辽西北票早侏罗世兴隆沟组英安岩的地球化学特征

辽西北票早侏罗世兴隆沟组英安岩具有埃达克岩的地球化学特征。它们具有较高的SiO2（≥63．93％）、Al2O3（≥15．40％）、Na2O（≥3．65％）和MgO（≥2．32％，Mg^#=0．48～0．61）含量，较高的Sr（〉463μg／g）、Cr（〉119μg／g）、Ni（〉75μg／g）含量，较低的Yb（〈1．70μg／g）、Y（〈17μg/g）含量，高的La／Yb（〉18）、Sr／Y（〉34）值和低Rb／Sr（≤0．31）比值，稀土元素强烈分馏，弱的负铕异常（Eu／Eu^＋=0．80～0．87）．它们的Nd同位素（^143Nd/^144Nd=0．512414～0．512502．εND（t）=-2．10～-0．38，TDM：0．89～1．02Ga），Sr同位素（^87Sr／^86Sr=0．7073～0．7075，8Sr（t）=11．16～13．78）和Pb同位素（^206Pb／^204Pb=18．28～18．40，^207Pb／^204Pb=15．42～15．53，^208Ph／^204Pb=38．08～38．27）组成与华北陆块古老的岩石圈地幔及其中的中晚侏罗世和早白垩世火山岩不同。这表明兴隆沟组英安岩可能是古亚洲洋壳残片部分熔融形成的，熔体在上升过程中与地幔楔发生过强烈的混染作用。据此，推测古亚洲洋曾向华北陆块发生过俯冲作用。     

The viscosity of hydrous dacitic liquids: implications for the rheology of evolving silicic magmas

The viscosity of a series of six synthetic dacitic liquids, containing up to 5.04 wt% dissolved water, was measured above the glass transition range by parallel-plate viscometry. The temperature of the 10¹¹ Pa s isokom decreases from 1065 K for the anhydrous liquid, to 864 K and 680 K for water contents of 0.97 and 5.04 wt% H₂O. Including additional measurements at high temperatures by concentric-cylinder and falling-sphere viscometry, the viscosity (η) can be expressed as a function of temperature and water content w according to: where η is in Pa s, T is temperature in K, and w is in weight percent. Within the conditions of measurement, this parameterization reproduces the 76 viscosity data with a root-mean square deviation (RMSD) of 0.16 log units in viscosity, or 7.8 K in temperature. The measurements show that water decreases the viscosity of the dacitic liquids more than for andesitic liquids, but less than for rhyolites. At low temperatures and high water contents, andesitic liquids are more viscous than the dacitic liquids, which are in turn more viscous than rhyolitic liquids, reversing the trend seen for high temperatures and low water contents. This suggests that the relative viscosity of different melts depends on temperature and water content as much as on bulk melt composition and structure. At magmatic temperatures, rhyolites are orders of magnitude more viscous than dacites, which are slightly more viscous than andesites. During degassing, all three liquids undergo a rapid viscosity increase at low water contents, and both dacitic and andesitic liquids will degas more efficiently than rhyolitic liquids. During cooling and differentiation, changing melt chemistry, decreasing temperature and increasing crystal content all lead to increases in the viscosity of magma (melt plus crystals). Under closed system conditions, where melt water content can increase during crystallization, viscosity increases may be small. Conversely, viscosity increases are very abrupt during ascent and degassing-induced crystallization.     

Role of magma mixing in the petrogenesis of tephra erupted during the 1990–98 explosive activity of Nevado Sabancaya,southern Peru

