藻(Skeletonema costatum)、新月菱形藻(Nitzchia closterium)和旋链角毛藻(Chaetoceros curvisetus)的硝酸还原酶活性的测定;活体法更适于东海原甲藻(Prorocentrum donghainase)硝酸还原酶活性的测定。     

IPCC第六次气候变化评估中的气候约束预估方法

得益于第五次评估报告（AR5）以来约束预估研究的迅速发展,观测约束成为政府间气候变化专门委员会（IPCC）第一工作组（WGI）第六次评估报告（AR6）提升对未来预估约束的证据链中的重要一环。IPCC第一工作组第六次评估报告首次利用包括根据历史模拟温度升高幅度得到的观测约束、多模式预估以及第六次评估报告中更新的气候敏感度在内的多条证据链来约束全球地表温度未来变化的预估,减小了多模式预估的不确定性。文中回顾并介绍了IPCC第一工作组第六次评估报告中涉及的几种主要观测约束方法（多模式加权方法、基于归因结论的约束方法（ASK方法）、萌现约束方法）及其应用情况。在IPCC第一工作组第六次评估报告以及很多针对不同区域不同变量的预估研究中,观测约束方法均显示出了订正模式误差、改善模式预估的潜力。相比而言,目前中国在观测约束预估方面的研究还不多,亟待加强观测约束方法研究以及在中国区域气候变化预估中的应用,为中国应对气候变化的政策制定和适应规划提供更丰富、不确定性更小的未来气候信息。      

村镇滑移隔震建筑瞬时摩擦耗能的参数敏感性分析

给出了村镇滑移隔震建筑瞬时摩擦耗能的概念,并以此概念为响应指标。通过极差大小的对比,分析了该响应指标对刚度比、第二阶段刚度系数、隔震层屈服位移、隔震层摩擦系数、系统质量比和上部结构自振周期六个参数变化的敏感程度,阐述了上述系统参数对瞬时摩擦耗能这一响应指标的影响规律。研究表明:场地条件和地震动幅值大小对瞬时摩擦耗能均有显著影响;在所考虑的参数范围内,上部结构自振周期总是对瞬时摩擦耗能有较为显著的影响,摩擦系数对瞬时摩擦耗能的影响跟场地条件有关,Ⅰ类场地条件中摩擦系数对瞬时摩擦耗能影响不显著,而Ⅱ、Ⅲ和Ⅳ类场地条件中,摩擦系数对瞬时摩擦耗能的影响则非常显著;隔震层屈服位移、刚度比和第二阶段刚度系数总得来讲对瞬时摩擦耗能影响不显著,质量比对瞬时摩擦耗能影响居中。     

Impact of global warming on drought in China

Spatial and temporal change patterns of air temperature (T), precipitation (P), relative humidity (RH), lower vapor pressure (VP), potential evapotranspiration (PET) and drought situation of 690 meteorological stations for all of China were evaluated in this study to understand the effects of warming on regional drought and hydrological processes. Here, the drought extent is expressed by aridity index (AI), which is the ratio of precipitation and reference crop evapotranspiration (ET₀) calculated by FAO Penman-Monteith equation, taking into account air temperature, atmospheric humidity, solar radiation, and wind. Our results indicate that there are different patterns of climate change from 1961 to 2008 and from 1981 to 2008. Little precipitation change occurred in China and ET₀ decreased from 1961 to 2008. But, the warming trend has intensified and the area with significant increasing precipitation has reduced since the early 1980’s and ET₀ has increased in most areas of China from 1981 to 2008 and decreased from 1961 to 2008. The areas affected by drought have shifted from North China and Northeast China to East China and South China since 1981. It is speculated that the increasing warming intensity after 1981 possibly strengthened the power of potential evapotranspiration and resulted in drought in most areas of Northeast China, North China, eastern Southwest China, and especially in East China and South China.     

基于"山西2015速度模型"的定位方法对比研究

为了确定山西台网基于“山西2015速度模型”的相对固定的定位方法,选择2010~2016年最大空隙角小于45°、参与定位台站数大于40的103个地震事件,分别采用单纯形法、Hypo2000、Hyposat结合PTD等3种方法重新测定。结果显示,单纯形法和Hyposat结合PTD测定的残差以及网缘地震的震中距两方面均优于Hypo2000;在震源深度方面,Hyposat结合PTD的结果较为可信。综合分析认为,基于“山西2015速度模型”定位地震时,山西台网应固定使用Hyposat结合PTD的方法。     

适用于声波方程数值模拟的时间-空间域隐式有限差分算子优化方法

声波方程数值模拟已广泛应用于理论地震计算,同时构成了地震逆时偏移成像技术的基础.对于有限差分法而言,在满足一定的稳定性条件时,普遍存在着因网格化而形成的数值频散效应.如何有效地缓解或压制数值频散是有限差分方法研究的关键所在.有限差分格式分为显式有限差分和隐式有限差分.隐式有限差分能够进一步压制数值频散效应.因此本文提出了给定频率范围满足时间-空间域隐式有限差分频散关系的方法,并根据震源频率、波速和网格间距确定波数范围,在此基础上建立方程确定了相应的隐式有限差分系数,使得差分系数能在更大频率范围符合波场传播规律.通过频散分析和正演模拟,验证了本文方法的有效性.     

花岗岩风化料弃土快速堆填过程中不排水抗剪强度评估

沿海沿江城市地下开挖产生的工程渣土含泥量大、含水率高且较松散,主要运往渣土场进行堆填处置。由于产量巨大而处置场地有限,许多渣土场在运营过程中存在堆填速度快、缺乏排水设施、超高超库容堆填等问题,容易引发堆填体失稳事故。目前对于非饱和工程渣土堆体在快速堆填过程中的失稳机制认识尚不清晰,尤其是对这一过程中的高饱和度工程渣土强度增长规律缺乏足够的认识。以深圳红坳渣土场填料——花岗岩风化料(CDG)填土为研究对象,对不同初始饱和度土样进行三轴不排水不排气等向压缩和剪切试验,结果表明:非饱和CDG填土不排水抗剪强度随围压增大呈非线性增长,增长速率与试样初始饱和度密切相关;当土样压缩后的饱和度超过0.7,不排水强度随围压的增长速率显著降低。基于有效固结应力法的原理,结合Hilf孔压公式和修正剑桥模型,提出了一种工程渣土不排水抗剪强度估算方法,并通过与试验结果对比验证了该方法对初始饱和度高于0.6的CDG填土的适用性。利用该方法确定的不排水强度cu与正应力σn的关系可应用于高饱和度工程渣土快速堆填中的稳定性分析。     

卡尔曼滤波压制瞬变电磁干扰技术及应用

煤田瞬变电磁探测经常是在干扰较强的煤矿周边进行,采集到的二次感应场信号大多噪声水平较高,难以开展解释工作。为消除野外数据中的这些电磁干扰,根据衰减曲线单向衰减的形态特征,通过应用卡尔曼滤波技术压制各种干扰,较好地恢复数据原始信号。通过对受到高压线电磁干扰的煤矿采空区实际探测数据进行该滤波方法的处理解释,对比滤波后数据与高压线断电后原测区重测的不受干扰的数据,得到了基本一致的效果,证明了该方法的有效性。