The Nevado Sabancaya in southern Peru has exhibited a persistent eruptive activity over eight years following a violent eruption in May–June 1990. The explosive activity consisted of alternated vulcanian and phreatomagmatic events, followed by declining phreatic activity since late 1997. The mean production rate of magma has remained low (10⁶–10⁷ m³ per year).The 1990–1998 eruptive episode produced andesitic and dacitic magmas. The juvenile tephra span a narrow range of compositions (60–64 wt% SiO₂). While SiO₂ contents do vary slightly, they do not show any systematic variation with time. Phenocryst assemblages in the juvenile rocks consist of mainly plagioclase, associated with high-Ca pyroxene, hornblende, biotite, and iron-titanium oxides. Rare fine-grained magmatic enclaves, with angular to subrounded shapes, are contained within some of the juvenile lava blocks, which were expelled since 1992. They have a homogeneous andesitic composition (57 wt% SiO₂) and show randomly oriented interlocking columnar or acicular crystals (plagioclase and amphibole), with interstitial glass and a few voids, which define a quench-textured groundmass.Textural, mineralogical and chemical evidence suggests that the 1990–1998 eruptions have mainly erupted hybrid andesites, except for the 1990 dacite. The hybrid andesites contain a mixed population of plagioclase phenocrysts: Ca-rich clear plagioclase (An_40–60), Na-rich clear plagioclase (An_25–35), and inversely zoned dusty-rimmed plagioclase with a sodic core (An_25–40) surrounded by a Ca-rich mantle (An_45–65). Melt-inclusions, wavy dissolution surfaces and stepped zoning within the dusty-rimmed plagioclases are compatible with resorption induced by magma recharge events. Chemical and isotopic lines of evidence also show that andesites are hybrids resulting from magma mixing processes. Repeated magma recharge, incomplete homogenisation and different degrees of crustal assimilation may explain the extended range of isotopic signatures.Our study leads to propose an evolution model for the magmatic system at Nevado Sabancaya. The main magma body consisted of dacitic magmas differentiating through extensive open-system crystallization (AFC). Repeated recharge of more mafic magmas induced magma mixing, leading to the formation of hybrid andesites. A partially crystalline boundary layer formed at the interface between the andesites and the recharge magma. The magmatic enclaves were produced by the disruption and dispersion of this andesitic layer as a result of new magma injection and/or sustained tectonic activity.Periodic magma recharge and interactions with groundwater are two processes that have enabled the explosive regime to remain persistent over an 8-year-long period. What precise mechanism triggers the eruptive activity remains speculative, but it may be related either to new magma injection, or to the sustained tectonic activity that occurred at that time in the vicinity of the volcano, or a combination of both.     

辽西建昌-凌源地区早侏罗世水泉沟组底部英安岩中斜长石环带特征的解译

辽西建昌-凌源地区早侏罗世水泉沟组底部英安岩中斜长石和角闪安山岩中的角闪石具有环带结构.对斜长石用电子探针分析方法研究,发现较完整的斜长石晶体是由具反环带特征的核部和5个具正环带特征的振荡环带组成,核部与振荡环带之间存在熔蚀面.采用相图和晶体环带样式理论分析得出,核部的反环带指示岩浆中无水矿物结晶使岩浆房中的PH2O增大,熔蚀面代表了PH2O增大到某一临界值导致岩浆房上覆围岩破裂,5个振荡环带反映岩浆房上覆围岩破裂后在岩浆房中心和边缘之间岩浆发生过强对流并最终喷出地表.具环带结构的角闪石的结晶压力(核部(5.8±0.5)×108Pa,边部(4.8±0.5)×108Pa)说明,岩浆房的深度为17.5±1.8km,岩浆房开放前流体超压达到过1×108Pa左右.推断,辽西建昌-凌源地区早侏罗世早期地壳岩石圈上部处于压应力状态,下部处于张应力状态.     

河南嵩县大庄萤石矿地质特征及成因

矿区位于华北地台南缘外方山断隆区的中西部,大庄—中胡背斜之北翼,属著名的秦岭多金属和非金属成矿带的一部分.矿区地层出露简单,断裂构造比较发育,中部近东西向的区域大断裂(F1)是本区萤石矿的主要控矿构造带.对该区萤石矿脉进行了初步研究,圈出了Ⅰ、Ⅱ号2个萤石矿体,矿体形态分别呈脉状和透镜状.初步研究认为大庄萤石矿属低温热液裂隙充填型矿床.本区沿断裂两侧且伴随有强烈的硅化、高岭石化和萤石矿化的次一级断裂破碎带,是寻找该类矿床的重要标志.     

Volcanic evolution of Volcán Aucanquilcha: a long-lived dacite volcano in the Central Andes of northern Chile

Volcán Aucanquilcha, northern Chile, has produced ∼37 km³ of dacite (63–66 wt% silica), mainly as lavas with ubiquitous magmatic inclusions (59–62 wt% silica) over the last ∼1 million years. A pyroclastic flow deposit related to dome collapse occurs on the western side of the edifice and a debris avalanche deposit occurs on the eastern side. The >6,000-m high edifice defines a 9-km E–W ridge and lies at the center of a cluster of more than 15 volcanoes, the Aucanquilcha Volcanic Cluster, that has been active for at least the past 11 million years. The E–W alignment of vents is nearly orthogonal to the arc axis. A majority of Volcán Aucanquilcha was constructed during the first 200,000 years of eruption, whereas the last 800,000 years have added little additional volume. The peak eruptive rate during the edifice-building phases was ∼0.16 km³/ka and the later eruptive rate was ∼0.02 km³/ka. Comparable dacite volcanoes elsewhere show a similar pattern of high volcanic productivity during the early stages and punctuated rather than continuous activity. Volcán Aucanquilcha lavas are dominated by phenocrysts of plagioclase, accompanied by two populations of amphibole, biotite, clinopyroxene, Fe–Ti oxides and (or) orthopyroxene. Accessory phases include zircon, apatite and rare quartz and sanidine. One amphibole population is pargasite and the other is hornblende. The homogeneity of dacite lava from Volcán Aucanquilcha contrasts with the heterogeneity (52–66 wt% silica) at nearby Volcán Ollagüe, which has been active over roughly the same period of time. We attribute this homogeneity at Aucanquilcha to the thermal development of the crust underneath the volcano resulting from protracted magmatism there, whereas Volcán Ollagüe lacks this magmatic legacy.     

太岳山17.9亿年英安斑岩的发现及其对华北克拉通南部裂谷系成因的约束

熊耳群火山岩系主要分布于华北克拉通南部地区, 主体喷发时限是1.75~1.80Ga。作为华北克拉通早期板块构造调整阶段的首次大规模岩浆活动, 该火山-侵入岩系的形成时限、时空分布规律和地球动力学背景尚有争议, 制约了对华北克拉通中元古代构造演化的进一步认识。本次研究在华北中部太岳山地区识别出中元古代英安斑岩, 与古元古代花岗质片麻岩围岩呈侵入关系, 无明显变质变形。锆石U-Pb年龄分析结果表明, 该英安斑岩形成于1.79Ga, 属于熊耳期岩浆活动的产物。样品中约90%的锆石显示出~1.92Ga和~2.16Ga两期年龄峰值, 推测其为围岩的捕获锆石。英安斑岩SiO₂含量为65.12%~66.11%, A/CNK=0.91~1.05, 全碱(K₂O+Na₂O)含量为6.85%~7.28%, Na₂O/K₂O=0.48~0.54, 属于钾玄岩系列。样品稀土元素含量较高, 亏损Nb、Ta、Zr、Hf等高场强元素, 富集Rb、Ba、La等大离子亲石元素, 与华北克拉通南部地区熊耳期英安-流纹斑岩的地球化学特征完全一致, 指示板内伸展环境。太岳山熊耳期英安斑岩的发现, 贯通了中条山地区的熊耳群火山岩系、吕梁地区汉高山群和小两岭火山岩系, 完善了熊耳三叉裂谷系北支的空间分布范围, 是华北克拉通中部地区开启中元古代裂陷作用演化的重要岩浆记录。

     

阿尔泰南缘阿舍勒盆地泥盆纪火山岩中古老锆石的U-Pb年龄、Hf同位素和稀土元素特征及其地质意义

阿尔泰造山带南缘发育有NW向斜列的四个泥盆纪海相火山岩沉积盆地,位于北西端的阿舍勒盆地产有阿舍勒大型铜锌矿床,前人对该矿床开展了大量研究,但其容矿火山岩的年龄尚未明确厘定。本文应用LA-ICP-MS锆石U-Pb定年和锆石Hf同位素、微量元素,对阿舍勒铜锌矿区内出露的泥盆纪火山岩进行了研究。由锆石U-Pb定年获得了一组火山岩老锆石谐和年龄为1985±8.9Ma,加权年龄为2005±30Ma,代表了阿尔泰地区前寒武纪结晶基底的形成时代,其Th/U值在0.25～0.90之间,εHf(t)为-1.4～8.5,平均值为3.3;另外一组新锆石年龄为408±8Ma,其εHf(t)为9.3,Th/U值为0.49,具有典型岩浆锆石特征,代表了早泥盆世岩浆活动高峰期一次火山活动时代。老锆石∑REE从最低的1015×10-6变化到最高的3486×10-6,表现为轻稀土亏损,重稀土富集特征;本组锆石不同于正常岩浆锆石的显著特征是部分出现Ce元素负异常。锆石U-Pb年龄、Hf同位素及稀土元素Ce负异常特征综合显示,阿尔泰前寒武纪结晶基底可能形成于Columbia超大陆拼合聚集背景下,其物源来自强还原性地幔物质与氧化性地壳物质的不均匀混合。